scholarly journals Promoted Disappearance of CO2 Hydrate Self-Preservation Effect by Surfactant SDS

Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3909
Author(s):  
Xueping Chen ◽  
Shuaijun Li ◽  
Peng Zhang ◽  
Wenting Chen ◽  
Qingbai Wu ◽  
...  

The capture, storage and utilization of CO2 through hydrate-related technology is a promising approach to addressing the global warming issue. Dissociation is required after the transportation of CO2 gas in the form of a self-preserving hydrate. In order to investigate the dissociation behaviors as the self-preservation effect is removed, CO2 hydrates were frozen, and then the self-preservation effect was removed through uniform heating. An evident dependence of hydrate dissociation duration on the initial dissociation rates after losing the preservation effect was observed. The results in the silica gel powder and sodium dodecyl sulphate solution showed significant reductions in the initial dissociation temperatures and a slight decrease in the initial dissociation rates when compared with those of pure water. The reductions in the former were 2.88, 2.89, and 5.73 °C in silica gel, sodium dodecyl sulphate, and a combination of the two, respectively, while the reductions in the latter were 0.12, 0.12, and 0.16 mmol/min, respectively. As the results are inconsistent with the conventional mechanism elucidating a self-preservation effect, the ice shell theory was hence further supplemented by introducing innovative contribution factors—nonenclathrated liquid water and gas molecules dissolved inside. These findings are expected to provide references for CO2 gas transportation and usage of the self-preservation effect.

2020 ◽  
Author(s):  
Xueping Chen ◽  
Peng Zhang ◽  
Shuaijun Li ◽  
Wenting Chen ◽  
Qingbai Wu ◽  
...  

Abstract Capture, storage and utilization of CO2 gas through the hydrate technology is deemed as a promising approach to solve the problem on global warming. After efficient transportation of CO2 gas with the self-preservation effect of hydrate, the dissociations of hydrate are required in some practical scenarios. In order to investigate the initial dissociation properties of hydrates while the self-preservation effect was removed, CO2 hydrates were formed in different experimental conditions and media and then frozen. After that, the self-preservation effect of hydrates was slowly removed through a uniform heating method. The measurement results exhibit that comparing with the pure water (PW), the initial dissociation temperatures (IDT) are significantly lowered by the silica gel powder (SG) and sodium dodecyl sulphate (SDS) solution (SS). Similarly, the initial dissociation rates (IDR) of hydrates are also reduced. These patterns are opposite to the traditional elucidating mechanism of the self-preservation effect of hydrate. Hence, the theory of ice shell was supplemented furthermore. In addition, it is found that the final duration time of the entire dissociation process of hydrate after losing the preservation effect presents obvious dependence on the initial dissociation rate (IDR). These findings are expected to provide some references for the future transportation of CO2 gas with the self-preservation effect of hydrate.


2019 ◽  
Vol 4 (3) ◽  
Author(s):  
Abdul Rahman Hassan ◽  
Al Dabbaas Khuzama Mansoor A ◽  
Nor Azirah Sulaiman ◽  
Nurul Hannan Mohd Safari ◽  
Sabariah Rozali

Water shortage has become a real problem at global level and therefore, new and innovative technologies were established to provide sustainable solutions to water crisis. One of the effective approaches to resolve the global challenges is introducing the membrane-based desalination. Reverse Osmosis (RO) is a pressure driven membrane process which becoming increasingly popular and widely used for water purification applications that require high salt rejection such as brackish and seawater desalination. In this study, the influence of Sodium dodecyl sulphate (SDS) surfactant in producing the finest membrane for desalination were investigated in terms of performance, morphological structure and molecular orientation. From a polymer blending of polysulfone (PSF)/N-Methyl-2-Pyrrolidone (NMP)/polyvinylpyrrolidone (PVP)/sodium dodecyl sulphate (SDS) were formulated for making of low pressure reverse osmosis (LPRO) membrane. In order to examine the influence of SDS surfactant, different concentration from 0 wt% to 3 wt% were employed for desalination application of 10,000ppm (brackish water) and 50 000ppm (seawater). Experimental data showed that the increasing of 0.5wt% in surfactant produced higher pure water permeation (PWP) and flux. At 2.5wt% of SDS, the LPRO membranes showed the highest PWP of about 44.8L/m2h and brackish water flux at 45.58L/m2h. Meanwhile, at 3.0wt%, the highest flux of seawater at 39.37L/m2h was obtained. Moreover, the optimized LPRO (2wt% of SDS) membrane performed high rejection ratio of 90.9% for brackish water and 90.4% for seawater concentration of 10,000ppm and 50,000ppm, respectively. Therefore, the findings revealed that the fabricated LPRO membrane having a good potential to be used as eco-efficient desalination process of brackish water and seawater technology.


RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38006-38010 ◽  
Author(s):  
Yue Teng ◽  
Le Xin Song ◽  
Wei Liu ◽  
Juan Xia ◽  
Li Zhao ◽  
...  

A novel metallo-supramolecular micelle PF–SDS–SM was formed at room temperature through the self-assembly of potassium ferrioxalate and sodium dodecyl sulphate.


BIBECHANA ◽  
2014 ◽  
Vol 11 ◽  
pp. 103-112 ◽  
Author(s):  
Tulasi Prasad Niraula ◽  
Ajaya Bhattarai ◽  
Sujeet Kumar Chatterjee

Careful measurements of surface tension and viscosity of sodium dodecyl sulphate (SDS) in presence and absence of KCl in pure water and methanol-water mixed solvent media containing 0.1, 0.2, 0.3 and 0.4 volume fractions of methanol at 308.15 K are reported. The concentration of KCl is 0.01M. The concentration of SDS varies from 4.86×10-3 to 29.56×10-3 mol.l-1. The critical micelle concentration (cmc) increases with increase in percentage of methanol and decreases with addition of salt. DOI: http://dx.doi.org/10.3126/bibechana.v11i0.10388 BIBECHANA 11(1) (2014) 103-112


2018 ◽  
Vol 26 (2) ◽  
pp. 058
Author(s):  
Anna P. Roswiem ◽  
Triayu Septiani

<em>Bahan<strong> </strong>baku untuk membuat baso adalah daging hewan, pada umumnya dari daging sapi, ayam, ikan dan babi. Di beberapa daerah di Indonesia terjadi kasus baso tikus. Tujuan penelitian ini adalah menguji ada tidaknya kandungan daging tikus pada produk baso yang dijual di pasar Cempaka Putih-Kecamatan Kramat Jakarta Pusat dan di pedagang baso atau mie baso di sekitar kampus Universitas YARSI Jakarta. Daging adalah protein salah satu metode untuk mengidentifikasi protein adalah metode Sodium Dodecyl Sulphate Polyacrylamide Gel Electrophoresis (SDS-PAGE).<strong> </strong>Hasil penelitian menunjukkan bahwa dari 6 sampel baso terindikasi ada 2 sampel baso dengan nomor 1 dan 5 yang dibuat dari campuran daging sapi dan tikus; ada 1 sampel baso dengan nomor 6 yang terbuat dari daging tikus; dan 2 sampel baso dengan nomor 2 dan 3 yang terbuat dari campuran sapi  dan babi, dan hanya 1 sampel baso dengan nomor sampel 4 yang benar-benar terbuat dari daging sapi.</em>


2018 ◽  
Vol 10 (6) ◽  
pp. 06013-1-06013-5 ◽  
Author(s):  
I. G. Vorobiova ◽  
◽  
Yu. A. Mirgorod ◽  
A. S. Chekadanov ◽  
◽  
...  

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