scholarly journals Isomerization of n-C5/C6 Bioparaffins to Gasoline Components with High Octane Number

Energies ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1672 ◽  
Author(s):  
Jenő Hancsók ◽  
Tamás Kasza ◽  
Olivér Visnyei
Keyword(s):  
Octane Number ◽  
Research Work ◽  
Oxidation Stability ◽  
Waste Cooking Oil ◽  
Side Reactions ◽  
Jet Fuels ◽  
Diesel Fuels ◽  
Boiling Range ◽  
Alternative Feedstocks ◽  
By Products

The thermal and catalytic conversion processes of alternative feedstocks (e.g., waste and biomass) to different engine fuels can result in the formation of a significant amount of light hydrocarbons as by-products in the boiling range of gasoline. The properties of these C5/C6 hydrocarbons need to be improved due to many reasons, e.g., their benzene content, and/or poor oxidation stability (high olefin content) and low octane number (<60). The aim of the research work was to increase the octane number of benzene containing C5/C6 bioparaffin fractions by catalytic isomerization. These by-products were obtained from special hydrocracking of waste cooking oil to hydrocarbons in the boiling range of aviation turbine fuels (JET fuels)/diesel fuels. Experiments were carried out in a reactor system containing down-flow tubular reactors over Pt/Al2O3/Cl and Pt/H-Mordenite/Al2O3 catalysts at 115–145 °C and 230–270 °C, respectively. Based on the results obtained at different process parameter combinations, it was concluded that the hydrogenation of benzene was complete over both catalysts, and the liquid yields were higher (ca. 98% > ca. 93 %) in the case of Pt/Al2O3/Cl. In addition, the octane number was also enhanced (ca. 32 > ca. 27 unit) in the products compared to the feedstock. This was because a higher isoparaffin content can be obtained at a lower operating temperature. Moreover, cracking side reactions take place to a lesser extent. The utilization of these isomerized bio-origin light fractions can contribute to the competitiveness of second-generation biofuels.

A Convenient Way for the Synthesis of Mono N-Alkylated Ethanolamine

2020 ◽  
Author(s):  
ZHE LI ◽  
Changren Yan
Keyword(s):  
Side Reactions ◽  
By Products

<p><i>N-</i>alkylated ethanol amines, especially the <i>N-</i>monoalkylated ethanol amines, feature widely applications in industries. This manuscript would introduce a new methodology to prepare <i>N-</i>monoalkylated ethanol amine derivatives that could avoid potential side reactions forming <i>N,N-</i>dialkylated by-products.</p>

Novel approaches for the production of bio-diesel using waste vegetable oil

2014 ◽  
Vol 3 (10) ◽  
pp. 3419
Author(s):  
Mohan Reddy Nalabolu* ◽  
Varaprasad Bobbarala ◽  
Mahesh Kandula
Keyword(s):  
Diesel Fuel ◽  
Oxidation Stability ◽  
Acid Value ◽  
Waste Cooking Oil ◽  
Flash Point ◽  
Carbon Residue ◽  
Fuel Properties ◽  
Present Moment ◽  
Total Acid ◽  
Cooking Oil

At the present moment worldwide waning fossil fuel resources as well as the tendency for developing new renewable biofuels have shifted the interest of the society towards finding novel alternative fuel sources. Biofuels have been put forward as one of a range of alternatives with lower emissions and a higher degree of fuel security and gives potential opportunities for rural and regional communities. Biodiesel has a great potential as an alternative diesel fuel. In this work, biodiesel was prepared from waste cooking oil it was converted into biodiesel through single step transesterification. Methanol with Potassium hydroxide as a catalyst was used for the transesterification process. The biodiesel was characterized by its fuel properties including acid value, cloud and pour points, water content, sediments, oxidation stability, carbon residue, flash point, kinematic viscosity, density according to IS: 15607-05 standards. The viscosity of the waste cooking oil biodiesel was found to be 4.05 mm2/sec at 400C. Flash point was found to be 1280C, water and sediment was 236mg/kg, 0 % respectively, carbon residue was 0.017%, total acid value was 0.2 mgKOH/g, cloud point was 40C and pour point was 120C. The results showed that one step transesterification was better and resulted in higher yield and better fuel properties. The research demonstrated that biodiesel obtained under optimum conditions from waste cooking oil was of good quality and could be used as a diesel fuel.

Ecological aspects of storage and transportation of diesel fuels

2021 ◽  
pp. 49-54
Author(s):  
V.Kh. Nurullayev ◽  
◽  
Kh.G. Ismayilova ◽  
L.M. Shikhiyeva ◽  
◽  
...  
Keyword(s):  
Diesel Fuel ◽  
Fractional Composition ◽  
Freezing Temperature ◽  
Environmental Safety ◽  
Petroleum Products ◽  
Oil Products ◽  
Jet Fuels ◽  
Diesel Fuels ◽  
Ecological Aspects

The paper presents up-to-date and perspective requirements for the quality of diesel fuels. The effect of chemical, as well as fractional composition on the quality of diesel fuels is marked. The capability of obtaining prospective ecologically friendly diesel fuel based on the mixture of Azerbaijani oils via hydro-treatment in the presence of the catalyst of alumonickelmolibdene is noted. Ecologically friendly diesel fuels with ASTMD 4294 by sulfur - 0.039 % mass, ASTMD 3227 by sour sulfur - 0.006 % mass, ASTMD 5708 by metals: V ˃ 2 mg/kg, Ni ˃ 1 mg/kg, Fe ˃ 3 mg/kg, Na ˃ 8 mg/kg, as well as with the freezing temperature of ASTMD 97 – 50 оС have been obtained. Such kinds of diesel fuel meet EN standards and provide environmental safety in storage and transportation to the European countries. The prospect of obtaining and using buffer plug (mixture of petroleum products) during consistent pumping of various sorts of oil products without ecologic-economic risks of jet fuels is shown as well.

Genetic Algorithm Approach to Optimize Biodiesel Production by Ultrasonic System

2014 ◽  
Vol 9 (1) ◽  
pp. 59-70 ◽  
Author(s):  
Ebrahim Fayyazi ◽  
Barat Ghobadian ◽  
Gholamhassan Najafi ◽  
Bahram Hosseinzadeh
Keyword(s):  
Genetic Algorithm ◽  
Catalyst Concentration ◽  
Ultrasonic Method ◽  
Research Work ◽  
Optimization Method ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Genetic Algorithm Approach ◽  
Mixing Method

Abstract Ultrasonic processing is an effective tool to attain required mixing while providing the necessary activation energy in the field of biofuels. In this regard, optimization of fast transesterification of waste cooking oil is very important. The goal of this research paper is therefore to determine the effect of important parameters such as methanol to oil molar ratio, catalyst concentration (potassium hydroxide), temperature, and horn position on oil conversion to methyl ester in ultrasonic mixing method. Result of experiments showed that the optimum conditions for the transesterification process have been obtained as molar ratio of alcohol to oil as 6:1, catalyst concentration of 1 wt.%, temperature as 45°C, and horn position at the interface of methanol to oil. The results show that the ultrasonic method decreases the reaction time as much as up to eight times compare to the conventional stirring. For practically evaluating the theoretical optimum point using genetic algorithm, the obtained values were verified experimentally. In order to perform this, the catalyst concentration, temperature, and the time of reaction were determined, and the values are 1%, 48°C, and 449s, respectively. For the obtained values, the biodiesel conversion was 93.2%, so that the experimental optimum value is closed to that of the theoretical values. As a result, experimental data confirmed the obtained values from optimization method in this research work.

Evaluation of the tribological properties and oxidative stability of epoxidized and ring opened products of pure rice bran oil

2020 ◽  
pp. 135065012095053
Author(s):  
Ananthan D Thampi ◽  
Abhishek R John ◽  
M Muhammed Arif ◽  
S Rani
Keyword(s):  
Hydrogen Peroxide ◽  
Vegetable Oils ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Research Work ◽  
Viscosity Index ◽  
Oxidation Stability ◽  
High Viscosity ◽  
Molar Ratio ◽  
Four Levels

Vegetable oils constitute a potential base stock for bio-lubricants, which has good biodegradability, high flash point, high viscosity index and excellent boundary lubrication properties. They also possess some limitations like low thermal and oxidation stability, poor low temperature properties and narrow range of viscosities. These limitations can be altered by modifying the vegetable oils chemically or by providing additives into the oils. This research work focused on the chemical modification of pure rice bran oil by epoxidation process using 30% hydrogen peroxide and glacial acetic acid. The epoxidized rice bran oil was then subjected to ring opening process using butanoic acid. The epoxidation process was optimized with four factors (Temperature, Time, Weight % of Catalyst, Hydrogen Peroxide molar ratio), each factors having four levels. The lubricant properties of pure rice bran oil (RBO), epoxidized rice bran oil (ERBO) and ring opened rice bran oil (RRBO) were studied. It was noted that the lubricant properties of ERBO and RRBO were better compared to pure RBO.

Thermal-oxidation stability of jet fuels in a two-phase closed system

2009 ◽  
Vol 45 (2) ◽  
pp. 115-121
Author(s):  
G. N. Kishkilev ◽  
V. A. Astaf’ev ◽  
A. V. Isaev ◽  
M. I. Fakhrutdinov
Keyword(s):  
Thermal Oxidation ◽  
Closed System ◽  
Oxidation Stability ◽  
Jet Fuels ◽  
Two Phase ◽  
Thermal Oxidation Stability

POSSIBILITIES OF USING CAMELINA SATIVA OIL FOR PRODUCING BIODIESEL FUEL

Transport ◽  
2012 ◽  
Vol 27 (1) ◽  
pp. 60-66 ◽  
Author(s):  
Ernestas Zaleckas ◽  
Violeta Makarevičienė ◽  
Eglė Sendžikienė
Keyword(s):  
Diesel Engines ◽  
Methyl Esters ◽  
Oxidation Stability ◽  
Quality Parameters ◽  
Camelina Sativa ◽  
Biodiesel Fuel ◽  
Optimal Dosage ◽  
The European Union ◽  
Oilseed Crops ◽  
Alternative Feedstocks

Biofuels for diesel engines are produced mainly from rapeseed oil in Lithuania and the Member States of the European Union. In order to minimise an adverse impact of biodiesel fuel on the food sector, it is necessary to look for alternative feedstocks for producing biodiesel fuel including the potential utilisation of the new kinds of oilseed crops and various fatty waste. Camelina (Camelina sativa) could be one of the kinds of such oilseed crops, and therefore the physical and chemical parameters of Camelina sativa oil and biodiesel fuel produced from this oil were determined and the conformity of quality parameters with the requirements of biofuel standard was evaluated. It was found that fatty acid methyl esters made from Camelina sativa oil had a high iodine value (164.6÷169.6 g I2 / 100 g oil), and therefore could be used as fuel for diesel engines only in the mixtures with methyl esters produced from animal fat or used for frying oil. It has been established that similar mixtures can contain 50÷60% of Camelina sativa oil methyl esters. The possibilities of increasing oxidation stability as well as improving the cold flow properties of ester mixtures were investigated. The most effective antioxidant – Ionol (optimal dosage of 500 ppm) and the most efficient depressants Wintron XC-30 (optimal dosage – 1500 ppm) and Infineum R-442 (optimal dosage – 1200 ppm) were selected.

A comprehensive review on biodiesel cold flow properties and oxidation stability along with their improvement processes

RSC Advances ◽  
2015 ◽  
Vol 5 (105) ◽  
pp. 86631-86655 ◽  
Author(s):  
I. M. Monirul ◽  
H. H. Masjuki ◽  
M. A. Kalam ◽  
N. W. M. Zulkifli ◽  
H. K. Rashedul ◽  
...  
Keyword(s):  
Oxidation Stability ◽  
Waste Cooking Oil ◽  
Fatty Acid Esters ◽  
Flow Properties ◽  
Cold Flow ◽  
Animal Fats ◽  
Cooking Oil ◽  
Cold Flow Properties ◽  
Different Sources ◽  
Acid Esters

Biodiesel, which comprises fatty acid esters, is derived from different sources, such as vegetable oils from palm, sunflower, soybean, canola, Jatropha, and cottonseed sources, animal fats, and waste cooking oil.

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