scholarly journals Micro- and Macroscale Consequences of Interactions between CO2 and Shale Rocks

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1167 ◽  
Author(s):  
Mohammad H. Bhuiyan ◽  
Nicolaine Agofack ◽  
Kamila M. Gawel ◽  
Pierre R. Cerasi

In carbon storage activities, and in shale oil and gas extraction (SOGE) with carbon dioxide (CO2) as stimulation fluid, CO2 comes into contact with shale rock and its pore fluid. As a reactive fluid, the injected CO2 displays a large potential to modify the shale’s chemical, physical, and mechanical properties, which need to be well studied and documented. The state of the art on shale–CO2 interactions published in several review articles does not exhaust all aspects of these interactions, such as changes in the mechanical, petrophysical, or petrochemical properties of shales. This review paper presents a characterization of shale rocks and reviews their possible interaction mechanisms with different phases of CO2. The effects of these interactions on petrophysical, chemical and mechanical properties are highlighted. In addition, a novel experimental approach is presented, developed and used by our team to investigate mechanical properties by exposing shale to different saturation fluids under controlled temperatures and pressures, without modifying the test exposure conditions prior to mechanical and acoustic measurements. This paper also underlines the major knowledge gaps that need to be filled in order to improve the safety and efficiency of SOGE and CO2 storage.

Author(s):  
Thais Helena Sydenstricker Flores-Sahagun ◽  
Kelly Priscila Agapito ◽  
ROSA MARIA JIMENEZ AMEZCUA ◽  
Felipe Jedyn

2021 ◽  
Author(s):  
Florence Letitia Bebb ◽  
Kate Clare Serena Evans ◽  
Jagannath Mukherjee ◽  
Bilal Saeed ◽  
Geovani Christopher

Abstract There are several significant differences between the behavior of injected CO2 and reservoired hydrocarbons in the subsurface. These fundamental differences greatly influence the modeling of CO2 plumes. Carbon capture, utilization, and storage (CCUS) is growing in importance in the exploration and production (E&P) regulatory environment with the Oil and Gas Climate Initiative (OGCI) making CCUS a priority. Companies need to prospect for storage sites and evaluate both the short-term risks and long-term fate of stored carbon dioxide (CO2). Understanding the physics governing fluid flow is important to both CO2 storage and hydrocarbon exploration and production. In the last decade, there has been much research into the movement and migration of CO2 in the subsurface. A better understanding of the flow dynamics of CO2 plumes in the subsurface has highlighted a number of significant differences in modeling CO2 storage sites compared with hydrocarbon reservoir simulations. These differences can greatly influence reliability when modeling CO2 storage sites.


BioResources ◽  
2020 ◽  
Vol 15 (3) ◽  
pp. 6795-6810
Author(s):  
Nurul Fatiha Osman ◽  
Paimon Bawon ◽  
Seng Hua Lee ◽  
Pakhriazad Hassan Zaki ◽  
Syeed SaifulAzry Osman Al-Eldrus ◽  
...  

Particleboard was produced by mixing oil heat-treated rubberwood particles at different ratios, with the goal of achieving high dimensional stability. Rubberwood particles were soaked in palm oil for 2 h and heat treated at 200 °C for 2 h. The treated particles were soaked in boiling water for 30 min to remove oil and were tested for chemical alteration and thermal characterization via Fourier-transform infrared spectroscopy and thermogravimetric analysis. Particleboard was fabricated by mixing treated rubberwood particles (30%, 50%, and 70%) with untreated particles (70%, 50%, and 30%, respective to previous percentages) and bonded with urea-formaldehyde (UF) resin. The results revealed that oil-heat treated particles had greater thermal stability than the untreated particles. The addition of oil heat treated particles improved the physical properties of the particleboard with no significant reduction in mechanical strength. However, this was only valid for ratios of 70% untreated to 30% treated and 50% untreated to 50% treated. When a ratio of 70% oil heat treated particles was used, both the physical and mechanical properties were reduced drastically, due to bonding interference caused by excessive oil content. Particleboard made with a ratio of 5:5 (treated to untreated) exhibited the best physical and mechanical properties.


2015 ◽  
Vol 75 (7) ◽  
Author(s):  
Amir Arifin ◽  
Abu Bakar Sulong ◽  
Norhamidi Muhamad ◽  
Junaidi Syarif

Hydroxyapatite (HA) has been widely used in biomedical applications due to its excellent biocompatibility. However, Hydroxyapatite possesses poor mechanical properties and only tolerate limited loads for implants. Titanium is well-known materials applied in implant that has advantage in mechanical properties but poor in biocompatibility. The combination of the Titanium alloy and HA is expected to produce bio-implants with good in term of mechanical properties and biocompatabilty. In this work, interaction and mechanical properties of HA/Ti6Al4V was analyzed. The physical and mechanical properties of HA/Ti6Al4V composite powder obtained from compaction (powder metallurgy) of 60 wt.% Ti6Al4V and 40 wt.% HA and sintering at different temperatures in air were investigated in this study. Interactions of the mixed powders were investigated using X-ray diffraction. The hardness and density of the HA/Ti6Al4V composites were also measured. Based on the results of XRD analysis, the oxidation of Ti began at 700 °C. At 1000 °C, two phases were formed (i.e., TiO2 and CaTiO3). The results showed that the hardness HA/Ti6Al4V composites increased by 221.6% with increasing sintering temperature from 700oC to 1000oC. In contrast, the density of the composites decreased by 1.9% with increasing sintering temperature. 


2015 ◽  
Vol 1754 ◽  
pp. 19-24
Author(s):  
A. Alipour Skandani ◽  
R. Ctvrtlik ◽  
M. Al-Haik

ABSTRACTMaterials with different allotropes can undergo one or more phase transformations based on the changes in the thermodynamic states. Each phase is stable in a certain temperature/pressure range and can possess different physical and mechanical properties compared to the other phases. The majority of material characterizations have been carried out for materials under equilibrium conditions where the material is stabilized in a certain phase and a lesser portion is devoted for onset of transformation. Alternatively, in situ measurements can be utilized to characterize materials while undergoing phase transformation. However, most of the in situ methods are aimed at measuring the physical properties such as dielectric constant, thermal/electrical conductivity and optical properties. Changes in material dimensions associated with phase transformation, makes direct measurement of the mechanical properties very challenging if not impossible. In this study a novel non-isothermal nanoindentation technique is introduced to directly measure the mechanical properties such as stiffness and creep compliance of a material at the phase transformation point. Single crystal ferroelectric triglycine sulfate (TGS) was synthetized and tested with this method using a temperature controlled nanoindentation instrument. The results reveal that the material, at the transformation point, exhibits structural instabilities such as negative stiffness and negative creep compliance which is in agreement with the findings of published works on the composites with ferroelectric inclusions.


2020 ◽  
Author(s):  
Susilawati ◽  
Jantiber Siburian ◽  
Yuan Alfinsyah Sihombing ◽  
Bonar Ferdiansyah ◽  
Sri Ningsih Y. Pakpahan

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