scholarly journals Silver Decorated Reduced Graphene Oxide as Electrocatalyst for Zinc–Air Batteries

Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 462 ◽  
Author(s):  
Laksanaporn Poolnapol ◽  
Wathanyu Kao-ian ◽  
Anongnat Somwangthanaroj ◽  
Falko Mahlendorf ◽  
Mai Thanh Nguyen ◽  
...  

Due to their low cost and very high energy density, zinc–air batteries (ZABs) exhibit high potential for various energy applications. The electrochemical performance of the air-cathode has a decisive impact on the discharge performance of ZABs because the sluggish oxygen reduction reaction (ORR) kinetics increase the overpotential of the air-cathode and hence the performance of ZABs. In this work, reduced graphene oxide decorated with silver nanoparticles (AgNP/rGO) is synthesized using simultaneous reduction of graphene oxide and silver ions. Different amounts of silver loading are examined for the synthesis of AgNP/rGO. The synthesized AgNP/rGO samples are analyzed using a rotating disk electrode in order to investigate ORR activity. Then, the synthesized AgNP/rGO electrocatalyst is applied on a tubular designed zinc–air battery in order to study the performance of the zinc–air battery. Results demonstrate that AgNP/rGO is an efficient and cost-effective ORR electrocatalyst for its practical application in ZABs.

2017 ◽  
Vol 4 (11) ◽  
pp. 3004-3010 ◽  
Author(s):  
Bo Chen ◽  
Yifan Tian ◽  
Zhaoxi Yang ◽  
Yunjun Ruan ◽  
Jianjun Jiang ◽  
...  

Science ◽  
2020 ◽  
Vol 371 (6524) ◽  
pp. 46-51
Author(s):  
Wei Sun ◽  
Fei Wang ◽  
Bao Zhang ◽  
Mengyi Zhang ◽  
Verena Küpers ◽  
...  

Rechargeable alkaline zinc-air batteries promise high energy density and safety but suffer from the sluggish 4 electron (e−)/oxygen (O2) chemistry that requires participation of water and from the electrochemical irreversibility originating from parasitic reactions caused by caustic electrolytes and atmospheric carbon dioxide. Here, we report a zinc-O2/zinc peroxide (ZnO2) chemistry that proceeds through a 2e−/O2 process in nonalkaline aqueous electrolytes, which enables highly reversible redox reactions in zinc-air batteries. This ZnO2 chemistry was made possible by a water-poor and zinc ion (Zn2+)–rich inner Helmholtz layer on the air cathode caused by the hydrophobic trifluoromethanesulfonate anions. The nonalkaline zinc-air battery thus constructed not only tolerates stable operations in ambient air but also exhibits substantially better reversibility than its alkaline counterpart.


2019 ◽  
Vol 48 (16) ◽  
pp. 5193-5202 ◽  
Author(s):  
Kai Le ◽  
Zhou Wang ◽  
Fenglong Wang ◽  
Qi Wang ◽  
Qian Shao ◽  
...  

Lab-synthesized sandwich-like LDH/rGO composites were assembled into asymmetric supercapacitors exhibiting high energy density and excellent cycling stability.


2017 ◽  
Vol 53 (1) ◽  
pp. 228-231 ◽  
Author(s):  
Subba R. Marri ◽  
Satyajit Ratha ◽  
Chandra Sekhar Rout ◽  
J. N. Behera

Hydrothermal synthesis of VSe2/reduced graphene oxide (RGO) has been reported and its supercapacitor performance was evaluated in a typical CR2032 coin cell setup. A specific capacitance of 680 F g−1and an ultra-high energy density of 212 W h kg−1were achieved.


2019 ◽  
Vol 10 (6) ◽  
pp. 1902836 ◽  
Author(s):  
Yizhan Hao ◽  
Shouzhi Wang ◽  
Yongliang Shao ◽  
Yongzhong Wu ◽  
Shiding Miao

Nanoscale ◽  
2013 ◽  
Vol 5 (17) ◽  
pp. 7984 ◽  
Author(s):  
Feng Luan ◽  
Gongming Wang ◽  
Yichuan Ling ◽  
Xihong Lu ◽  
Hanyu Wang ◽  
...  

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