scholarly journals Relaxor Phase Evolution of (Bi0.5Na0.5-xKx)TiO3 Ceramics due to K Ion Substitution and Their Corresponding Electrical Properties

Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 455 ◽  
Author(s):  
Sam Yeon Cho ◽  
Eun-Young Kim ◽  
Sun Yong Kim ◽  
Thuy Linh Pham ◽  
Jin Kyu Han ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Phase Evolution ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
Tetragonal Structure ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Structural And Electrical Properties ◽  
Ion Substitution

We synthesized lead-free piezoelectric (Bi0.5Na0.5-xKx)TiO3 (BNKT) ceramics using a conventional solid-state reaction method. We have investigated the structural and electrical properties of the materials with x = 0.05 to 0.40. The X-ray diffraction (XRD) analysis suggests that the BNKT ceramics show the transition from rhombohedral to tetragonal structure. The ratio of the tetragonal structure increased continuously in accordance with the increasing composition of x. The sample of x = 0.10 showed a similar ratio between the tetragonal and rhombohedral structures. Frequency-dependent dielectric measurements showed a sort of relaxor properties emerged with increasing x composition, this effect may be interpreted in terms of the formation of polar nano-regions (PNRs) in samples. The value of remnant polarization (Pr) decreases rapidly as x increases beyond the point of x = 0.10 from 25.3 μC/cm2 to 5.9 μC/cm2. On the contrary, as for inverse piezoelectric coefficient (d33*), a higher value of d33* (336 pm/V) at x = 0.10, was observed when compared with x = 0.05 (d33* = 51 pm/V). These results can be explained by the formation of PNRs and their variations with the external applied field. We here propose a possible mechanism showing the effects of dipolar defects, which can be resulted from the K ion substitution on (Bi,Na)TiO3 (BNT) ceramics.

Synthesis of Polycrystalline LaYO3 with Different Sintering Temperature

2015 ◽  
Vol 819 ◽  
pp. 117-122 ◽  
Author(s):  
N.A. Shafiqa ◽  
M.S. Idris ◽  
C.A. Salmie Suhana ◽  
R.A.M. Osman ◽  
T.Q. Tan
Keyword(s):  
Single Phase ◽  
Sintering Temperature ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
Scanning Electron Micrographs ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Pure Phase ◽  
Perovskite Ceramic

Synthesis of LaYO3 was carried out via conventional solid state reaction method. The polycrystalline samples were sintered at temperatures in the range of 1300 °C to 1500 °C with each deviation is 50 °C. X-ray diffraction (XRD) analysis indicated that the perovskite ceramic obtained its single phase at 1500 °C with ordered monoclinic perovskite structure. The pure phase sample showed 98.79 % relative density and scanning electron micrographs also proved that the porosity of the sample reduced when sample undergo sintering.

Electrical Properties of BNKTZ Ceramics as a Function of Calcination Temperature

2016 ◽  
Vol 872 ◽  
pp. 103-108
Author(s):  
Pichitchai Butnoi ◽  
Supalak Manotham ◽  
Pharatree Jaita ◽  
Ratabongkot Sanjoom ◽  
Denis Russell Sweatman ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Calcination Temperature ◽  
Piezoelectric Properties ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Xrd Patterns ◽  
Ferroelectric And Piezoelectric Properties ◽  
Xrd Method

In this research, the Bi0.5(Na0.80K0.20)0.5Ti0.99Ti0.10O3 were prepared via a conventional solid-state reaction method, and their properties were related with calcination temperature. The crystalline structure of BNKTZ ceramics was assessed by X-ray diffraction (XRD) method. Other physical properties, i.e. porosity, density, microstructure, and electrical properties were determined. XRD patterns for all samples showed a pure perovskite, where coexistence between rhombohedral and tetragonal phases was observed for some conditions. The optimum dielectric constant was obtained for the ceramic calcined at 800 °C. The ferroelectric and piezoelectric properties were improved and showed the highest values for the calcination temperature around 900-1000°C. The improvements of ferroelectric and piezoelectric properties were proposed to be due to the ceramics had compositions closed to MPB composition. Furthermore, density also had a contribution for the improvements.

Effect of CeO2 Nanoparticle on the Structural and Electrical Properties of BSCCO-2223 High Temperature Superconductor

2020 ◽  
Vol 307 ◽  
pp. 104-109
Author(s):  
E.S. Nurbaisyatul ◽  
Hashim Azhan ◽  
Azman Kasim ◽  
Norazila Ibrahim
Keyword(s):  
High Temperature Superconductor ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Critical Transition Temperature ◽  
X Ray ◽  
Tetragonal Crystal ◽  
Tetragonal Crystal Structure ◽  
Structural And Electrical Properties ◽  
Oxide Nanoparticle

A study of the effects of Cerium oxide nanoparticle doped with BSCCO-2223 on the microstructure and superconducting properties was carried out. All samples were synthesized using solid state reaction method. Ce concentration is varied from x = 0.0 up to 0.1 in a general stoichiometry of Bi1.6Pb0.4Sr2Ca1-xCexCu3Oy. The samples were characterized structurally and electrically by X-Ray Diffraction (XRD) and four-point probe method respectively. XRD analysis shows that both (Bi,Pb)-2212 and (Bi,Pb)-2223 phases coexist in the samples having tetragonal crystal structure but changed to orthorhombic when x=0.10. The values of critical transition temperature, TC and critical current density, JC of the samples decreased with the increase in Ce concentration. The possible reasons for the observed degradation in superconducting and structural properties of Bi-2223 due to Ce nanoparticles addition were discussed.

Fabrication and study the effect of the laser on the properties of the compound Tl2-xHgxBa2-ySryCa2Cu3O10+δ superconductor

2018 ◽  
pp. 168
Author(s):  
A. Kareem Dahash Ali ◽  
Nihad Ali Shafeek
Keyword(s):  
Transition Temperature ◽  
Solid State ◽  
Hydrostatic Pressure ◽  
Electrical Properties ◽  
Co2 Laser ◽  
Temperature Shift ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structural And Electrical Properties

This study included the fabrication of    compound (Tl2-xHgxBa2-ySryCa2Cu3O10+δ) in a manner solid state and under hydrostatic pressure ( 8 ton/cm2) and temperature annealing(850°C), and determine the effect of the laser on the structural and electrical properties elements in the compound, and various concentrations of x where (x= 0.1,0.2,0.3 ). Observed by testing the XRD The best ratio of compensation for x is 0.2 as the value of a = b = 5.3899 (A °), c = 36.21 (A °) show that the installation of four-wheel-based type and that the best temperature shift is TC= 142 K  .When you shine a CO2 laser on the models in order to recognize the effect of the laser on these models showed the study of X-ray diffraction of these samples when preparing models with different concentrations of the values ​​of x, the best ratio of compensation is 0.2 which showed an increase in the values ​​of the dimensions of the unit cell a=b = 5.3929 (A °), c = 36.238 (A°). And the best transition temperature after shedding laser is TC=144 K. 

Structure and Electrical Characteristics of BaTiO3 and Ba0.99Er0.01TiO3 Ceramics

2018 ◽  
Vol 280 ◽  
pp. 127-133 ◽  
Author(s):  
F. A. Ismail ◽  
Rozana Aina Maulat Osman ◽  
Mohd Sobri Idris ◽  
N.A.M. Ahmad Hambali
Keyword(s):  
Perovskite Phase ◽  
Microstructural Analysis ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
Grain Sizes ◽  
Capacitance Voltage ◽  
Ion Incorporation ◽  
Voltage Breakdown

Conventional solid state reaction method was used to prepare BaTiO3 and Ba0.99Er0.01TiO3 ceramics. Influence of Er3+ ion incorporation on their structural, microstructural and electrical properties was studied. The phase pure samples were obtained when heated at 1400 °C for overnight. The tetragonal perovskite phase of BaTiO3 and Ba0.99Er0.01TiO3 was confirmed by using X-ray Diffraction (XRD) analysis which is in agreement with results obtained from Rietveld refinement analysis. The lattice parameters and unit cell volume of BaTiO3 increased when doped with Erbium. Microstructural analysis of BaTiO3 and Ba0.99Er0.01TiO3 ceramics showed that the grain sizes of BaTiO3 and Ba0.99Er0.01TiO3 significantly decreased. The dielectric properties of BaTiO3 and Ba0.99Er0.01TiO3 were investigated as a function of temperature and frequency. It revealed that the Curie temperature (TC) increased by doping Er content from 110 °C to 120 °C. Ba0.99Er0.01TiO3 exhibited the high value of dielectric constant (ε=5929) at TC of 120 °C. The capacitance-voltage characteristic revealed that the voltage breakdown for both BaTiO3 and Ba0.99Er0.01TiO3 exceeded 30 V.

Dielectric Properties and Raman Spectroscopy in Ca-Substituted Na0.5Bi0.5TiO3 Ferroelectric Ceramics

2011 ◽  
Vol 324 ◽  
pp. 298-301 ◽  
Author(s):  
Roy Jean Roukos ◽  
Olivier Bidault ◽  
Julien Pansiot ◽  
Ludivine Minier ◽  
Lucien Saviot
Keyword(s):  
Raman Spectroscopy ◽  
Dielectric Properties ◽  
Room Temperature ◽  
Rhombohedral Phase ◽  
Xrd Analysis ◽  
Solid State Reaction Method ◽  
Ferroelectric Ceramics ◽  
Dielectric Measurements ◽  
X Ray Diffraction ◽  
X Ray

Lead free Na0.5Bi0.5TiO3 (NBT) and (Na0.5Bi0.5TiO3)1-x(CaTiO3)x (NBT-CT) piezoelectric ceramics with the perovskite structure were studied. The NBT and NBT-CT samples were synthesized using a solid-state reaction method and characterized with X-ray diffraction (XRD), Raman spectroscopy and dielectric measurements for several compositions (x = 0, 0.07, 0.15) at room temperature. The XRD analysis showed a stabilization of a rhombohedral phase at a low concentration of Ca (0 < x <0.15), whereas Raman spectra reveal a strong modification for the sample with x = 0.15. The dielectric properties of these ceramics were studied by measuring impedance in the 79-451K temperature range for unpoled and field cooling with an electric field (FC) conditions.

Structural and Electrical Properties of Colossal Magnetoresistive LSMO Thin Films Prepared by KrF Laser Ablation Method

2001 ◽  
Vol 666 ◽  
Author(s):  
Fumiaki Mitsugi ◽  
Tomoaki Ikegami ◽  
Kenji Ebihara ◽  
Jagdish Narayan ◽  
Alexander M. Grishin
Keyword(s):  
Thin Films ◽  
Laser Ablation ◽  
Electrical Properties ◽  
Lattice Mismatch ◽  
X Ray Diffraction ◽  
Axis Orientation ◽  
X Ray ◽  
Colossal Magnetoresistive ◽  
Laser Ablation Method ◽  
Structural And Electrical Properties

ABSTRACTWe prepared colossal magnetoresistive La0.8Sr0.2MnO3 thin films on the MgO, SrTiO3 and LaAlO3 single crystal substrates using KrF excimer pulsed laser ablation technique. The structural and electrical properties of the La0.8Sr0.2MnO3 thin films which were strained by the lattice mismatch are reported. The in-plane lattice mismatch between the La0.8Sr0.2MnO3 and MgO, SrTiO3 and LaAlO3 substrates are -7.8 %, -0.5 % and +2.3 %, respectively. The X-ray diffraction spectra of the films exhibited c-axis orientation. In the case of the La0.8Sr0.2MnO3 / LaAlO3 thin films with thickness over 100 nm, the divided (00l) peaks were observed. The surface morphology and transport property of the strongly stressed La0.8Sr0.2MnO3 / LaAlO3 were different from those of La0.8Sr0.2MnO3 / MgO and La0.8Sr0.2MnO3 / SrTiO3thin films.

Structural and electrical properties of Cu-doped Ni–Zn nanocrystalline ferrites for MLCI applications

2017 ◽  
Vol 31 (33) ◽  
pp. 1750318 ◽  
Author(s):  
D. Venkatesh ◽  
K. V. Ramesh
Keyword(s):  
Electrical Properties ◽  
Cation Distribution ◽  
Tetrahedral Site ◽  
Lattice Parameter ◽  
X Ray Diffraction ◽  
Sem Images ◽  
X Ray ◽  
Structural And Electrical Properties ◽  
Phase Spinel ◽  
Diffraction Patterns

Polycrystalline Cu substituted Ni–Zn ferrites with chemical composition Ni[Formula: see text]Zn[Formula: see text]-Cu[Formula: see text]Fe2O4 (x = 0.00 to 0.25 in steps of 0.05) have been prepared by citrate gel autocombustion method. The samples for electrical properties have been sintered at 900[Formula: see text]C for 4 h. The X-ray diffraction patterns of all samples indicate the formation of single phase spinel cubic structure. The value of lattice parameter is decreases with increasing Cu concentration. The estimated cation distribution can be derived from X-ray diffraction intensity calculations and IR spectra. The tetrahedral and octahedral bond lengths, bond angles, cation–cation and cation–anion distances were calculated by using experimental lattice parameter and oxygen positional parameters. It is observed that Cu ions are distributed in octahedral site and subsequently Ni and Fe ions in tetrahedral site. The grain size of all samples has been calculated by Scanning Electron Microscopy (SEM) images. The variations in DC electrical resistivity and dielectric constant have been explained on the basis of proposed cation distribution.

Temperature Dependence on Dielectric Response of La0.7Ba0.3Mn0.4Ti0.6O3 Ceramic

2015 ◽  
Vol 1107 ◽  
pp. 45-52
Author(s):  
Aaliyawani Ezzerin Sinin ◽  
Walter Charles Primus ◽  
Abdul Halim Shaari ◽  
Zainal Abidin Talib ◽  
Sinin Hamdan
Keyword(s):  
Dielectric Properties ◽  
Temperature Dependence ◽  
Low Frequency ◽  
Sintered Sample ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Conventional Solid State Reaction ◽  
Low Frequencies ◽  
X Ray ◽  
Lcr Meter

Ceramic sample of La0.70Ba0.30Mn0.40Ti0.60O3 oxide has been prepared by the conventional solid-state reaction method. The sintered sample was characterized by using x-ray diffraction (XRD) and low frequency LCR meter. XRD result shows that the sample has a cubic structure with the existence of impurity phase. The dielectric properties of La0.70Ba0.30Mn0.40Ti0.60O3 measured from room temperature to 200°C shows that the dielectric permittivity is temperature dependence with strong dispersion at low frequencies. A circuit model based on the universal capacitor response function is also being used to represent the dielectric properties of the sample.

MULTIFERROIC MATERIALS Bi1-xSmxFeO3: A STUDY OF RAMAN AND ABSORPTION SPECTROSCOPIES

2010 ◽  
Vol 19 (02) ◽  
pp. 247-254 ◽  
Author(s):  
NGUYEN VAN MINH ◽  
DAO VIET THANG
Keyword(s):  
Lattice Dynamics ◽  
Optical Band Gap ◽  
Solid State Reaction Method ◽  
Diffraction Measurement ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
Conventional Solid State Reaction ◽  
X Ray ◽  
Lattice Constants ◽  
Raman Measurement

Multiferroic Bi 1-x Sm x FeO 3(x = 0.00, 0.05, 0.1, 0.15, 0.2) ceramics were prepared by conventional solid state reaction method. X-ray diffraction measurement was carried out to characterize the crystal structure and to detect the impurities existing in these ceramics. The substitution of rare earth Sm for Bi was found to decrease the impurity phase in BiFeO 3 ceramics. There is strong evidence that both lattice constants a and c of the unit cell become smaller as the Sm 3+ content is increased. The effect of introducing Sm 3+ is shown to decrease the optical band gap for doped sample Bi 1-x Sm x FeO 3. Additionally, the temperature-dependent Raman measurement performed for the lattice dynamics study of Bi 1-x Sm x FeO 3 samples reveals a strong band centered at around 1000–1300 cm-1 which is associated with the resonant enhancement of two-phonon Raman scattering in the multiferroic Bi 1-x Sm x FeO 3 samples. This two-phonon signal is shown to broaden with increasing x. The Raman spectra at low wavenumbers are suggested to be related with magnon in this system.

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