scholarly journals Mathematical Model of Carbon Dioxide Injection into a Porous Reservoir Saturated with Methane and Its Gas Hydrate

Energies ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 440 ◽  
Author(s):  
Marat K. Khasanov ◽  
Guzal R. Rafikova ◽  
Nail G. Musakaev

In this paper, the process of methane replacement in gas hydrate with carbon dioxide during CO2 injection into a porous medium is studied. A model that takes into account both the heat and mass transfer in a porous medium and the diffusion kinetics of the replacement process is constructed. The influences of the diffusion coefficient, the permeability and extent of a reservoir on the time of full gas replacement in the hydrate are analyzed. It was established that at high values of the diffusion coefficient in hydrate, low values of the reservoir permeability, and with the growth of the reservoir length, the process of the CH4-CO2 replacement in CH4 hydrate will take place in the frontal regime and be limited, generally, by the filtration mass transfer. Otherwise, the replacement will limited by the diffusion of gas in the hydrate.

SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.


2021 ◽  
Vol 230 ◽  
pp. 01011
Author(s):  
Serhii Matkivskyi ◽  
Oleksandr Kondrat ◽  
Oleksandr Burachok

The development of gas condensate fields under the conditions of elastic water drive is characterized by uneven movement of the gas-water. Factors of hydrocarbon recovery from producing reservoirs which are characterized by the active water pressure drive on the average make up 50-60%. To increase the efficiency of fields development, which are characterized by an elastic water drive, a study of the effect of different volumes of carbon dioxide injection at the gas-water contact on the activity of the water pressure system and the process of flooding producing wells was carried out. Using a three-dimensional model, the injection of carbon dioxide into wells located at the boundary of gas-water contact with flow rates from 20 to 500 thousand m3/day was investigated. Analyzing the simulation data, it was found that increasing the volume of carbon dioxide injection provides an increase in accumulated gas production and a significant reduction in water production. The main effect of the introduction of this technology is achieved by increasing the rate of carbon dioxide injection to 300 thousand m3/day. The set injection rates allowed us to increase gas production by 67% and reduce water production by 83.9% compared to the corresponding indicators without injection of carbon dioxide. Taking into account above- mentioned, the final decision on the introduction of carbon dioxide injection technology and optimal technological parameters of producing and injection wells operation should be made on the basis of a comprehensive technical and economic analysis using modern methods of the hydrodynamic modeling of reservoir systems.


2021 ◽  
Author(s):  
Mark Trupp ◽  
Scott Ryan ◽  
Ishtar Barranco Mendoza ◽  
Daniel Leon ◽  
Leigh Scoby-Smith

Author(s):  
Gubaidullin A. A. ◽  
Musakaev N. G. ◽  
Duong Ngoc Hai ◽  
Borodin S. L. ◽  
Nguyen Quang Thai ◽  
...  

In this work the mathematical model is constructed and the features of the injection of warm carbon dioxide (with the temperature higher than the initial reservoir temperature) into the porous reservoir initially saturated with methane gas and water are investigated. Self-similar solutions of the one-dimensional problem describing the distributions of the main parameters in the reservoir are constructed. The effect of the parameters of the injected carbon dioxide and the reservoir on the intensity of the CO2 hydrate formation is analyzed


2021 ◽  
Vol 43 (4) ◽  
pp. 467-475
Author(s):  
A. I. Shayakhmetov ◽  
V. L. Malyshev ◽  
E. F. Moiseeva ◽  
A. I. Ponomarev ◽  
Yu. V. Zeigman

The purpose of this work is to study the effect of carbon dioxide oil solubility on the aggregation of asphaltene associates and decrease of oil permeability of sandstones. Consideration is given to the interaction variants of oil and carbon dioxide in a free volume before being injected into a porous medium and immediately in the porous medium. The influence of oil composition on the aggregation of asphaltene associates is studied. The effect of the dissolved carbon dioxide on associate dispersion in oil is examined through oil filtering in sandstones. If asphaltene aggregation occurs in a porous medium it causes pore plugging leading to reduced permeability, complicates the development of carbon dioxide injection wells and, as a result, prevents from achieving the planned indicators of oil production and oil recovery. It is found that in the case when oil interacts with carbon dioxide in the free volume before being injected into a porous medium, the increase in the volume of filtered oil and the concentration of carbon dioxide dissolved in oil, and decrease in sandstone permeability reduce the relative mobility of oil with the dissolved carbon dioxide. The significant influence of sandstone permeability on the experimental results indicates that the sizes of asphaltene aggregates are comparable to the sizes of small pores. We have not observed complete attenuation of filtration after passing of oil with dissolved carbon dioxide through sandstones. Based on the analysis of changes in oil composition and properties carried out in the laboratory experiments on oil displacement by carbon dioxide rims, it has been determined that aggregation of asphaltene associates takes place under immediate contact of oil and carbon dioxide in a porous medium. The higher the asphaltene content in oil, the lower the formation permeability, whereas tight formations feature a more significant decrease in permeability.


Author(s):  
R.A . Virts

The paper considers a two-dimensional mathematical model of filtration of a viscous incompressible liquid or gas in a porous medium. A unique feature of the model under consideration is the incorporation of poroelastic properties of the solid skeleton. From a mathematical point of view, the equations of mass conservation for liquid / gaseous and solid phases, Darcy's law, the rheological ratio for a porous medium, and the conservation law of the balance of forces are considered. The work is aimed at numerical study of the model initial-boundary value problem of carbon dioxide injection into the rock with minimum initial porosity. Also, it is necessary to find out the parameters at which the porosity will increase in the upper layers of the rock and, as a result, the gas will come to the surface. Section 1 contains a statement of the problem and a brief review of scientific papers related to this topic. In Section 2, the original system of constitutive equations is transformed. In the case of slow flows, when the convective term can be neglected, a system arises that consists of a second-order parabolic equation for the effective pressure of the medium and a first-order equation for porosity. Section 3 presents the results and conclusions of a numerical study of the initial-boundary value problem.


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