scholarly journals Viscosity and Rheological Properties of Graphene Nanopowders Nanofluids

Entropy ◽  
2021 ◽  
Vol 23 (8) ◽  
pp. 979
Author(s):  
Abderrahim Bakak ◽  
Mohamed Lotfi ◽  
Rodolphe Heyd ◽  
Amine Ammar ◽  
Abdelaziz Koumina
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Dynamic Viscosity ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Heat Extraction ◽  
Rheological Characterization ◽  
Shear Rates ◽  
Rheological Measurements

The dynamic viscosity and rheological properties of two different non-aqueous graphene nano-plates-based nanofluids are experimentally investigated in this paper, focusing on the effects of solid volume fraction and shear rate. For each nanofluid, four solid volume fractions have been considered ranging from 0.1% to 1%. The rheological characterization of the suspensions was performed at 20 ∘C, with shear rates ranging from 10−1s−1 to 103s−1, using a cone-plate rheometer. The Carreau–Yasuda model has been successfully applied to fit most of the rheological measurements. Although it is very common to observe an increase of the viscosity with the solid volume fraction, we still found here that the addition of nanoparticles produces lubrication effects in some cases. Such a result could be very helpful in the domain of heat extraction applications. The dependence of dynamic viscosity with graphene volume fraction was analyzed using the model of Vallejo et al.

Rheological Properties of Copper-Graphite MIM Feedstocks Prepared with Waste PET Binder

2014 ◽  
Vol 660 ◽  
pp. 209-213 ◽  
Author(s):  
Mohammad Fadhil Mat Nor ◽  
Safian Sharif ◽  
Khairur Rijal Jamaludin
Keyword(s):  
Shear Rate ◽  
Injection Molding ◽  
Rheological Properties ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Metal Injection Molding ◽  
Injection Molding Process ◽  
Binder System ◽  
Molding Process ◽  
Capillary Rheometry

In this study, waste polyethylene terephthalate (PET) polymer binder systems were used to prepare copper-graphite metal injection molding (MIM) feedstock. A mixer and screw extrusion were used to achieve optimized feedstock, and the rheological properties of the resulting fluids were evaluated using a capillary rheometry to simulate the injection molding process. The solid loadings in the copper-graphite mixes were investigated in the ranges of 51-53% using PET binder system. The effects of shear rate (γ), solid volume fraction (φ) and temperature (T) on the rheological behavior of the copper/graphite MIM feedstocks are discussed.High viscosity trend was notably recorded as shear rate increased relatively. The results indicated that this feedstock system shows dilatant characteristic and lots of further work shall be conducted in attempt to establish this as an ideal binder system.

scholarly journals Rheological properties of traditional balsamic vinegar: New insights and markers for objective and perceived quality

2017 ◽  
Vol 6 (1) ◽  
Author(s):  
Pasquale M. Falcone ◽  
Elisa Sabatinelli ◽  
Federico Lemmetti ◽  
Paolo Giudici
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Dynamic Viscosity ◽  
Flow Instability ◽  
Relaxation Times ◽  
Sensory Properties ◽  
Flow Behaviour ◽  
Shear Rates ◽  
Wide Range ◽  
Balsamic Vinegar

The molecular structure of Traditional Balsamic Vinegar (TBV) undergoes shear-induced and time-dependent jamming transitions due to the high solute concentration and self-assembling phenomena of high molecular size melanoidins with very-long relaxation times (12 years at least or more than 25). The purpose of this work was to perform a descriptive and quantitativeevaluation of relationships between rheological properties, vinegar composition, and perceptual assessment of sensory properties according to the official sensory procedure. With this aim, vinegars having quality traits matching legal requirements for the PDO designation were analyzed for their reducing sugars (glucose and fructose), volatile acidity, fixed acidity, pH, Brix degree, and density as well as for their flow behaviour and dynamic viscosity over a wide range of shear rates. Results showed that flow behaviour of TBV was affected by jamming properties over wide-scale ranges of shear rate producing flow instability below a shear rate of 60s-1. Homogeneous, continuous flow was found at medium-high shear rates with thickening and/or thinning traits. A common onset for the structure scaling was mathematically estimated to occur close to when the density was 1.32 gmL-1. Comparative analysis of rheological, compositional and sensory properties suggested that the colloidal jamming of the vinegar melanoidins dominated the total olfactive and gustative stimuli, and determined the classification of the vinegars that had a higher dynamic viscosity but more homogeneous flow as being of the highest commercial quality category. A robust statistical model was proposed encoding for the top-down decision-making process for quality assignment according to the official sensory procedure, using composition and flow properties as predictor variables. 

scholarly journals Macroscopic rheology of non-Brownian suspensions at high shear rates: the influence of solid volume fraction and non-Newtonian behaviour of the liquid phase

2021 ◽  
Author(s):  
Patrick Wilms ◽  
Jörg Hinrichs ◽  
Reinhard Kohlus
Keyword(s):  
Liquid Phase ◽  
Shear Rate ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Shear Thinning ◽  
High Shear ◽  
Rate Dependency ◽  
Shear Rates ◽  
Liquid Phases ◽  
High Shear Rates

AbstractModelling the macroscopic rheology of non-Brownian suspensions is complicated by the non-linear behaviour that originates from the interaction between solid particles and the liquid phase. In this contribution, a model is presented that describes suspension rheology as a function of solid volume fraction and shear rate dependency of both the liquid phase, as well as the suspension as a whole. It is experimentally validated using rotational rheometry ($$\varphi$$ φ ≤ 0.40) and capillary rheometry (0.55 ≤ $$\varphi$$ φ  ≤ 0.60) at shear rates > 50 s−1. A modified Krieger-Dougherty relation was used to describe the influence of solid volume fraction on the consistency coefficient, $$K$$ K , and was fitted to suspensions with a shear thinning liquid phase, i.e. having a flow index, $$n$$ n , of 0.50. With the calculated fit parameters, it was possible to predict the consistency coefficients of suspensions with a large variation in the shear rate dependency of the liquid phase ($$n$$ n = 0.20–1.00). With increasing solid volume fraction, the flow indices of the suspensions were found to decrease for Newtonian and mildly shear thinning liquid phases ($$n$$ n ≥0.50), whereas they were found to increase for strongly shear thinning liquid phases ($$n$$ n ≤0.27). It is hypothesized that this is related to interparticle friction and the relative contribution of friction forces to the viscosity of the suspension. The proposed model is a step towards the prediction of the flow curves of concentrated suspensions with non-Newtonian liquid phases at high shear rates.

Guidelines for rheological characterization of polyamide melts (IUPAC Technical Report)

2009 ◽  
Vol 81 (2) ◽  
pp. 339-349 ◽  
Author(s):  
Dick J. Dijkstra
Keyword(s):  
Rheological Properties ◽  
Preparation Method ◽  
Polyamide 6 ◽  
Temperature History ◽  
Rheological Characterization ◽  
Rheological Measurements ◽  
Industrial Organizations ◽  
Technical Report ◽  
Commercial Polymers

Most producers of polyamide have their own characterization method to study the rheological properties of polyamide 6 (PA6). However, the measured rheological properties depend strongly on the sample preparation method, humidity regulation, and time-temperature history during the measurement and not least on the kind of rheometer being used. This investigation is the result of an IUPAC project initiated by the Subcommittee on Structure and Properties of Commercial Polymers. Members of several industrial organizations, universities, and institutes cooperated, with the aim of formulating a guideline to measure reproducible rheological properties of PA6. The results of the investigation show the changes in molecular weight during different kinds of rheological measurements due to hydrolysis and amidization reactions. A guideline is introduced which can be used to make comparable rheological measurements on PA6.

Design and Characterization of a MEMS-Microfluidic Sensor for Rheological Applications

2009 ◽  
Vol 74 ◽  
pp. 81-84 ◽  
Author(s):  
H. Berthet ◽  
H. Stone ◽  
F. Marty ◽  
B. Mercier ◽  
J. Jundt ◽  
...  
Keyword(s):  
Shear Rate ◽  
Complex Fluids ◽  
High Shear Rate ◽  
Capillary Viscometer ◽  
High Shear ◽  
Flow Sensors ◽  
Shear Rates ◽  
Rheological Measurements ◽  
Very High

We present our efforts to design, manufacture, and characterize a capillary viscometer aimed at performing very high shear rate rheology of complex fluids, and fabricated using hybrid MEMS/microfluidic technology. We demonstrate that microfluidic and MEMS technologies can be combined to integrate fluidic channels with microfabricated stress and flow sensors, enabling rheological measurements at shear rates up to 500000s-1 and beyond.

scholarly journals Quantification of shear viscosity and wall slip velocity of highly concentrated suspensions with non-Newtonian matrices in pressure driven flows

2021 ◽  
Author(s):  
Patrick Wilms ◽  
Jan Wieringa ◽  
Theo Blijdenstein ◽  
Kees van Malssen ◽  
Reinhard Kohlus
Keyword(s):  
Shear Stress ◽  
Liquid Phase ◽  
Shear Rate ◽  
Shear Viscosity ◽  
Slip Velocity ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Wall Slip ◽  
Flow Index ◽  
Concentrated Suspensions

AbstractThe rheological characterization of concentrated suspensions is complicated by the heterogeneous nature of their flow. In this contribution, the shear viscosity and wall slip velocity are quantified for highly concentrated suspensions (solid volume fractions of 0.55–0.60, D4,3 ~ 5 µm). The shear viscosity was determined using a high-pressure capillary rheometer equipped with a 3D-printed die that has a grooved surface of the internal flow channel. The wall slip velocity was then calculated from the difference between the apparent shear rates through a rough and smooth die, at identical wall shear stress. The influence of liquid phase rheology on the wall slip velocity was investigated by using different thickeners, resulting in different degrees of shear rate dependency, i.e. the flow indices varied between 0.20 and 1.00. The wall slip velocity scaled with the flow index of the liquid phase at a solid volume fraction of 0.60 and showed increasingly large deviations with decreasing solid volume fraction. It is hypothesized that these deviations are related to shear-induced migration of solids and macromolecules due to the large shear stress and shear rate gradients.

Dispersion of solids in fracturing flows of yield stress fluids

2017 ◽  
Vol 830 ◽  
pp. 93-137 ◽  
Author(s):  
S. Hormozi ◽  
I. A. Frigaard
Keyword(s):  
Yield Stress ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Three Dimensional ◽  
Process Variations ◽  
Model Framework ◽  
Shear Rates ◽  
Low Viscosity ◽  
High Shear Rates ◽  
Solids Concentration

Solids dispersion is an important part of hydraulic fracturing, both in helping to understand phenomena such as tip screen-out and spreading of the pad, and in new process variations such as cyclic pumping of proppant. Whereas many frac fluids have low viscosity, e.g. slickwater, others transport proppant through increased viscosity. In this context, one method for influencing both dispersion and solids-carrying capacity is to use a yield stress fluid as the frac fluid. We propose a model framework for this scenario and analyse one of the simplifications. A key effect of including a yield stress is to focus high shear rates near the fracture walls. In typical fracturing flows this results in a large variation in shear rates across the fracture. In using shear-thinning viscous frac fluids, flows may vary significantly on the particle scale, from Stokesian behaviour to inertial behaviour across the width of the fracture. Equally, according to the flow rates, Hele-Shaw style models give way at higher Reynolds number to those in which inertia must be considered. We develop a model framework able to include this range of flows, while still representing a significant simplification over fully three-dimensional computations. In relatively straight fractures and for fluids of moderate rheology, this simplifies into a one-dimensional model that predicts the solids concentration along a streamline within the fracture. We use this model to make estimates of the streamwise dispersion in various relevant scenarios. This model framework also predicts the transverse distributions of the solid volume fraction and velocity profiles as well as their evolutions along the flow part.

scholarly journals Use of helical ribbon mixer for measurement of rheological properties of fruit pulps

2013 ◽  
Vol 19 (No. 4) ◽  
pp. 148-153 ◽  
Author(s):  
P. Novotná ◽  
A. Landfeld ◽  
K. Kýhos ◽  
M. Houška ◽  
J. Strohalm
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Flow Behaviour ◽  
Rotational Rheometer ◽  
Shear Rates ◽  
Coaxial Cylinders ◽  
Helical Ribbon ◽  
Flow Behaviour Index ◽  
Average Shear ◽  
Behaviour Index

Fruit pulps contain fine particles of the flesh of the original fruit that are suspended in the fruit juice. This suspension has a tendency to settling or separation during measurements of its rheological properties in the rotational rheometer with coaxial cylinders (especially if the greater gap is used). In this case the use of a mixer is convenient. The mixer can serve as a tool for measurement of rheological properties and at the same time it can prevent the settling and it is not sensitive to the occurrence of greater particles in the measured fluid. The helical ribbon mixer was used in this work for measurement of five samples of fruit pulp. The mixer was calibrated by the use of Newtonian fluid of known viscosity (honey). The radius of the inner cylinder of hypothetical rotational rheometer was predicted from the assumption that mixer and cylinder exhibit the same torque necessary for the rotation at the same rotational speed. The average shear rate in the mixed pulp was predicted by using the relation valid for power law fluids and rheometer with coaxial cylinders. The radius (where the average shear rate was calculated) was chosen by the requirement that the shear rate would be almost independent of changes in the flow behaviour index valid for measured pulps. Firstly the flow behaviour index was predicted as a slope of torque vs. rotational speed dependence in log-log co-ordinates. It was found that the flow behaviour index varies in the range 0.2–0.3. The radius was predicted from a graph where shear rates for 0.2 and 0.3 are the same. Then the average shear rates were calculated from rotational speeds for individual flow behaviour indexes. Rheological properties measured by using a mixer correspond to those measured with a rotational rheometer with coaxial cylinders satisfactorily only in the case that the creeping flow regime was kept in the mixed fluid. The fruit pulps are strongly non-Newtonian fluids with very low values of the flow behaviour index around 0.2.

scholarly journals Soft channel formation and symmetry breaking in exotic active emulsions

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
L. N. Carenza ◽  
G. Gonnella ◽  
A. Lamura ◽  
D. Marenduzzo ◽  
G. Negro ◽  
...  
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Self Assembly ◽  
Contractile Activity ◽  
Active Material ◽  
Fluid Flows ◽  
Shear Rates ◽  
Two Phases ◽  
The Stability ◽  
Isotropic Fluid

Abstract We use computer simulations to study the morphology and rheological properties of a bidimensional emulsion resulting from a mixture of a passive isotropic fluid and an active contractile polar gel, in the presence of a surfactant that favours the emulsification of the two phases. By varying the intensity of the contractile activity and of an externally imposed shear flow, we find three possible morphologies. For low shear rates, a simple lamellar state is obtained. For intermediate activity and shear rate, an asymmetric state emerges, which is characterized by shear and concentration banding at the polar/isotropic interface. A further increment in the active forcing leads to the self-assembly of a soft channel where an isotropic fluid flows between two layers of active material. We characterize the stability of this state by performing a dynamical test varying the intensity of the active forcing and shear rate. Finally, we address the rheological properties of the system by measuring the effective shear viscosity, finding that this increases as active forcing is increased—so that the fluid thickens with activity.

Rheological Characterization of Body Lotions

2001 ◽  
Vol 11 (2) ◽  
pp. 83-88 ◽  
Author(s):  
Ming Long Yao ◽  
Jayesh C. Patel
Keyword(s):  
Thermal Stability ◽  
Temperature Sensitivity ◽  
Viscoelastic Properties ◽  
Rheological Characterization ◽  
Performance Properties ◽  
Rheological Measurements ◽  
End Use ◽  
And Storage

Abstract This study is attempted to demonstrate the application of rheological measurements in characterization of cosmetics products. As part of this study, several rheological tests were carried out on three common, commercially available body lotions to analyze their complex properties. The tests described in this study were simple and predictive in which the viscoelastic properties were successfully related with the end-use performance properties such as applicability, processing behavior, temperature sensitivity and storage and thermal stability.

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