Entropy Multiparticle Correlation Expansion for a Crystal
Keyword(s):
As first shown by H. S. Green in 1952, the entropy of a classical fluid of identical particles can be written as a sum of many-particle contributions, each of them being a distinctive functional of all spatial distribution functions up to a given order. By revisiting the combinatorial derivation of the entropy formula, we argue that a similar correlation expansion holds for the entropy of a crystalline system. We discuss how one- and two-body entropies scale with the size of the crystal, and provide fresh numerical data to check the expectation, grounded in theoretical arguments, that both entropies are extensive quantities.
2020 ◽
Vol 501
(1)
◽
pp. 994-1001
2019 ◽
Vol 281
◽
pp. 225-235
◽
Keyword(s):
1996 ◽
Vol 251
(3-4)
◽
pp. 157-163
◽
2007 ◽
Vol 13
(6)
◽
pp. 437-447
◽
1964 ◽
Vol 20
(1)
◽
pp. 53-59
◽
2006 ◽
Vol 125
(11)
◽
pp. 114102
◽