scholarly journals Evaluation of the Global S-Entropy Production in Membrane Transport of Aqueous Solutions of Hydrochloric Acid and Ammonia

Entropy ◽  
2020 ◽  
Vol 22 (9) ◽  
pp. 1021
Author(s):  
Kornelia M. Batko ◽  
Andrzej Ślęzak
Keyword(s):  
Membrane Transport ◽  
Concentration Polarization ◽  
Experimental Studies ◽  
Concentration Field ◽  
Membrane System ◽  
Lower Entropy ◽  
Convective State ◽  
Polarization Coefficient ◽  
Production Of Entropy ◽  
Entropy Source

The results of experimental studies of volume osmotic fluxes (Jvkr) and fluxes of dissolved substances (Jkr) in a system containing a synthetic Nephrophan® membrane (Orwo VEB Filmfabrik, Wolfen, Germany) set in a horizontal plane are presented. The membrane separated water and aqueous HCl or ammonia solutions or aqueous ammonia and HCl solutions. It was found that for the homogeneity conditions of the solutions Jvk and Jk depend only on the concentration and composition of the solutions. For concentration polarization conditions (where concentration boundary layers are created on both sides), Jvkr and Jkr depend on both the concentration and composition of the solutions and the configuration of the membrane system. The obtained results of the Jvk and Jk flux studies were used to assess the global production of entropy for the conditions of homogeneity of solutions (ΦSk), while Jvkr and Jkr—to assess the global production of entropy for concentration polarization conditions (ΦSkr). In addition, the diffusion-convective effects and the convection effect in the global source of entropy were calculated. The concentration polarization coefficient ζir was related to modified concentration Rayleigh number, e.g., the parameter controlling the transition from non-convective (diffusive) to convective state. This number acts as a switch between two states of the concentration field: convective (with a higher entropy source value) and non-convective (with a lower entropy source value). The operation of this switch indicates the regulatory role of earthly gravity in relation to membrane transport.

scholarly journals The Role of Gravity in the Evolution of the Concentration Field in the Electrochemical Membrane Cell

Entropy ◽  
2020 ◽  
Vol 22 (6) ◽  
pp. 680 ◽  
Author(s):  
Kornelia M. Batko ◽  
Andrzej Ślęzak ◽  
Wioletta M. Bajdur
Keyword(s):  
Boundary Layers ◽  
Concentration Polarization ◽  
Concentration Field ◽  
Membrane System ◽  
Volume Transport ◽  
Cellulose Acetate Membrane ◽  
Concentration Boundary ◽  
Concentration Boundary Layers ◽  
Mechanical Stirring

The subject of the study was the osmotic volume transport of aqueous CuSO4 and/or ethanol solutions through a selective cellulose acetate membrane (Nephrophan). The effect of concentration of solution components, concentration polarization of solutions and configuration of the membrane system on the value of the volume osmotic flux ( J v i r ) in a single-membrane system in which the polymer membrane located in the horizontal plane was examined. The investigations were carried out under mechanical stirring conditions of the solutions and after it was turned off. Based on the obtained measurement results J v i r , the effects of concentration polarization, convection polarization, asymmetry and amplification of the volume osmotic flux and the thickness of the concentration boundary layers were calculated. Osmotic entropy production was also calculated for solution homogeneity and concentration polarization conditions. Using the thickness of the concentration boundary layers, critical values of the Rayleigh concentration number ( R C r ), i.e., the switch, were estimated between two states: convective (with higher J v i r ) and non-convective (with lower J v i r ). The operation of this switch indicates the regulatory role of earthly gravity in relation to membrane transport.

scholarly journals Testing Sorption Properties of Halloysite by Means of the Laser Interferometry Method

2015 ◽  
Vol 37 (1) ◽  
pp. 43-47
Author(s):  
Sławomir Wąsik ◽  
Michał Arabski ◽  
Karolina Maciejec ◽  
Grażyna Suchanek ◽  
Anna Świercz
Keyword(s):  
Concentration Field ◽  
Laser Interferometry ◽  
Membrane System ◽  
Absorption Capacity ◽  
Sorption Properties ◽  
Concentration Profiles ◽  
Adsorbed Substance ◽  
Interferometry Method ◽  
Set Up ◽  
Kinetics Of

The objective of the present study has been to test the laser interferometry method in terms of its usability for investigating sorption properties of minerals. This method was used to test the absorption capacity of halloysite with reference to glucose, which is often found in industrial wastewater and whose excess can disturb the environmental eco-balance. The sorption capacity of halloysite was thus determined indirectly, basing on the comparison of concentration profiles as well as time characteristics of glucose quantities released from the control solution and from the solution incubated with a halloysite adsorbent. An analysis of glucose diffusion was conducted in a two-chamber membrane system. On the basis of the obtained concentration profiles, the evolution of the concentration field was determined; so were the removal efficiency (%) and the amount of glucose adsorbed at equilibrium (qe, mg/g). The obtained results confirm good sorption properties of halloysite with respect to the investigated substance as well as usability of the method for this kind of investigations. The presented tests suggest that the measurement set-up can be optimised in such as way that visual rendering and testing the kinetics of the adsorbed substance direct release from the studied material become possible.

A review on membrane applications and transport mechanisms in vacuum membrane distillation

2017 ◽  
Vol 34 (1) ◽  
Author(s):  
Rakesh Baghel ◽  
Sushant Upadhyaya ◽  
Kailash Singh ◽  
Satyendra P. Chaurasia ◽  
Akhilendra B. Gupta ◽  
...  
Keyword(s):  
Membrane Fouling ◽  
Membrane Separation ◽  
Critical Evaluation ◽  
Experimental Studies ◽  
Membrane Distillation ◽  
Permeate Flux ◽  
Separation Processes ◽  
Vacuum Membrane Distillation ◽  
Polarization Coefficient ◽  
The Impact

AbstractThe main aim of this article is to provide a state-of-the-art review of the experimental studies on vacuum membrane distillation (VMD) process. An introduction to the history of VMD is carried out along with the other membrane distillation configurations. Recent developments in process, characterization of membrane, module design, transport phenomena, and effect of operating parameters on permeate flux are discussed for VMD in detail. Several heat and mass transfer correlations obtained by various researchers for different VMD modules have been discussed. The impact of membrane fouling with its control in VMD is discussed in detail. In this paper, temperature polarization coefficient and concentration polarization coefficient are elaborated in detail. Integration of VMD with other membrane separation processes/industrial processes have been explained to improve the performance of the system and make it more energy efficient. A critical evaluation of the VMD literature is incorporated throughout this review.

scholarly journals The use of membrane technologies in boiler houses of heat and power enterprises

2019 ◽  
Vol 110 ◽  
pp. 02056
Author(s):  
Elena Kuvardina ◽  
Natalia Semicheva ◽  
Nikolay Kuvardin ◽  
Valery Tolmacheva ◽  
Vasily Amelin
Keyword(s):  
Concentration Polarization ◽  
Membrane Surface ◽  
Experimental Studies ◽  
Low Frequency ◽  
Frequency Range ◽  
Working Process ◽  
Water Stream ◽  
Vibration Effect ◽  
Slowing Down ◽  
Membrane Technologies

The article is about the use of membrane technologies in water treatment cycle for boiler houses which use water of superficial reservoirs for operation. Working process of a flat membrane element is described in the article. Movement scheme of purified water streams is introduced. The layer of undesirable deposits which are slowing down membrane operation is formed on membrane surface during its operation. This formed layer is a result of the arising concentration polarization. Impact of low-frequency fluctuations on saturation water stream is offered to decrease concentration polarization which leads to decline in production of membrane devices. Fluctuations were brought in a stream by means of the vibrator. Steady standing waves are in the membrane device as a result of vibration effect. These waves reduce the formation of undesirable deposits layer on a membrane surface. Results received by mathematical modeling and confirmed by experimental studies state that process productivity of ultrafiltration increased by 30% in frequency range of 60-70 Hz. Frequency range is in standing wave.

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