scholarly journals Entropy Determination of Single-Phase High Entropy Alloys with Different Crystal Structures over a Wide Temperature Range

Entropy ◽  
2018 ◽  
Vol 20 (9) ◽  
pp. 654 ◽  
Author(s):  
Sebastian Haas ◽  
Mike Mosbacher ◽  
Oleg Senkov ◽  
Michael Feuerbacher ◽  
Jens Freudenberger ◽  
...  
Keyword(s):  
Single Phase ◽  
Configurational Entropy ◽  
Solid Solution Phase ◽  
High Entropy Alloys ◽  
Scanning Calorimetry ◽  
High Entropy ◽  
Thermal Entropy ◽  
Fcc Alloys ◽  
Good Agreement

We determined the entropy of high entropy alloys by investigating single-crystalline nickel and five high entropy alloys: two fcc-alloys, two bcc-alloys and one hcp-alloy. Since the configurational entropy of these single-phase alloys differs from alloys using a base element, it is important to quantify the entropy. Using differential scanning calorimetry, cp-measurements are carried out from −170 °C to the materials’ solidus temperatures TS. From these experiments, we determined the thermal entropy and compared it to the configurational entropy for each of the studied alloys. We applied the rule of mixture to predict molar heat capacities of the alloys at room temperature, which were in good agreement with the Dulong-Petit law. The molar heat capacity of the studied alloys was about three times the universal gas constant, hence the thermal entropy was the major contribution to total entropy. The configurational entropy, due to the chemical composition and number of components, contributes less on the absolute scale. Thermal entropy has approximately equal values for all alloys tested by DSC, while the crystal structure shows a small effect in their order. Finally, the contributions of entropy and enthalpy to the Gibbs free energy was calculated and examined and it was found that the stabilization of the solid solution phase in high entropy alloys was mostly caused by increased configurational entropy.

scholarly journals Kinetically Limited Phase Formation of Pt-Ir Based Compositionally Complex Thin Films

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2298
Author(s):  
Aparna Saksena ◽  
Dimitri Bogdanovski ◽  
Hrushikesh Sahasrabuddhe ◽  
Denis Music ◽  
Jochen M. Schneider
Keyword(s):  
Thin Films ◽  
Activation Energy ◽  
Surface Diffusion ◽  
Phase Formation ◽  
Single Phase ◽  
Configurational Entropy ◽  
High Entropy Alloys ◽  
X Ray ◽  
High Entropy ◽  
Two Phases

The phase formation of PtIrCuAuX (X = Ag, Pd) compositionally complex thin films is investigated to critically appraise the criteria employed to predict the formation of high entropy alloys. The formation of a single-phase high entropy alloy is predicted if the following requirements are fulfilled: 12 J∙K−1 mol−1 ≤ configurational entropy ≤ 17.5 J∙K−1 mol−1, −10 kJ∙mol−1 ≤ enthalpy of mixing ≤ 5 kJ∙mol−1 and atomic size difference ≤ 5%. Equiatomic PtIrCuAuX (X = Ag, Pd) fulfill all of these requirements. Based on X-ray diffraction and energy-dispersive X-ray spectroscopy data, near-equiatomic Pt22Ir23Cu18Au18Pd19 thin films form a single-phase solid solution while near-equiatomic Pt22Ir23Cu20Au17Ag18 thin films exhibit the formation of two phases. The latter observation is clearly in conflict with the design rules for high entropy alloys. However, the observed phase formation can be rationalized by considering bond strengths and differences in activation energy barriers for surface diffusion. Integrated crystal orbital Hamilton population values per bond imply a decrease in bond strength for all the interactions when Pd is substituted by Ag in PtIrCuAuX which lowers the surface diffusion activation energy barrier by 35% on average for each constituent. This enables the surface diffusion-mediated formation of two phases, one rich in Au and Ag and a second phase enriched in Pt and Cu. Hence, phase formation in these systems appears to be governed by the complex interplay between energetics and kinetic limitations rather than by configurational entropy.

A review on phase prediction in high entropy alloys

2021 ◽  
pp. 095440622110089
Author(s):  
Vinay Kumar Soni ◽  
S Sanyal ◽  
K Raja Rao ◽  
Sudip K Sinha
Keyword(s):  
Solid Solution ◽  
Phase Formation ◽  
Single Phase ◽  
High Entropy Alloy ◽  
High Entropy Alloys ◽  
Modeling Tools ◽  
High Entropy ◽  
Recent Developments ◽  
Phase Prediction ◽  
The Stability

The formation of single phase solid solution in High Entropy Alloys (HEAs) is essential for the properties of the alloys therefore, numerous approach were proposed by many researchers to predict the stability of single phase solid solution in High Entropy Alloy. The present review examines some of the recent developments while using computational intelligence techniques such as parametric approach, CALPHAD, Machine Learning etc. for prediction of various phase formation in multicomponent high entropy alloys. A detail study of this data-driven approaches pertaining to the understanding of structural and phase formation behaviour of a new class of compositionally complex alloys is done in the present investigation. The advantages and drawbacks of the various computational are also discussed. Finally, this review aims at understanding several computational modeling tools complying the thermodynamic criteria for phase formation of novel HEAs which could possibly deliver superior mechanical properties keeping an aim at advanced engineering applications.

scholarly journals Al, Cu and Zr Addition to High Entropy Alloys: The Effect on Recrystallization Temperature

2018 ◽  
Vol 941 ◽  
pp. 1137-1142
Author(s):  
Elena Colombini ◽  
Andrea Garzoni ◽  
Roberto Giovanardi ◽  
Paolo Veronesi ◽  
Angelo Casagrande
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Single Phase ◽  
Boundary Energy ◽  
Cold Deformation ◽  
Recrystallization Temperature ◽  
High Entropy Alloys ◽  
High Entropy ◽  
Ni Alloy ◽  
Sluggish Diffusion

The equimolar Cr, Mn, Fe, Co and Ni alloy, first produced in 2004, was unexpectedly found to be single-phase. Consequently, a new concept of materials was developed: high entropy alloys (HEA) forming a single solid-solution with a near equiatomic composition of the constituting elements. In this study, an equimolar CoCrFeMnNi HEA was modified by the addition of 5 at% of either Al, Cu or Zr. The cold-rolled alloys were annealed for 30 minutes at high temperature to investigate the recrystallization kinetics. The evolution of the grain boundary and the grain size were investigated, from the as-cast to the recrystallized state. Results show that the recrystallized single phase FCC structures exhibits different twin grains density, grain size and recrystallization temperatures as a function of the at.% of modifier alloying elements added. In comparison to the equimolar CoCrFeMnNi, the addition of modifier elements increases significantly the recrystallization temperature after cold deformation. The sluggish diffusion (typical of HEA alloys), the presence of a solute in solid solution as well as the low twin boundary energy are responsible for the lower driving force for recrystallization.

scholarly journals Single-sided NMR for the measurement of the degree of cross-linking and curing

2018 ◽  
Vol 7 (1) ◽  
pp. 21-30 ◽  
Author(s):  
Norbert Halmen ◽  
Christoph Kugler ◽  
Eduard Kraus ◽  
Benjamin Baudrit ◽  
Thomas Hochrein ◽  
...  
Keyword(s):  
Relaxation Times ◽  
Curing Kinetics ◽  
Cross Linking ◽  
Scanning Calorimetry ◽  
First Results ◽  
Non Destructive ◽  
Kinetics Of ◽  
Good Agreement

Abstract. The degree of cross-linking and curing is one of the most important values concerning the quality of cross-linked polyethylene (PE-X) and the functionality of adhesives and resin-based components. Up to now, the measurement of this property has mostly been time-consuming and usually destructive. Within the shown work the feasibility of single-sided nuclear magnetic resonance (NMR) for the non-destructive determination of the degree of cross-linking and curing as process monitoring was investigated. First results indicate the possibility of distinguishing between PE-X samples with different degrees of cross-linking. The homogeneity of the samples and the curing kinetics of adhesives can also be monitored. The measurements show good agreement with reference tests (wet chemical analysis, differential scanning calorimetry, dielectric analysis). Furthermore, the influence of sample temperature on the characteristic relaxation times can be observed.

scholarly journals Shear localization of fcc high-entropy alloys

2018 ◽  
Vol 183 ◽  
pp. 03028 ◽  
Author(s):  
Marc A. Meyers ◽  
Zezhou Li ◽  
Shiteng Zhao ◽  
Bingfeng Wang ◽  
Yong Liu ◽  
...  
Keyword(s):  
Shear Strain ◽  
Single Phase ◽  
Dynamic Compression ◽  
Impact Resistance ◽  
Shear Localization ◽  
Solid Solution Hardening ◽  
High Entropy Alloys ◽  
High Entropy ◽  
Work Hardening Rate ◽  
High Work

Dynamic behavior of the single phase (fcc) Al0.3CoCrFeNi and CoCrFeMnNi high-entropy alloys (HEAs) was examined. The combination of multiple strengthening mechanisms such as solid solution hardening, cutting forest dislocation, as well as mechanical nano-twinning leads to a high work-hardening rate, compared with conventional alloys. The resistance to shear localization was studied by dynamicallyloading hat-shaped specimens to induce forced shear localization. However, no adiabatic shear band could be observed for Al0.3CoCrFeNi HEA at a large shear strain ~1.1. Additionally, shear localization of the CoCrFeMnNi HEA was only found at an even larger shear strain ~7 under dynamic compression. It is therefore proposed that the combination of the excellent strain-hardening ability and modest thermal softening of these two kinds of high-entropy alloys gives rise to remarkable resistance to shear localization, which makes HEAs excellent candidates for impact resistance applications.

scholarly journals Determination of a methodology for formulating constituent models of high entropy alloys

2019 ◽  
Vol 591 ◽  
pp. 012058
Author(s):  
L C Matache ◽  
T Chereches ◽  
P Lixandru ◽  
A Mazuru ◽  
D Mitrica ◽  
...  
Keyword(s):  
High Entropy Alloys ◽  
High Entropy

scholarly journals Investigation of Clusters and Their Effect on Grain Growth in Single Phase AlxCoCrFeNi High Entropy Alloys

2018 ◽  
Vol 24 (S1) ◽  
pp. 2214-2215
Author(s):  
Bharat Gwalani ◽  
Riyadh Salloom ◽  
Talukder Alam ◽  
Sheena V. Grace ◽  
Srivilliputhur Srinivasan ◽  
...  
Keyword(s):  
Grain Growth ◽  
Single Phase ◽  
High Entropy Alloys ◽  
High Entropy
Sign in / Sign up

Export Citation Format

Share Document