scholarly journals The Fabrication of Calcium Alginate Beads as a Green Sorbent for Selective Recovery of Cu(Ⅱ) from Metal Mixtures

Crystals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 255 ◽  
Author(s):  
Niannian Yang ◽  
Runkai Wang ◽  
Pinhua Rao ◽  
Lili Yan ◽  
Wenqi Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Calcium Alginate ◽  
Selective Adsorption ◽  
Optical Emission ◽  
Alginate Beads ◽  
Emission Spectrometry ◽  
Sorption Behavior

Calcium alginate (CA) beads as a green sorbent were easily fabricated in this study using sodium alginate crosslinking with CaCl2, and the crosslinking pathway was the exchange between the sodium ion of α-L-guluronic acid and Ca(II). The experimental study was conducted on Cu(II), Cd(II), Ni(II) and Zn(II) as the model heavy metals and the concentration was determined by inductively coupled plasma optical emission spectrometry (ICP-OES). The characterization and sorption behavior of the CA beads were analyzed in detail via using scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The adsorption experiments demonstrated that the CA beads exhibited a high removal efficiency for the selective adsorption of Cu(II) from the tetra metallic mixture solution and an excellent adsorption capacity of the heavy metals separately. According to the isotherm studies, the maximum uptake of Cu(II) could reach 107.53 mg/g, which was significantly higher than the other three heavy metal ions in the tetra metallic mixture solution. Additionally, after five cycles of adsorption and desorption, the uptake rate of Cu(II) on CA beads was maintained at 92%. According to the properties mentioned above, this material was assumed to be applied to reduce heavy metal pollution or recover valuable metals from waste water.

scholarly journals Determination of heavy metals and selenium content in chicken liver at Erbil city, Iraq

2020 ◽  
Vol 9 (3) ◽  
Author(s):  
Hoshyar Saadi Ali ◽  
Dhary Alewy Almashhadany ◽  
Hawraz Sami Khalid
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Optical Emission ◽  
Critical Issue ◽  
Chicken Liver ◽  
Poultry Meat ◽  
Emission Spectrometry ◽  
Toxic Heavy Metals

Heavy metal contamination of poultry meat is a critical issue for human health due to associated risks of cytotoxicity and systemic pathologies after ingestion of such metals. A total of twenty chicken liver samples were collected from markets of Erbil city and analyzed for ten heavy metals contents by Inductively Coupled Plasma Optical Emission Spectrometry. The targeted metals were cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), mercury (Hg), zinc (Zn) and selenium (Se). The average concentrations (mg/kg) of targeted trace elements were 0.06±0.027, 0.06±0.05, 2.05±0.34, 1.85±0.47, 0.15±0.17, and 33.53±5.24 for Co, Cr, Cu, Mn, Ni, and Zn respectively. Copper (Cu) levels significantly exceeded the maximum permissible limit of WHO. Moreover, the average concentrations of toxic heavy metals and selenium were 0.07±0.037, 0.278±0.10, 0.11±0.083, and 2.01±0.454 mg/kg for Cd, Pb, Hg, and Se respectively. Hg and Pb levels exceeded the permissible limits of WHO. Higher levels of Cu and Hg in poultry may pose a serious threat to consumers which demand countermeasures and precautions to be taken. Iraqi Standards Authority and relevant official institutions are strongly recommended to regulate safe disposal of heavy metal waste in the environment to reduce animal exposure to such metals.

scholarly journals Concentrations of macronutrients, minerals and heavy metals in home-prepared diets for adult dogs and cats

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Vivian Pedrinelli ◽  
Rafael Vessecchi Amorim Zafalon ◽  
Roberta Bueno Ayres Rodrigues ◽  
Mariana Pamplona Perini ◽  
Renata Maria Consentino Conti ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Pet Owners ◽  
Diet Formulation ◽  
Iron And Zinc ◽  
Plasma Optical Emission Spectrometry

Abstract Pet owners often don’t acknowledge the need for home-prepared diet formulation by a trained professional and may use recipes from sources such as the internet. Macronutrient and mineral composition of home-prepared diets were analyzed and compared to NRC and FEDIAF recommendations, and heavy metal concentrations were analyzed and compared to FDA maximum tolerable levels (MTL) for dogs and cats. Recipes of home-prepared diets for adult dogs (n = 75) and cats (n = 25) were evaluated. Analyses of protein, fat, and fiber were performed according to AOAC, and mineral and heavy metal analyses were performed using inductively coupled plasma optical emission spectrometry (ICP-OES). None of the diets supplied recommended levels of all nutrients evaluated, and more than 84.0% of diets presented three or more nutrients below recommendations. Nutrients with most levels below recommendations were calcium and potassium in recipes for dogs and iron and zinc in recipes for cats. As for heavy metals, levels of lead, cobalt, mercury, uranium, and vanadium were above MTLs. Results suggest that home-prepared diets may be a health risk to dogs and cats if not properly formulated. Furthermore, the chronic heavy metal intake must be better elucidated in order to understand the full impact of results.

scholarly journals Heavy Metal Uptake of Corn Irrigated with Human Urine

2017 ◽  
Vol 6 (1) ◽  
pp. 1
Author(s):  
Horacio Sabejon Factura
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Low Income ◽  
Inductively Coupled Plasma ◽  
Heavy Metal Contamination ◽  
Optical Emission ◽  
Low Income Countries ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Sanitation Systems

<p>Pit latrine (PL) is one of the most common disposal systems for human excreta in low-income countries but because it is a hole in the ground, infiltration of liquid effluent into the soil can continuously occur. Poor sanitation systems permit the spread of heavy metals in urine to water bodies especially the groundwater. This study investigated the accumulation of heavy metals in shoots of corn plants irrigated with urine. A pot experiment with corn was conducted under greenhouse conditions. Urine was diluted to 3:1 ratio (water and urine respectively) and was compared to control (water only). Using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), heavy metals such as Boron, Barium, Cobalt, Copper, Iron, Manganese, Nickel, Silicon, Strontium and Zinc were detected in shoots of all plants with contents ranging from 0.22 to 2,487.44 milligram (mg) per kilogram (kg). The higher amounts detected in urine irrigated plants than the control proved the presence of the metals in the urine. Reuse of urine will definitely benefit farmers while at the same time reduce the risk of heavy metal contamination in groundwater.</p>

scholarly journals Comparison of heavy metal accumulation capacity of some indigenous mosses in Southwest China cities: a case study in Chengdu city

2010 ◽  
Vol 56 (No. 2) ◽  
pp. 60-66 ◽  
Author(s):  
Y.E. Chen ◽  
S. Yuan ◽  
Y.Q. Su ◽  
L. Wang
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Atomic Absorption Spectrophotometry ◽  
Heavy Metal Accumulation ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission Spectrometry ◽  
Accumulation Capacity ◽  
The Difference

In order to evaluate the accumulation capacity of heavy metals in mosses, the total contents of eight elements (Cu, Zn, Fe, Mn, Ni, Pb, Cd, Cr) determined by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Atomic Absorption Spectrophotometry (AAS) methods were compared in four types of indigenous mosses (<i>Brachythecium plumosum, Eurhynchium laxirete, Taxiphyllum taxirameum, Haplocladium strictulum</i>), which were collected from different sampling sites in the Chengdu city, China. The study found that heavy metal concentrations showed significant differences in interspecies and intraspecies comparison, while the accumulation capacity of <i>T. taxirameum</i> was higher than others. ANOVA analysis indicated that the atmospheric pollution of heavy metals in Wangjiang Park was relatively more serious than that of Ta Zishan Park and Cultural Park. The data also showed that the concentrations of heavy metals in the Chengdu city were higher compared to some foreign cities. The results are coincident with the previous conclusions that the difference of heavy metal depositions in mosses was not only related to environment, but also to their biological features.

scholarly journals PHYTOCHEMICAL SCREENING AND HEAVY METAL ANALYSIS OF ULVA RETICULATA

2018 ◽  
Vol 11 (4) ◽  
pp. 84
Author(s):  
Gomathi K ◽  
Anna Sheba L
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Inductively Coupled Plasma ◽  
Tamil Nadu ◽  
Optical Emission ◽  
Phytochemical Analysis ◽  
Icp Oes ◽  
Dissolved Metals ◽  
Metal Analysis ◽  
Heavy Metal Analysis

 Objective: Ulva reticulata is a marine edible green seaweed widely distributed along the coastal lines of India. The present study was designed to screen the phytochemicals and evaluate heavy metals content of U. reticulata collected from Rameshwaram, Tamil Nadu, India, in the perspective of assessing their therapeutic value and/or safety in relation to its uses.Method: The seaweed sample was subjected to extraction with solvents of different polarities (methanol, ethanol, acetone, chloroform, and petroleum ether) and screened for phytochemicals according to standard methods. Heavy metal analysis was also performed with the dried sample powder using inductively coupled plasma optical emission spectrophotometer (ICP-OES).Result: Preliminary phytochemical analysis revealed the presence of reducing sugar, proteins, flavonoids, glycosides, alkaloids, and anthraquinones. ICP-OES indicated the seaweed to contain relative amount of heavy metals in the order of iron (Fe) > chromium (Cr) > Zinc (Zn) > nickel (Ni) > copper (Cu) > lead (Pb) - cadmium (Cd) and is within the permissible limits set by the WHO/FAO, except Fe and Cr.Conclusion: The different solvent extracts of U. reticulata showed the presence of the number of phytochemicals. Furthermore, the present study has revealed the presence of heavy metals in U. reticulata which can be a representative picture of the dissolved metals in the aquatic phase.

scholarly journals Assessing the protective effects of different surface coatings on NaYF4:Yb3+, Er3+ upconverting nanoparticles in buffer and DMEM

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Maysoon I. Saleh ◽  
Bastian Rühle ◽  
Shu Wang ◽  
Jörg Radnik ◽  
Yi You ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Surface Coatings ◽  
Emission Spectrometry ◽  
Dissolution Behavior ◽  
Aqueous Environment ◽  
Protective Effects ◽  
Microporous Silica ◽  
Surface Functionalizations

Abstract We studied the dissolution behavior of β NaYF4:Yb(20%), Er(2%) UCNP of two different sizes in biologically relevant media i.e., water (neutral pH), phosphate buffered saline (PBS), and Dulbecco’s modified Eagle medium (DMEM) at different temperatures and particle concentrations. Special emphasis was dedicated to assess the influence of different surface functionalizations, particularly the potential of mesoporous and microporous silica shells of different thicknesses for UCNP stabilization and protection. Dissolution was quantified electrochemically using a fluoride ion selective electrode (ISE) and by inductively coupled plasma optical emission spectrometry (ICP OES). In addition, dissolution was monitored fluorometrically. These experiments revealed that a thick microporous silica shell drastically decreased dissolution. Our results also underline the critical influence of the chemical composition of the aqueous environment on UCNP dissolution. In DMEM, we observed the formation of a layer of adsorbed molecules on the UCNP surface that protected the UCNP from dissolution and enhanced their fluorescence. Examination of this layer by X-ray photoelectron spectroscopy (XPS) and mass spectrometry (MS) suggested that mainly phenylalanine, lysine, and glucose are adsorbed from DMEM. These findings should be considered in the future for cellular toxicity studies with UCNP and other nanoparticles and the design of new biocompatible surface coatings.

scholarly journals Distribution of Selected Heavy Metals Bioaccumulation in Various Parts of Indigenous Rice (Bokilong, Ponsulak and Taragang) in North Borneo

2020 ◽  
Vol 10 (1) ◽  
pp. 61-69
Author(s):  
Diana Demiyah Mohd Hamdan ◽  
Amirah Syuhada Mohd Azman ◽  
Fazilah Musa ◽  
Mohd Khalizan Sabullah
Keyword(s):  
Heavy Metals ◽  
Inductively Coupled Plasma ◽  
Environmental Influence ◽  
Optical Emission ◽  
Emission Spectrometry ◽  
Local Climate ◽  
Inductively Coupled ◽  
North Borneo ◽  
Plasma Optical Emission Spectrometry ◽  
Element Type

The prospect of three native upland paddy landraces known as Bokilong, Ponsulak and Taragang as heavy metals accumulator for phytoremediation was determined. Bioaccumulation of heavy metals (As, Cd, Cr, Cu, Fe, Pb, and Zn) in various parts of paddy plants collected from Kiulu valley, North Borneo in the natural conditions during the vegetative phase and harvest season were analysed by Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES). All selected heavy metals were traced in soil samples of all three paddy landraces rhizosphere where the most available heavy metals were Fe followed by Zn. Heavy metals bioavailability in soil seemed to be influenced by the local climate of the cultivation field. Bokilong landrace is an accumulator of As, Cd, Cu, Pb and Zn. Ponsulak paddy can help clean up the soil by phytoextraction of As, Cr, Cu, Fe and Zn. Taragang paddy has a prospect in phytoextraction of Cd and Pb to remediate excess amount of this element in the soil. Different heavy metals concentration trends were accumulated in these three paddy landraces in grain indicated different nutritional values. Heavy metal uptake characteristic differs between upland paddy landraces and there was also environmental influence affecting the mobility rate of these elements in paddy plant depending on the element type and paddy genotype.

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