scholarly journals Temperature Stable, High-Quality Factor Li2TiO3-Li4NbO4F Microwave Dielectric Ceramics

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 741
Author(s):  
Shangrui Xu ◽  
Juan Jiang ◽  
Zelai Cheng ◽  
Xiangyi Chen ◽  
Shikuan Sun ◽  
...  

In this work, (1-x)Li2TiO3-xLi4NbO4F ceramics were prepared by the conventional solid-state ceramic route. With the increase of Li4NbO4F content, the phase structure transformed from ordered monoclinic to disordered cubic. By increasing Li3NbO4F content, the temperature coefficient of resonant frequency (τf) was successfully adjusted closer to zero, while the dielectric constant (εr) and microwave quality factor (Qf) decreased to some degree. Outstanding microwave dielectric properties with a εr = 18.7, Qf = 61,388 GHz (6.264 GHz), and τf = 0.9 ppm/°C were obtained for 0.9Li2TiO3-0.1Li4NbO4F ceramics sintered at 1050 °C for 2 h, which indicated that these ceramics are suitable for practical applications in the field of microwave substrates and components.

2017 ◽  
Vol 100 (9) ◽  
pp. 3982-3989 ◽  
Author(s):  
Wen-Bo Li ◽  
Di Zhou ◽  
Li-Xia Pang ◽  
Yan-Zhu Dai ◽  
Ze-Ming Qi ◽  
...  

2020 ◽  
Author(s):  
Hongyang Zhang ◽  
Cheng Liu ◽  
Liang Shi ◽  
Wenwen Wang ◽  
Wenhao Xu ◽  
...  

Abstract Well-densified Li3(Mg1 − xZnx)2SbO6 (0.00 ≤ x ≤ 0.08) microwave dielectric ceramics were synthesized via a two-stage sintering process. The effects of Zn2+ substitution on the microstructure and microwave dielectric properties were investigated. All samples were identified as pure phase via the XRD detection. Remarkable microwave dielectric properties with a near-zero τf value were obtained in the Li3(Mg1 − xZnx)2SbO6 (x = 0.04) sample sintered at 1325 ℃ for 5 h: εr = 7.8, Q × f = 97,719 GHz (13.4 GHz), τf =-6 ppm/℃. The high Q × f value was suggested to relate with the dense morphology and grain size effect. All experimental results indicate that the Li3(Mg1 − xZnx)2SbO6 ceramics are promising for 5G communication applications.


2010 ◽  
Vol 25 (7) ◽  
pp. 1239-1242 ◽  
Author(s):  
Liang Fang ◽  
Chunchun Li ◽  
Xiyang Peng ◽  
Changzheng Hu ◽  
Bolin Wu

Two novel La3+ and Ti4+ cosubstituted Sr3LaNb3O12 ceramics, Sr2La2TiNb2O12 and SrLa3Ti2NbO12, were prepared and the effect of substitution on the microwave dielectric properties was investigated. Results showed that as the amounts of substitution increased, dielectric constant (εr) increased from 36 to 41, and temperature coefficient of resonant frequency (τf) improved from −9 to 3 ppm/°C, whereas the quality factor (Q×f) decreased from 45,000 to 33,600 GHz. A temperature-stable microwave dielectric ceramics SrLa3Ti2NbO12 with τf of 3 ppm/°C, εr of 41, Q×f of 33,600 GHz was obtained; it might be a promising candidate for practical application in base stations if the quality factor is enhanced beyond 40,000 GHz.


2014 ◽  
Vol 32 (2) ◽  
pp. 297-300
Author(s):  
Abdul Manan ◽  
Sami Khan ◽  
Ibrahim Qazi

AbstractCa2Ce2Ti5O16 dielectric ceramics prepared by conventional solid-state ceramic route was investigated. Phase composition and microwave dielectric properties were measured using XRD and Vector network analyzer, respectively. XRD analysis of the calcined and sintered samples revealed the formation of CeO2 and another unidentified phase (that vanished at ≥ 1400 °C) as secondary phases along with the parent Ca2Ce2Ti5O16 phase. The amount of the parent Ca2Ce2Ti5O16 phase increased with increasing sintering temperature from 1350 °C to 1450 °C accompanied by a decrease in the apparent density. The density decreased but ɛr and Qu f o increased with sintering temperature. An er ~ 81.5, Qu fo ~5915 GHz and t f ~ 219 GHz were achieved for the sample sintered at 1450 °C.


2012 ◽  
Vol 2012 (CICMT) ◽  
pp. 000303-000306
Author(s):  
Dhanesh Thomas P. Abhilash ◽  
M. T. Sebastian

The LiZnPO4 ceramic has been prepared by the conventional solid state ceramic route. The ceramic sintered at 825 °C has an εr of 4.9, Qu×f of 65400 GHz, and τf of −80 ppm/°C. The LiZnPO4 ceramic shows low coefficient of thermal expansion (CTE) of 5.3 ppm/°C. The slightly large negative τf of LiZnPO4 has been tuned nearly to zero with TiO2 addition. LiZnPO4-TiO2 composite containing 0.15 volume fraction TiO2 sintered at 925 °C shows good microwave dielectric properties: εr = 7.8, Qu×f = 39800 GHz and τf = −6.8 ppm/°C. LiZnPO4−0.15 Vf TiO2 composite shows a CTE of 6.9 ppm/°C.


Sign in / Sign up

Export Citation Format

Share Document