scholarly journals Effect of Batchelor Flow on Polymorphic Crystallization in a Rotating Disk Crystallizer

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 701
Author(s):  
Zun-Hua Li ◽  
Jinsoo Kim ◽  
Woo-Sik Kim
Keyword(s):  
Phase Transformation ◽  
Cooling Rate ◽  
Induction Time ◽  
Rotation Speed ◽  
Fluid Motion ◽  
Rotating Disk ◽  
Stable Form ◽  
Ethanol Fraction

In this work, the influence of Batchelor flow on the polymorphic crystallization in a rotating disk (RD) crystallizer was investigated. By regulating crystallization parameters, i.e., the rotation speed, cooling rate, and ethanol fraction, we found that a higher fraction of L-histidine stable Form-A at the induction time and a faster rate of phase transformation could be obtained in the RD crystallizer as compared to previous results in a mixing tank crystallizer. Based on these results, we concluded that the polymorphic crystallization in the RD crystallizer was more effective due to Batchelor flow fluid motion.

Numerical Integration of the Navier-Stokes Equations for a Disk Rotating in a Housing

1985 ◽  
Vol 40 (8) ◽  
pp. 789-799 ◽  
Author(s):  
A. F. Borghesani
Keyword(s):  
Boundary Layer ◽  
Cylindrical Cavity ◽  
Boundary Layer Thickness ◽  
Stokes Equations ◽  
Fluid Motion ◽  
Rotating Disk ◽  
Infinite Medium ◽  
Navier Stokes ◽  
Navier Stokes Equations ◽  
Viscous Torque

The Navier-Stokes equations for the fluid motion induced by a disk rotating inside a cylindrical cavity have been integrated for several values of the boundary layer thickness d. The equivalence of such a device to a rotating disk immersed in an infinite medium has been shown in the limit as d → 0. From that solution and taking into account edge effect corrections an equation for the viscous torque acting on the disk has been derived, which depends only on d. Moreover, these results justify the use of a rotating disk to perform accurate viscosity measurements.

Mineral interfacial processes in the method of induced polarization

Geophysics ◽  
1984 ◽  
Vol 49 (7) ◽  
pp. 1105-1114 ◽  
Author(s):  
James D. Klein ◽  
Tom Biegler ◽  
M.D. Horne
Keyword(s):  
Frequency Domain ◽  
Diffusion Layer ◽  
Electrode Potential ◽  
Rotation Speed ◽  
Low Frequency ◽  
Rotating Disk ◽  
Active Species ◽  
Hydrodynamic Theory ◽  
Electrode Polarization ◽  
Disk Electrodes

A phenomenological laboratory investigation has been conducted of the IP response of pyrite, chalcopyrite, and chalcocite. The technique that was used is standard in electrochemistry and employs rotating disk electrodes. The effect of rotation is to stir the electrolyte and thus to restrict the maximum distance available for diffusion of electroactive aqueous species. For high rotation speed and low excitation frequencies, the mean diffusion length exceeds the thickness of the diffusion layer. The net effect is to reduce the electrode impedance at low frequency. The thickness of the diffusion layer and thus the impedance at low frequency can be controlled by the rotation speed. Measurements using rotating disk electrodes have been conducted in both the time domain and the frequency domain. For both pyrite and chalcopyrite, the results were the same: no dependence on rotation was observed. For frequency domain measurements with chalcocite, a strong dependence on rotation was observed. The interpreted diffusion layer thickness was found to depend on rotation speed to the [Formula: see text] power, in agreement with results predicted by hydrodynamic theory. The results of this study imply that there are two physical processes responsible for electrode polarization in the IP method. For chalcocite and perhaps other related copper sulfide minerals, the probable mechanism is diffusion of copper ions in the groundwater. In case, the phenomenon is correctly described by the Warburg impedance. Chalcocite’s distinctive response is thought to be related to its forming a reversible oxidation‐reduction couple with cupric ions in solution. No other common sulfide mineral forms a reversible couple with its cations in solution. For the other minerals of this study, the lack of dependence on rotation implies that diffusion of active species in the electrolyte is not the controlling process. Possible alternate mechanisms include surface controlled processes such as surface diffusion or adsorption phenomena. Ancillary data obtained during this study indicate the interface impedance of chalcopyrite is proportional to the electrode potential which in turn can be controlled by rotation speed, electrolyte composition, or application of an external dc current or voltage. This implies that the surface concentration of active species is dependent on electrode potential.

Continuous Cooling Transformation of Overcooling Austenite and Structure Evolution of Si Steel

2013 ◽  
Vol 652-654 ◽  
pp. 947-951
Author(s):  
Hui Li ◽  
Yun Li Feng ◽  
Da Qiang Cang ◽  
Meng Song
Keyword(s):  
Phase Transformation ◽  
Cooling Rate ◽  
Optical Microscope ◽  
Structure Evolution ◽  
Upward Trend ◽  
Continuous Cooling Transformation ◽  
Continuous Cooling ◽  
Hardness Tester ◽  
Gleeble 3500 ◽  
Evolution Of Microstructure

The static continuous cooling transformation (CCT)curves of 3.15 Si-0.036 C-0.21 Mn-0.008 S-0.008 N-0.022 Al are measured on Gleeble-3500 thermal mechanical simulator, the evolution of microstructure and the tendency of hardness are investigated by optical microscope (OM) and hardness tester. The results show that there is no evident change in microstructure which mainly are ferrite and little pearlite under different cooling rates, but the transition temperature of ferrite is gradually reduced with the increase of cooling rate. When the cooling rate is increased from 0.5°C/s to 20°C/s, the ending temperatures of phase transformation are decreased by 118°C, when cooling rate reaches to 10, Widmanstatten ferrite appears. The hardness of the steel turns out gradual upward trend with the increase of cooling rate.

Nonlinear Resonant Motion of Traveling Waves in Rotating Disks

2000 ◽  
Author(s):  
Albert C. J. Luo ◽  
Chin An Tan
Keyword(s):  
Traveling Waves ◽  
Rotation Speed ◽  
Rotating Disk ◽  
Disk Drive ◽  
Computer Memory ◽  
Rotating Disks ◽  
Resonant Wave ◽  
Linear And Nonlinear ◽  
Resonant Spectrum ◽  
Disk Drive Industry

Abstract The resonant conditions for traveling waves in rotating disks are derived. The nonlinear resonant spectrum of a rotating disk is computed from the resonant conditions. Such a resonant spectrum is useful for the disk drive industry to determine the range of operational rotation speed. The resonant wave motions for linear and nonlinear, rotating disks are simulated numerically for a 3.5-inch diameter computer memory disk.

Study of In-Plane Motions in a Thin Rotating Disk

2000 ◽  
Author(s):  
Moreshwar Deshpande ◽  
C. D. Mote
Keyword(s):  
Critical Speed ◽  
Natural Frequencies ◽  
Rotation Speed ◽  
Rotating Disk ◽  
Travelling Wave ◽  
Linear Strain ◽  
Strain Measure ◽  
Nodal Diameter ◽  
Plane Oscillations ◽  
Disk Energy

Abstract A model for the in-plane oscillations of a thin rotating disk has been derived using a nonlinear strain measure to calculate the disk energy. This accounts for the stiffening of the disk due the radial expansion resulting from its rotation. The corresponding non-dimensionalized natural frequencies are seen to depend only on rotation speed and have been calculated. The radially expanded disk configuration is linearly stable over the range of rotation speeds studied here. The sine and cosine modes for all nodal diameters couple to each other at all nonzero rotation speeds and the strength of this coupling increases with rotation speed. This coupling causes the reported frequencies of the stationary disk to split. The zero, one and two nodal diameter in-plane modes do not have a critical speed corresponding to the vanishing of the backward travelling wave frequency. The use of a linear strain measure in earlier work incorrectly predicts instability of the rotating equilibrium and the existence of critical speeds in these modes.

Stable-Form Screening: Overcoming Trace Impurities That Inhibit Solution-Mediated Phase Transformation to the Stable Polymorph of Sulfamerazine

2008 ◽  
Vol 97 (6) ◽  
pp. 2130-2144 ◽  
Author(s):  
Yuchuan Gong ◽  
Benjamin M. Collman ◽  
Shawn M. Mehrens ◽  
Enxian Lu ◽  
Jonathan M. Miller ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Stable Form ◽  
Trace Impurities ◽  
Stable Polymorph

scholarly journals Effect of hot rolling history and cooling rate on the phase transformation of plain carbon steel

2017 ◽  
Vol 55 (04) ◽  
pp. 229-236
Author(s):  
I. SCHINDLER ◽  
S. RUSZ ◽  
P. OPĚLA ◽  
J. RUSZ ◽  
Z. SOLOWSKI ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Carbon Steel ◽  
Cooling Rate ◽  
Hot Rolling ◽  
Plain Carbon Steel ◽  
Effect Of Hot Rolling

Effect of Cooling Rate on Phase Transformation and Microstructure Evolution in a Large Size Forged Ingot of Medium Carbon Low Alloy Steel

2017 ◽  
pp. 413-423
Author(s):  
Emna Ben Fredj ◽  
Hadi Ghasemi Nanesa ◽  
Davood Shahriari ◽  
Jean-Benoit Morin ◽  
Mohammad Jahazi
Keyword(s):  
Phase Transformation ◽  
Cooling Rate ◽  
Alloy Steel ◽  
Microstructure Evolution ◽  
Low Alloy Steel ◽  
Medium Carbon ◽  
Large Size
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