scholarly journals Rheological Behavior of Warm Mix Asphalt Modified with Foaming Process and Surfactant Additive

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 410
Author(s):  
Guoyang Lu ◽  
Shaowei Zhang ◽  
Shaofeng Xu ◽  
Niya Dong ◽  
Huayang Yu

Surfactants are frequently used to improve the engineering performances of foamed bitumen. Additionally, the foaming process can also perform a significant influence on the foam characteristics and rheological properties of foamed bitumen. However, rare research investigates the synergistic effect of both surfactant and foaming process on the engineering properties of foamed bitumen. To fill the gap, this research investigated the synergistic effect of surfactant and foaming process on the foaming characteristics and rheological properties of foamed bitumen. Based on the experimental results, the synergistic effect shows a significant effect on improving the half-life of foamed bitumen, which reached up to 69 s when 6% foaming Evotherm-DAT content was used. In addition, the foaming temperature also has a significant effect on the foaming characteristics. This study shows that the best foaming conditions can be achieved when the foaming temperature and Evotherm-DAT content are 170 °C and 8%, respectively. Based on the study of synergistic effect, the engineering performances of surfactant foamed bitumen were further characterized in this research, for instance, the enhancement in high-temperature performance and fatigue resistance, and the improvement in workability. Generally, the results of this study have greatly promoted the application of surfactant foam bitumen in the engineering practice.

2016 ◽  
Vol 54 (2) ◽  
pp. 333-357 ◽  
Author(s):  
Ester Laguna-Gutierrez ◽  
Javier Pinto ◽  
Vipin Kumar ◽  
Maria L Rodriguez-Mendez ◽  
Miguel A Rodriguez-Perez

Obtaining high-density polyethylene-based microcellular foams is a topic of interest due to the synergistic properties that can be obtained by the fact of achieving a microcellular structure using a polymer with a high number of interesting properties. However, due to the high crystallinity of this polymer, the production of low-density microcellular foams, by a physical foaming process, is not a simple task. In this work, the proposed solution to produce these materials is based on using crosslinked high-density polyethylenes. By crosslinking the polymer matrix, it is possible to increase the amount of gas available for foaming and also to improve the extensional rheological properties. In addition, the foaming time and the foaming temperature have also been modified with the aim of analyzing and understanding the mechanisms taking place during the foaming process to finally obtain cellular materials with low densities and improved cellular structures. The results indicate that cellular materials with relative densities of 0.37 and with cell sizes of approximately 2 µm can be produced from crosslinked high-density polyethylene using the appropriate crosslinking degree and foaming parameters.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1145
Author(s):  
Wei Li ◽  
Sen Han ◽  
Xiaokang Fu ◽  
Ke Huang

The aims of this paper are to prepare disintegrated high volume crumb rubber asphalt (DHVRA) with low viscosity, good workability and low-temperature performance by adding disintegrating agent (DA) in the preparation process, and to further analyze the disintegrating mechanism and evaluated high-temperature and low-temperature rheological properties. To obtain DHVRA with excellent comprehensive performance, the optimum DA dosage was determined. Based on long-term disintegrating tests and the Fluorescence Microscopy (FM) method, the correlations between key indexes and crumb rubber (CR) particle diameter was analyzed, and the evaluation indicator and disintegrating stage division standard were put forward. Furthermore, Fourier transform infrared spectroscopy (FT-IR) and Gel Permeation Chromatography (GPC) was used to reveal the reaction mechanism, and the contact angle test method was adopted to evaluate the surface free energy (SFE). In addition, the high-temperature and low-temperature rheological properties were measured, and the optimum CR content was proposed. Results indicated that the optimum DA dosage was 7.5‰, and the addition of DA promoted the melt decomposition of CR, reduced the viscosity and improved the storage stability. The 135 °C rotational viscosity (RV) of DHVRA from mixing for 3 h could be reduced to 1.475 Pa·s, and the softening point difference was even less than 2 °C. The linear correlation between 135 °C RV and the diameter of CR particle in rubber asphalt system was as high as 0.968, and the viscosity decay rate (VDR) was used as the standard to divide the disintegrating process into a fast disintegrating stage, stable disintegrating stage and slight disintegrating stage. Compared to common rubber asphalt (CRA), DHVRA has an absorption peak at 960 cm−1 caused by trans olefin = C-H, and higher molecular weight and polar component of surface energy. Compared with CRA, although the high-temperature performance of DHVRA decreases slightly, the low-temperature relaxation ability can be greatly improved.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2585
Author(s):  
Zhelun Li ◽  
Xin Yu ◽  
Yangshi Liang ◽  
Shaopeng Wu

Effective thermal conduction modification in asphalt binders is beneficial to reducing pavement surface temperature and relieving the urban heat island (UHI) effect in the utilization of solar harvesting and snow melting pavements. This study investigated the performance of two nanometer-sized modifiers, graphene (Gr) and carbon nanotubes (CNTs), on enhancing the thermal, physical and rheological properties of asphalt binders. Measurements depending on a transient plant source method proved that both Gr and CNTs linearly increased the thermal conductivity and thermal diffusivity of asphalt binders, and while 5% Gr by volume of matrix asphalt contributed to 300% increments, 5% CNTs increased the two parameters of asphalt binders by nearly 72% at 20 °C. Meanwhile, a series of empirical and rheological properties experiments were conducted. The results demonstrated the temperature susceptibility reduction and high-temperature properties promotion of asphalt binders by adding Gr or CNTs. The variation trends in the anti-cracking properties of asphalt binders modified by Gr and CNTs with the modifier content differed at low temperatures, which may be due to the unique nature of Gr. In conclusion, Gr, whose optimal content is 3% by volume of matrix asphalt, provides superior application potential for solar harvesting and snow melting pavements in comparison to CNTs due to its comprehensive contributions to thermal properties, construction feasibility, high-temperature performance and low-temperature performance of asphalt binders.


2018 ◽  
Vol 225 ◽  
pp. 01006 ◽  
Author(s):  
Dewi Puspitasari ◽  
Fatthie Khairullah Hishyam Rabie ◽  
Turnad Lenggo Ginta ◽  
Jundika Candra Kurnia ◽  
Mazli Mustapha

This study concerns about the influence of foaming temperature which is applied to foaming process of aluminum foam to improve the stability of aluminum foam cell wall. Powder metallurgical method with four major foaming temperatures of 750°C, 800°C, 850°C and 900°C have been selected. Furthermore, the porosity of the foam was determined by ImageJ Analysis Software. Microhardness testing on the cell wall of aluminium foam was conducted according to ASTM E 92 using microhardness tester LM24AT with 200 grams and 15 s for loading time. The universal testing machine was applied to characterize the effect of foaming temperature on compression strength. The aluminum foam was observed in macroscopic and microscopic level using optical microscope (OM). The result revealed that the foaming temperature of 800°C gave the lowest value of porosity, with the highest hardness and compressive strength of 55.29 HV and 1.41 MPa, respectively. In addition, the highest porosity level was acquired by foaming temperature which was set at 900 °C. The lowest hardness value of 38.50 HV was obtained by foaming temperature of 700°C and the minimum compressive strength value of 0.75 MPa was exhibited when the foaming temperature was set at 900°C.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1854 ◽  
Author(s):  
Marek Iwański ◽  
Grzegorz Mazurek ◽  
Przemysław Buczyński

This article discusses the results of bitumen foam properties optimisation with respect to three factors: air pressure, bitumen temperature and amount of water. The test materials were unmodified bitumen 50/70 and bitumen 50/70 modified with 2.5% synthetic wax. The experiment was designed according to the 3(3−1) fractional factorial design. The distribution of parameters of bitumen foam were measured with the authors’ original apparatus using a laser beam. This measurement method increased the accuracy of maximum expansion ratio (ER) and half-life (HL) estimation. Based on HL and ER results, it was found that the foaming process increased bitumen stiffness due to the dynamic ageing of the bitumen. The experimental design allows more effective control over the properties of foamed bitumen with respect to its intended use. The presence of synthetic wax extended the half-life of the bitumen foam.


2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Jiupeng Zhang ◽  
Guoqiang Liu ◽  
Li Xu ◽  
Jianzhong Pei

Sasobit additives with different dosages were added into 70# and 90# virgin asphalt binders to prepare WMA binders. The rheological properties, includingG∗andδ, were measured by using DSR at the temperature ranging from 46°C to 70°C, and the effects of temperature, additive dosage and aging onG∗/sin⁡δ, critical temperature, and H-T PG were investigated. The results indicate that WMA additive improvesG∗but reducesδ, and the improvement on 70# virgin binder is more significant.G∗/sin⁡δexponentially decreases with the increasing temperature but linearly increases with the increasing additive dosage. Aging effect weakens the interaction between binder and additive but significantly increases the binder’s viscosity; that is whyG∗/sin⁡δis higher after short-term aging. In addition, the critical temperature increases with the increasing additive dosage, and the additive dosage should be more than 3% and 5% to improve H-T PG by one grade for 70# and 90# virgin binder, respectively.


2021 ◽  
pp. 026248932110536
Author(s):  
Yun Zhang ◽  
Yadong He ◽  
Chunling Xin ◽  
Yanbin Su

The rare earth nucleating agent was used to modify block copolymerized polypropylene (PPB) in foaming process. The results show that the crystallization of PPB and the melting temperature of β-crystal increased gradually with increased β-crystal nucleating agent content. The total crystallinity decreased with amount of addition increasing, and the relative content of β-crystal increased first and then decreased. When β-crystal nucleating agent content was 0.4 wt%, the relative β-crystal content reached the maximum value of 95.27%, and the final crystal grain refinement significantly. The addition of rare earth β-crystal nucleating agent has a good effect on improving the uniformity of foam cells. Under the same content of β-crystal nucleating agent and pressure, the average cell diameter and expansion ratio increased with the saturation temperature increasing. After the foaming temperature reaches 155°C, the expansion ratio began to decrease, which was also consistent with the changed trend of relative β-crystal content. At the same content of temperature and relative β-crystal, as the foaming pressure increased, the cell diameter decreased gradually, and the expansion ratio increased first, and then decreased.


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