scholarly journals Strengthening and Thermally Activated Processes in an AX61/Saffil Metal Matrix Composite

Crystals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 466
Author(s):  
Zuzanka Trojanová ◽  
Zoltán Száraz ◽  
Pavel Lukáč ◽  
Zdeněk Drozd ◽  
Ján Džugan
Keyword(s):  
Metal Matrix ◽  
Room Temperature ◽  
Load Transfer ◽  
Strengthening Mechanisms ◽  
Thermally Activated ◽  
Squeeze Cast ◽  
Stress Components ◽  
Activated Processes ◽  
Relaxation Curves ◽  
Thermally Activated Process

AX61 magnesium alloy was reinforced with short Saffil fibres using squeeze cast technology. Samples were cut from the casting in two directions: parallel and perpendicular to the fibre plane. Samples were deformed in compression at various temperatures from room temperature to 300 °C. Various strengthening mechanisms such as load transfer, increased dislocation density, Orowan and Hall–Petch strengthening were analysed. During deformation, the stress relaxation tests were subsequently performed. The relaxation curves were evaluated with respect to Li and Feltham equations with the aim to find stress components in matrix and parameters of the thermally activated process(es).

Stress Relaxation in an AZ31 Magnesium Alloy

2011 ◽  
Vol 465 ◽  
pp. 101-104 ◽  
Author(s):  
Pavel Lukáč ◽  
Zuzanka Trojanová
Keyword(s):  
Magnesium Alloy ◽  
Stress Relaxation ◽  
Deformation Temperature ◽  
Room Temperature ◽  
Activation Volume ◽  
Initial Strain Rate ◽  
Az31 Magnesium Alloy ◽  
Thermally Activated ◽  
Relaxation Curves ◽  
Thermally Activated Process

Stress relaxation tests have been used in order to determine parameters of a possible thermally activated process in AZ31 magnesium alloy. The samples were deformed at a constant initial strain rate of 6.7x10-5 s-1 at various temperatures between room temperature and 300 °C. Stress relaxation, i.e. a decrease in the stress with time, was measured at various stress levels and at various temperatures. An analysis of the stress relaxation curves enabled to estimate the internal stress as a function of the strain and the test temperature. It has been shown that the activation volume is a function of the effective stress independently of the deformation temperature.

scholarly journals Strengthening Mechanisms in Carbon Nanotubes Reinforced Metal Matrix Composites: A Review

Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1613
Author(s):  
Íris Carneiro ◽  
Sónia Simões
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Metal Matrix Composites ◽  
Metal Matrix ◽  
Load Transfer ◽  
Second Phase ◽  
Matrix Composites ◽  
Strengthening Mechanisms ◽  
Metal Matrix Nanocomposites ◽  
Main Challenge

Carbon nanotubes (CNTs)-reinforced metal matrix composites are very attractive advanced nanocomposites due to their potential unusual combination of excellent properties. These nanocomposites can be produced by several techniques, the most reported being powder metallurgy, electrochemical routes, and stir or ultrasonic casting. However, the final mechanical properties are often lower than expected. This can be attributed to a lack of understanding concerning the strengthening mechanisms that act to improve the mechanical properties of the metal matrix via the presence of the CNTs. The dispersion of the CNTs is the main challenge in the production of the nanocomposites, and is independent of the production technique used. This review describes the strengthening mechanism that act in CNT-reinforced metal matrix nanocomposites, such as the load transfer, grain refinement or texture strengthening, second phase, and strain hardening. However, other mechanisms can occur, such as solid solution strengthening, and these depend on the metal matrix used to produce the nanocomposites. Different metallic matrices and different production techniques are described to evaluate their influence on the reinforcement of these nanocomposites.

scholarly journals Investigation on the Strengthening Mechanisms of Nickel Matrix Nanocomposites

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1426
Author(s):  
Íris Carneiro ◽  
José Valdemar Fernandes ◽  
Sónia Simões
Keyword(s):  
Grain Refinement ◽  
Metal Matrix ◽  
Load Transfer ◽  
Second Phase ◽  
Strengthening Effect ◽  
Small Contribution ◽  
Strengthening Mechanisms ◽  
Metal Matrix Nanocomposites ◽  
The Matrix ◽  
Matrix Nanocomposites

The strengthening effect of carbon nanotubes (CNTs) in metal matrix nanocomposites occurs due to several mechanisms that act simultaneously. The possible strengthening mechanisms for metal matrix nanocomposites reinforced with CNTs consist of: (1) load transfer, (2) grain refinement and texture strengthening, (3) second phase strengthening, and (4) strain hardening. The main focus of this work is to identify the strengthening mechanisms that play a role in the case of the Ni-CNT nanocomposite produced by powder metallurgy. For the dispersion and mixing of the metallic powders with CNTs, two different routes were performed by ultrasonication and ball milling. The results indicated that four different strengthening mechanisms are present in the nanocomposites and had a different contribution to the final mechanical properties. The load transfer and the increase in dislocation density seem to strongly affect the properties and microstructure of the nanocomposite. The grain refinement and the presence of second phase particles have a small contribution in the strengthening of this nanocomposite, since the introduction of CNTs in the Ni matrix slightly affects the size and orientation of the grains in the matrix and a few nanometric particles of Ni3C were identified.

Mass spectrometric study of allyl radical, allyl bromide and 1,5-hexadiene interactions with oxides; Cobalt suboxide Co3O4

1979 ◽  
Vol 44 (7) ◽  
pp. 2009-2014 ◽  
Author(s):  
Jana Nováková ◽  
Zdeněk Dolejšek
Keyword(s):  
Room Temperature ◽  
Allyl Bromide ◽  
Catalytic Properties ◽  
Mass Spectrometric Study ◽  
Spectrometric Study ◽  
Flow Conditions ◽  
Allyl Radical ◽  
Knudsen Flow ◽  
Thermally Activated ◽  
Radical Interaction

Products of (a) allyl radical interaction with unheated Co3O4, (b) thermally activated 1,5-hexadiene or thermally activated allyl bromide with unheated Co3O4, (c) moderately heated Co3O4 with unheated 1,5-hexadiene or allyl bromide were studied under Knudsen flow conditions. Cobalt suboxide Co3O4, a typical catalyst of deep oxidations yielded acrolein in reaction with allyl radicals as early as at the room temperature of the catalyst. A similar acrolein formation was also observed in the allyl radical interaction with other oxides exhibiting different catalytic properties. It appears that acrolein is in general the primary product of the allyl radical interaction with the oxides. The results are discussed and compared with previous data obtained with MoO3.

Structure and Conductivity of Iodine-Doped C60 Thin Films

1994 ◽  
Vol 359 ◽  
Author(s):  
Jun Chen ◽  
Haiyan Zhang ◽  
Baoqiong Chen ◽  
Shaoqi Peng ◽  
Ning Ke ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Conductivity ◽  
Room Temperature ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
X Ray ◽  
Thermally Activated ◽  
Order Of Magnitude

ABSTRACTWe report here the results of our study on the properties of iodine-doped C60 thin films by IR and optical absorption, X-ray diffraction, and electrical conductivity measurements. The results show that there is no apparent structural change in the iodine-doped samples at room temperature in comparison with that of the undoped films. However, in the electrical conductivity measurements, an increase of more that one order of magnitude in the room temperature conductivity has been observed in the iodine-doped samples. In addition, while the conductivity of the undoped films shows thermally activated temperature dependence, the conductivity of the iodine-doped films was found to be constant over a fairly wide temperature range (from 20°C to 70°C) exhibiting a metallic feature.

Strengthening Evaluation in a Composite Mg-RE Alloy Using TEM

2011 ◽  
Vol 678 ◽  
pp. 75-84 ◽  
Author(s):  
Marcello Cabibbo
Keyword(s):  
Electron Microscopy ◽  
Metal Matrix ◽  
Room Temperature ◽  
Strengthening Mechanism ◽  
Composite Alloy ◽  
Specific Strength ◽  
High Specific Strength ◽  
Transmission Electron ◽  
Sic Ceramic

Magnesium alloys containing rare earth elements are known to have high specific strength and corrosion resistance. The addition of SiC ceramic particles makes the metal matrix composite stronger with better wear and creep resistance and a still good machinability. The role of the reinforcement particles to the enhanced strength can be quantitatively evaluated using transmission electron microscopy (TEM). This paper presents a quantitative strengthening evaluation in a SiC Mg-RE composite alloy. The different contributions were determined by TEM inspections. The microstructure strengthening mechanism was studied after room temperature compression specimens. The way of combining the different contributions and the comparison to the measured yield stress, is also discussed and justified.

Ni-catalyzed cascade coupling reactions: synthesis and thermally-activated delayed fluorescence characterization of quinazolinone derivatives

2021 ◽  
Author(s):  
Zhongyan Chen ◽  
Lepeng Chen ◽  
Shou-Feng Zhang ◽  
Qianqian Zhen ◽  
Wenzhang Xiong ◽  
...  
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Coupling Reactions ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quinazolinone Derivatives

A nickel-catalyzed synthesis of 1,3-diaryl-6H-pyrazino[2,1-b]quinazolin-6-one was developed. This method enabled to access valuable pyrazino-fused quinazolinones with tolerance of many functional groups even at room temperature. The desired pyrazino-fused quinazolinones emit...

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