scholarly journals Rod-Shaped Carbon Aerogel-Assisted CdS Nanocomposite for the Removal of Methylene Blue Dye and Colorless Phenol

Crystals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 300
Author(s):  
Saradh Prasad ◽  
P. Shanmugam ◽  
K. Bhuvaneswari ◽  
G. Palanisamy ◽  
T. Pazhanivel ◽  
...  

A carbon aerogel (CA)-assisted CdS nanocomposite was prepared by hydrothermal process and was investigated as a photocatalyst towards the photodegradation of methylene blue (MB) dye and colorless phenol under visible light irradiation (VLI). CdS have attracted wide attention due to their relatively narrow band gap for the visible light effect and the suitably negative potential of the conduction band (CB) edge for the neutralization of H+ ions. The obtained characterization results suggest that the CA-assisted CdS nanocomposite has enhanced photophysical properties, a more surface area, and the desired morphology at the nm scale. Under optimization, CdS CA 8% shows superior catalytic activity for degradation compared with other samples. The photocatalytic activities of the as-synthesized samples were examined under VLI through the MB and phenol degradation. Compared with pure CA and CdS, the CA (8%)-assisted CdS nanoparticles (NPs) offer significantly enhanced photocatalytic efficiency for MB and phenol. The mechanism of photocatalytic reaction was examined by adding various scavengers, and the results revealed that the holes generated in CA (8%)-assisted CdS NPs have a crucial impact on the visible light photocatalytic process. The improved photocatalytic degradation was due to the strong interaction between the CA and CdS NPs.

2012 ◽  
Vol 234 ◽  
pp. 11-16 ◽  
Author(s):  
Thanh Nam Chau ◽  
Yi Ting Sung ◽  
Bai Bin Wang ◽  
Wein Duo Yang

Titanate nanotubes were synthesized by a solvothermal process at a low temperature in a highly alkaline water-methanol mixed solution. Powders were characterized by XRD, TEM, BET and UV-vis absorption spectroscopy. The as-prepared samples was tested by the adsorptive process and photodegradation reaction of methylene blue (MB) dye under visible-light irradiation. The results indicated that the titanate samples are synthesized in the methanol-water volume ratios of 10:90, 20:80 and 30:70 are still highly absorbability and all the titanate samples as-prepared have higher photocatalytic activities compared with TiO2P25 in the degradation of MB under visible light irradiation.


2020 ◽  
Vol 20 (9) ◽  
pp. 5759-5764
Author(s):  
V. Karthikeyan ◽  
G. Gnanamoorthy ◽  
P. Varun Prasath ◽  
V. Narayanan ◽  
Suresh Sagadevan ◽  
...  

Herein, we report the facile synthesis, characterization and visible-light-driven photocatalytic degradation of perforated curly Zn0.1Ni0.9O nanosheets synthesized by hydrothermal process. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies confirmed the cubic phase crystalline structure and growth of high density perforated curly Zn0.1Ni0.9O nanosheets, respectively. As a photocatalyst, using methylene blue (MB) as model pollutant, the synthesized nanosheets demonstrated a high degradation efficiency of ~76% in 60 min under visible light irradiation. The observed results suggest that the synthesized Zn0.1Ni0.9O nanosheets are attractive photocatalysts for the degradation of toxic organic waste in the water under visible light.


2014 ◽  
Vol 608 ◽  
pp. 224-229 ◽  
Author(s):  
Potjanaporn Chaengchawi ◽  
Karn Serivalsatit ◽  
Pornapa Sujaridworakun

A visible-light responsive CdS/ZnO nanocomposite photocatalyst was successfully synthesized by precipitation of CdS nanoparticles, using Cd (NO3)2 and Na2S as starting materials, on ZnO nanoparticles and then calcined at 400°C for 2 hours. The effects of the mole ratio of CdS and ZnO in the composites on their phase, morphology, and surface area were investigated by X-ray Diffraction (XRD), scanning electron microscope (SEM), Brunauer Emmett Teller method (BET), respectively. The photocatalytic degradation of methylene blue solution in the presence of composite products under visible-light irradiation was investigated. The results showed that the mole ratio of CdS and ZnO played a significant role on photocatalytic performance. The highest photocatalytic activity was obtained from the CdS/ZnO nanocomposite with mole ratio of 1:4, which is higher than that of pure CdS and pure ZnO.


2018 ◽  
Vol 47 (12) ◽  
pp. 4251-4258 ◽  
Author(s):  
Ming Zhang ◽  
Liwen Wang ◽  
Tianyu Zeng ◽  
Qigao Shang ◽  
Hong Zhou ◽  
...  

Two 3D coordination polymers, bridged by 4,4′-bipyridine, were readily synthesized and fully characterized. As efficient photocatalysts in dye degradation under visible light, the mechanism and stability were studied.


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