scholarly journals Predictive Modeling of Corrosion in Al/Mg Dissimilar Joint

2019 ◽  
Vol 3 (3) ◽  
pp. 70 ◽  
Author(s):  
Seyedsaied Ahmadvand ◽  
Mohammadreza Elahifard ◽  
Bijan Peik ◽  
Reza Behjatmanesh-Ardakani ◽  
Behrooz Abbasi ◽  
...  

In the absence of any abnormality (standard conditions), the gradient of any mechanical/thermodynamic stress would be intensified at the dissimilar joint due to an abrupt change in the chemical composition. This paper aims to investigate the effect of delocalizing this stress by imposing an optimum chemical gradient within the dissimilar joint. In this work, we computationally demonstrated that a homogenous distribution of magnesium atoms in the aluminum (100) structure with a specific chemical gradient could potentially reduce the susceptibility of the Mg/Al dissimilar joint towards micro-galvanic corrosion. This is achieved through the minimization of the work function gradient within the dissimilar joint.

Resources ◽  
2019 ◽  
Vol 8 (2) ◽  
pp. 108 ◽  
Author(s):  
Alberto Mannu ◽  
Gina Vlahopoulou ◽  
Paolo Urgeghe ◽  
Monica Ferro ◽  
Alessandra Del Caro ◽  
...  

The chemical composition and the color of samples of waste cooking oils (WCOs) were determined prior to and after filtration on two different pads of bentonite differing in particle size. The volatile fraction was monitored by headspace solid-phase microextraction (HS-SPME) coupled with gas-chromatography, while the variation of the composition of the main components was analyzed by 1H NMR. Both techniques allowed the detection of some decomposition products, such as polymers, terpenes, and derivatives of the Maillard process. The analysis of the chemical composition prior to and after bentonite treatment revealed a tendency for the clays to retain specific chemical groups (such as carboxylic acids or double bonds), independent of their particle size. A pair comparison test was conducted in order to detect the sensory differences of the intensity of aroma between the WCO treated with the two different bentonites. In addition, characterization of the bentonite by means of powder X-ray diffraction (XRD) and thermogravimetric measurements (TG) was performed.


1986 ◽  
Vol 28 (4) ◽  
pp. 536-539 ◽  
Author(s):  
Axel J. J. Dietrich

It is well known that there is a strong influence of fixation, i.e., acetic methanol versus formaldehyde, on the chromosome morphology at stages of the first meiotic division. In this study the influence of both these types of fixation on the morphology of mitotic chromosomes was examined in human lymphocytes. After methanol – acetic acid (3:1) fixation, the chromosomes show the "classical" condensed shape in which it is not always possible to recognize the two sister chromatids. These chromosomes are accessible to the conventional G-, R-, and C-banding techniques. After formaldehyde fixation at a relatively high pH, the chromosomes are thinner and longer (two to six times) when compared with chromosomes following methanol – acetic acid fixation. They show a scaffold-like morphology, sometimes with a halo of thin material around it. In all cases the two sister chromatids could be recognized. This chromosome structure could be easily stained with silver, Giemsa, 4,6-diamino-2-phenyl-indole (DAPI), and fluorescein isocyanate isomere 1 (FITC). The results obtained following these stainings gave no indication to any specific chemical composition of a probable central scaffold. The scaffold-like structures were not accessible to G-, R-, or C-banding techniques. The only effect observed following these banding techniques was the disappearance of the halo of thin material around the central scaffold-like structure.Key words: chromosome structure, fixation influence, human lymphocytes.


Author(s):  
G. A. Kunitsin ◽  
А. А. Pridein ◽  
O. V. Samokhina ◽  
D. V. Nizhel’skii ◽  
E. M. Gitman

At present decreasing of costs and increasing of efficiency are the most priority directions in any industry. Developing in this way, JSC “Ural steel” together with FGUP “CNIIchermet after I.P. Barding” had mastered production of sheet metal product with increased resistivity against atmosphere corrosion made of steel 14ХГНДЦ for construction of bridges. Because of specific chemical composition of the steel, in the process of metal structures running in the open air, a solid strong oxide film is formed on the metal of the structures which prevents further corrosion without painting. For bridge builders elimination of costly operation of painting of span structures will enable to decrease considerably the costs of bridges construction and running. Having many advantages, steel 14ХГНДЦ has some restrictions in applications for steel structures without painting, as follows: - in sea zone according to domestic norms no close than 500 m from coastline; - in case of disorderly conditions of protective film formation and/or application of salt solutions for surface cleaning (as a rule the restrictions refer to traffic area of bridge span). In view of that for JSC “Ural Steel”, as the leading producer of bridge steel in Russia, an actual task erose: to elaborate and create a weatherproof steel, which could not only operate the whole period of a bridge running without additional protection at bridges con­struction through sea areas or close to coastline, but also withstand severe climate conditions of our country, including areas of High North with temperature lower -50°С. To solve the task together with OJSC “Institute Giprostroymost” and JSC BNIIZhT, a research work was accomplished to elaborate a system of alloying new steel 06ГН3МД with nickel content ~3.0 %, as well as production modes ensuring required corrosion resistance for operation in sea zone. Results of laboratory studies of the new weatherproof steel 06ГН3МД for application in bridge  structures for coastal conditions and sea areas presented. Results of mechanical, technological, corrosion as well as fatigue tests of rolling products of the elaborated steel presented. It was established by laboratory studies that the new steel is weatherproofed and ensures lower corrosion losses, higher impact toughness at negative temperatures and plasticity comparing with steels used at present. It was shown that the strength class, technology and modes of factory welding of steel 06ГН3МД meet the  requirements to steel span structures of bridges. Base on the results of the studies, the chemical composition of the steel 06ГН3МД was specified, as well as modes of heat treatment, ensuring the required characteristics with significant acceding. It was established that samples of the new steel 06ГН3МД showed considerably higher corrosion resistance - in average by 20% comparing with steel 14ХГНДЦ. At that corrosion resistance tests of welded joints of the new steel showed even higher resistance of the seam comparing with the basic metal, which speaks about quality selection of welding modes and welding materials.


Author(s):  
K. L. Levine ◽  
D. V. Ryabokon ◽  
S. D. Khanin ◽  
R. V. Gelamo ◽  
N. A. Nikonorova

The paper studies multilayer graphenes in the form of free-standing films. The authors provide data about the morphology and electrical properties of films treated with plasma of various chemical composition. It is shown that it is possible to control the electrical properties of the surface and electron work function without significantly affecting its morphology. The obtained samples, combining mechanical flexibility with unreactiveness and high electrical conductivity, are promising for application in flexible charge storage devices.


2018 ◽  
Vol 45 (12) ◽  
pp. 1073-1083 ◽  
Author(s):  
Hamideh Mehdizadeh ◽  
Ebrahim Najafi Kani

In this study, a statistical experimental design based on response surface methodology (RSM) has been applied to predict and optimize the compressive strength of alkali-activated phosphorus slag in different ages (3, 7, and 28 days). For this purpose, the binder samples were prepared with different molar ratios of SiO2/Na2O (S/N), Na2O/Al2O3(Na/Al), and H2O/Al2O3(H/Al) as alkali activator. Results showed that S/N molar ratio plays its role in early ages of curing and Na/Al molar ratio, and showed its significant effect on 7 and 28 days of compressive strength. H/Al molar ratio had the most significant effect on compressive strength compared to the other parameters. The derived RSM models were statistically adequate and could be used to predict the compressive strength. The optimum chemical composition of activator to obtain the highest compressive strength was achieved as 0.39, 1.34, and 30 for S/N, Na/Al, and H/Al molar ratios, respectively, with compressive strength of 30, 65, and 100 MPa at 3, 7, and 28 days of curing.


2012 ◽  
Vol 12 (6) ◽  
pp. 3065-3114 ◽  
Author(s):  
R. M. Harrison ◽  
M. Dall'Osto ◽  
D. C. S. Beddows ◽  
A. J. Thorpe ◽  
W. J. Bloss ◽  
...  

Abstract. The REgents PARk and Tower Environmental Experiment (REPARTEE) comprised two campaigns in London in October 2006 and October/November 2007. The experiment design involved measurements at a heavily trafficked roadside site, two urban background sites and an elevated site at 160–190 m above ground on the BT Tower, supplemented in the second campaign by Doppler lidar measurements of atmospheric vertical structure. A wide range of measurements of airborne particle physical metrics and chemical composition were made as well as measurements of a considerable range of gas phase species and the fluxes of both particulate and gas phase substances. Significant findings include (a) demonstration of the evaporation of traffic-generated nanoparticles during both horizontal and vertical atmospheric transport; (b) generation of a large base of information on the fluxes of nanoparticles, accumulation mode particles and specific chemical components of the aerosol and a range of gas phase species, as well as the elucidation of key processes and comparison with emissions inventories; (c) quantification of vertical gradients in selected aerosol and trace gas species which has demonstrated the important role of regional transport in influencing concentrations of sulphate, nitrate and secondary organic compounds within the atmosphere of London; (d) generation of new data on the atmospheric structure and turbulence above London, including the estimation of mixed layer depths; (e) provision of new data on trace gas dispersion in the urban atmosphere through the release of purposeful tracers; (f) the determination of spatial differences in aerosol particle size distributions and their interpretation in terms of sources and physico-chemical transformations; (g) studies of the nocturnal oxidation of nitrogen oxides and of the diurnal behaviour of nitrate aerosol in the urban atmosphere, and (h) new information on the chemical composition and source apportionment of particulate matter size fractions in the atmosphere of London derived both from bulk chemical analysis and aerosol mass spectrometry with two instrument types.


2011 ◽  
Vol 13 (10) ◽  
pp. 4335 ◽  
Author(s):  
Szu-Hsian Lee ◽  
Wei-Chun Lin ◽  
Chi-Jen Chang ◽  
Chih-Chieh Huang ◽  
Chi-Ping Liu ◽  
...  

1973 ◽  
Vol 12 (66) ◽  
pp. 439-451 ◽  
Author(s):  
Robert Vivian ◽  
Gerard Bocquet

The works undertaken on the Glacier d’Argentière in order to divert the subglacial stream, have allowed access to several natural cavities which correspond to places where the glacier loses contact with its rock bed. These cavities show a certain number of original phenomena both on the rock bed and also on the ice arch. Studies of the basal ice layer reveal peculiar characteristics which distinguish it from the rest of the ice mass: lamination, interstratification of ice containing sand with pure ice, crystallographic composition, and specific chemical composition. The sliding speeds of the glacier are variable, and an increase in the friction below these cavitations is at the origin of a form of regressive glacial cavitation. The subglacial cavities are grouped together in a network transverse to the direction of glacier flow; they are interconnected by channels which are more or less open which allow proper thermal exchanges to be established and favour sliding.


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