scholarly journals Fluorinated and Platinized Titania as Effective Materials in the Photocatalytic Treatment of Dyestuffs and Stained Wastewater Coming from Handicrafts Factories

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 179 ◽  
Author(s):  
Julie Murcia ◽  
Ángela Cely ◽  
Hugo Rojas ◽  
María Hidalgo ◽  
José Navío

In this study, commercial and lab-prepared TiO2 were modified by fluorination and platinum photodeposition; and the effect of these modifications over the physicochemical and photocatalytic properties of TiO2 was evaluated. It was found that F and Pt addition leads to the modification of the optical and textural properties of TiO2. The materials prepared were tested in the photocatalytic degradation of different organic dyestuffs such as methylene blue (MB) and methyl orange (MO); the degradation of commercial anilines employed in the staining of natural fibers was also evaluated. Photocatalysis was also studied in this work as an eco-friendly treatment of wastewater coming from handicrafts factories. In general it was observed that the effectiveness of the photocatalytic treatment strongly depends on the substrate to be degraded, thus, fluorinated and platinized commercial Titania (Pt-F-P25) showed the best photocatalytic performance in the MB and MO photodegradation and in contrast, in the case of the anilines the highest degradation was obtained over commercial TiO2 fluorinated (F-P25). These results can be explained by differences observed in the structure and in the adsorption of these dyestuffs over the photocatalysts surfaces. F-P25 photocatalyst also demonstrated to be the best material for the treatment of real wastewater coming from handicrafts factories.

RSC Advances ◽  
2020 ◽  
Vol 10 (20) ◽  
pp. 11823-11830
Author(s):  
Yeshuo Dong ◽  
Fanjun Meng

Three dimensional laminated structure anatase TiO2/nano-Fe0 with exposed (001) facets were successfully synthesized, which exhibited higher photocatalytic performance in the photocatalytic degradation of methylene blue.


2013 ◽  
Vol 827 ◽  
pp. 3-7
Author(s):  
Shun Jiang He ◽  
Xue Yan Du ◽  
Qiao Wang ◽  
Jing Xu

The photocatalytic activity of eosin-sensitized TiO2 nanoparticles on photocatalytic degradation rate (PDR) of methyl orange under sunlight irradiation was studied. The influential factors on the degradation, such as eosin concentration, TiO2 dosage, sensitization time and sensitization temperature were also investigated. The results show that: The performance of TiO2 nanoparticles for PDR of methyl orange has been improved obviously for eosin sensitizing. The PDR of methyl orange reached 45.28% under the conditions of eosin concentration of 20mg/L, TiO2 dosage of 0.5000g/L, sensitization time of 24h and sensitization temperature of 20°C.


2021 ◽  
Author(s):  
Xianzhen Diao ◽  
Jin XU ◽  
Yufei WANG

Nanometer TiO2 photocatalysts were prepared by the sol–gel method. The catalysts were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, ultraviolet-visible spectroscopy, and other techniques. Methyl orange solution was used for the degradation of the organic material and ultrasonic technology was used to determine the photocatalytic performance of the catalysts. The results show that the photocatalytic performance of the Ni-N-TiO2 is clearly improved under ultrasonic conditions. The TiO2 photocatalytic degradation effect is optimal at a catalyst concentration of 0.3 g/L, an initial concentration of the organic matter of 0.03 mmol/L, a nickel-doping amount of 2 mol %, and a nitrogen-doping amount of 15 mol %. The use of ultrasound technology in combination with photocatalysis has a positive effect and results in a TiO2 degradation rate of methyl orange of 95 % after 3 h.


2015 ◽  
Vol 57 (38) ◽  
pp. 17844-17851 ◽  
Author(s):  
Chong-Chen Wang ◽  
Yan-Qiu Zhang ◽  
Tian Zhu ◽  
Peng Wang ◽  
Shi-Jie Gao

2019 ◽  
Vol 6 (1) ◽  
pp. 91-99
Author(s):  
Azrina Abd Aziz ◽  
U.R. Ramzilah

In this study, carbon quantum dots (CQDs) was prepared via a facile hydrothermal method. The objective for this study is to assess the performance of CQDs in photocatalytic degradation activity of methyl orange (MO) under artificial visible light source. For that reason, the prepared photocatalyst undergo further characterization by scanning electron microscope (SEM), energy dispersive X-ray spectroscope (EDX) and UV- Vis spectrophotometer (UV-VIS) to verify the morphology structure of the photocatalyst, elemental composition as well as the absorbance intensity, respectively. The results indicates that the prepared photocatalyst possess irregular porous shape with nanometre (nm) dimensions that can escalate the surface area for photocatalytic degradation activity. The elements of the photocatalyst mainly consist of carbon and oxygen as the major constituents in which necessary for photocatalytic activity with intense peak of absorbance intensity. The prepared CQDs also shows an excellent photocatalytic performance over the MO with degradation rate of 68.9% within 120 minutes.


2021 ◽  
Author(s):  
Liang Huang ◽  
Xianghui Jin ◽  
xumei Tao ◽  
Chen Yang ◽  
Yuanyuan Han

Abstract In this paper, NiAlCe hydrotalcite was prepared by co-precipitation method and hydrothermal method in different volume fractions of ethylene glycol-water mixed solvent and polyethylene glycol-water mixed solvent, and the effect of photocatalytic degradation of methyl orange under ultraviolet light was studied. Samples were characterized by XRD, XPS, UV-Vis and FT-IR in order to find the reasons for the improvement of photocatalytic performance under co-solvent system. NiAlCe-10%EG(h) and NiAlCe-15%PEG(h) had smaller particle size, which was beneficial to photocatalytic performance. The degradation rate of methyl orange could reach up to 100% in 42 min using NiAlCe hydrotalcite with 10% volume fraction of EG and in 48 min using NiAlCe hydrotalcite with 15% volume fraction of PEG. The photocatalytic effect of NiAlCe hydrotalcite samples prepared by hydrothermal method were better than that prepared by co-precipitation method. This provided a new type of catalyst for the degradation of dyes: preparing with ethylene glycol-water mixed solvent.


RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 62424-62432 ◽  
Author(s):  
Linrui Hou ◽  
Hui Hua ◽  
Hui Cao ◽  
Siqi Zhu ◽  
Changzhou Yuan

A mesoporous core–shell TiO2@C nanohybrid exhibited remarkable photocatalytic degradation efficiency and stability for methylene blue under visible light irradiation, and attractive electrochemical behaviors for electrochemical capacitors.


2017 ◽  
Vol 81 ◽  
pp. 282-290 ◽  
Author(s):  
Jin-Gang Yu ◽  
Jiao Zou ◽  
Liang-Liang Liu ◽  
Xin-Yu Jiang ◽  
Fei-Peng Jiao ◽  
...  

Coatings ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 79 ◽  
Author(s):  
Liwen Zhu ◽  
Chenyang Gong ◽  
Jianrong Xiao ◽  
Zhiyong Wang

Cu3N/MoS2 composite films were prepared by magnetron sputtering under different preparation parameter, and their photocatalytic properties were investigated. Results showed that the composite films surface was uniform and had no evident cracks. When the sputtering power of MoS2 increased from 2 W to 8 W, the photocatalytic performance of the composite films showed a trend of increasing first and then decreasing. Among these films, the composite films with MoS2 sputtering power of 4 W showed the best photocatalytic degradation performance. The photocatalytic degradation rate of methyl orange at 30 min was 98.3%, because the MoS2 crystal in the films preferentially grew over the Cu3N crystal, thereby affecting the growth of the Cu3N crystal. The crystallinity of the copper nitride also increased. During photocatalytic degradation, the proper amount of MoS2 reduced the band gap of Cu3N, and the photogenerated electron hole pairs were easily separated. Thus, the films produces additional photogenerated electrons and promotes the degradation reaction of the composite films on methyl orange solution.


Sign in / Sign up

Export Citation Format

Share Document