scholarly journals Zn-Co@N-Doped Carbon Derived from ZIFs for High-Efficiency Synthesis of Ethyl Methyl Carbonate: The Formation of ZnO and the Interaction between Co and Zn

Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 94 ◽  
Author(s):  
Ya-Nan Miao ◽  
Yuan Wang ◽  
Dong-Hui Pan ◽  
Xiang-Hai Song ◽  
Si-Quan Xu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Calcination Temperature ◽  
High Efficiency ◽  
Carbon Materials ◽  
Molar Ratio ◽  
X Ray ◽  
Basic Sites ◽  
Ethyl Methyl ◽  
Ethyl Methyl Carbonate ◽  
Methyl Carbonate

In this work, a series of Zn-Co@N-doped carbon materials were prepared by pyrolysis of Co/Zn-ZIF precursors under a N2 atmosphere and used for high-efficiency synthesis of ethyl methyl carbonate (EMC) from dimethyl carbonate (DMC) and diethyl carbonate (DEC). The Co to Zn molar ratio and calcination temperature were varied to study the physical and chemical properties of Zn-Co@N-doped carbon materials identified by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET), inductively coupled plasma (ICP), thermogravimetric analysis (TG) and temperature programmed desorption (TPD) analysis. It was deduced that the formation of a ZnO crystalline structure and the interaction between zinc and cobalt providing weak basic sites and strong basic sites, respectively, in different samples significantly affected their catalytic performance. The catalyst activated the reaction most effectively when the Co to Zn molar ratio was 1.0 and calcination temperature was 600 °C. With the DMC to DEC molar ratio controlled at 1:1, a superior yield of around 51.50% of product EMC can be gained over catalyst ZnCo/NC-600 at 100 °C with 1 wt% catalyst loading in 7 h.

Mg and Al dual-metal functionalized mesoporous carbon as highly efficient heterogeneous catalysts for synthesis of ethyl methyl carbonate

2021 ◽  
Author(s):  
Jinghui Shi ◽  
He Wang ◽  
Yanan Lin ◽  
Yunzuo Cui ◽  
Xiangxin Xue ◽  
...  
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Carbon Materials ◽  
Synthesis Method ◽  
One Pot ◽  
Ethyl Methyl ◽  
Ethyl Methyl Carbonate ◽  
Ordered Mesoporous ◽  
Methyl Carbonate ◽  
Dual Metal

Mg and Al dual-metal functionalized nanoscale porous carbon materials (MgAl@NC) with highly ordered mesoporous structures and mixed active sites were successfully prepared using a simple one-pot synthesis method. The catalytic...

Selective Synthesis of Ethyl Methyl Carbonate via Catalytic Reactive Distillation over Heterogeneous MgO/HZSM‐5

2019 ◽  
Vol 4 (24) ◽  
pp. 7366-7370
Author(s):  
Jianhua Lv ◽  
Huanhuan Cai ◽  
Yong Guo ◽  
Wenrui Liu ◽  
Ning Tao ◽  
...  
Keyword(s):  
Reactive Distillation ◽  
Selective Synthesis ◽  
Ethyl Methyl ◽  
Ethyl Methyl Carbonate ◽  
Methyl Carbonate

Application of vermiculite and limestone to desulphurization and to the removal of dust during briquette combustion

2003 ◽  
Vol 67 (6) ◽  
pp. 1243-1251 ◽  
Author(s):  
A. Lu ◽  
D. Zhao ◽  
J. Li ◽  
C. Wang ◽  
S. Qin
Keyword(s):  
Electron Microscopy ◽  
Coal Combustion ◽  
Combustion Temperature ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Retention Ratio ◽  
X Ray ◽  
Major Factors ◽  
Chemical Reactant ◽  
Scanning Electron

AbstractSmall domestic cooking furnaces are widely used in China. These cooking furnaces release SO2 gas and dust into the atmosphere and cause serious air pollution. Experiments were conducted to investigate the effects of vermiculite, limestone or CaCO3, and combustion temperature and time on desulphurization and dust removal during briquette combustion in small domestic cooking furnaces. Additives used in the coal are vermiculite, CaCO3 and bentonite. Vermiculite is used for its expansion property to improve the contact between CaCO3 and SO2 and to convey O2 into the interior of briquette; CaCO3 is used as a chemical reactant to react with SO2 to form CaSO4; and bentonite is used to develop briquette strength. Expansion of vermiculite develops loose interior structures, such as pores or cracks, inside the briquette, and thus brings enough oxygen for combustion and sulphation reaction. Effective combustion of the original carbon reduces amounts of dust in the fly ash. X-ray diffraction, optical microscopy, and scanning electron microscopy with energy dispersive X-ray analysis show that S exists in the ash only as anhydrite CaSO4, a product of SO2 reacting with CaCO3 and O2. The formation of CaSO4 effectively reduces or eliminates SO2 emission from coal combustion. The major factors controlling S retention are vermiculite, CaCO3 and combustion temperature. The S retention ratio increases with increasing vermiculite amount at 950°C. The S retention ratio also increases with increasing Ca/S molar ratio, and the best Ca/S ratio is 2-3 for most combustion. With 12 g of the original coal, 1 to 2 g of vermiculite, a molar Ca/S ratio of 2.55 by adding CaCO3, and some bentonite, a S retention ratio >65% can be readily achieved. The highest S retention ratio of 97.9% is achieved at 950°C with addition of 2 g of vermiculite, a Ca/S ratio of 2.55 and bentonite.

Synthesis of Precipitate Calcium Carbonate with Variation Morphology from Limestone by Using Solution Mixing Method

2019 ◽  
Vol 966 ◽  
pp. 200-203
Author(s):  
Zaenal Arifin ◽  
Triwikantoro ◽  
Bintoro Anang Subagyo ◽  
Mochamad Zainuri ◽  
Darminto
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Calcium Carbonate ◽  
Molar Ratio ◽  
Mixing Process ◽  
X Ray Diffraction ◽  
Precipitate Calcium Carbonate ◽  
X Ray ◽  
Mixing Method ◽  
Scanning Electron

Abstract. In this study, the CaCO3 powder has been successfully synthesized by mixing CaCl2 from natural limestone and Na2CO3 in the same molar ratio. The mixing process of solutions was carried out by employing the molar contents of 0.125, 0.25, 0.375 and 0.5M at varying temperatures of 30, 40, 60 and 80ᴼC. The produced CaCO3 microparticles were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The highest content of aragonite phase with morphology rod-like of the samples is around 29 wt%, resulting from the process using solution of 0.125 M at 80 ᴼC. While at 30 ᴼC and 40 ᴼC produced 100 wt% calcite phase.

Anion Storage Behavior of Graphite Electrodes in LiBF4/Sulfone/Ethyl Methyl Carbonate Solutions

Langmuir ◽  
2019 ◽  
Vol 35 (46) ◽  
pp. 14804-14811 ◽  
Author(s):  
Yunju Wang ◽  
Jiayu Li ◽  
Yuhao Huang ◽  
Hongyu Wang
Keyword(s):  
Graphite Electrodes ◽  
Ethyl Methyl ◽  
Ethyl Methyl Carbonate ◽  
Carbonate Solutions ◽  
Storage Behavior ◽  
Methyl Carbonate

scholarly journals Ni2P/rGO/NF Nanosheets As a Bifunctional High-Performance Electrocatalyst for Water Splitting

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 744 ◽  
Author(s):  
Jinyu Huang ◽  
Feifei Li ◽  
Baozhong Liu ◽  
Peng Zhang
Keyword(s):  
Electron Microscopy ◽  
Water Splitting ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
High Efficiency ◽  
Splitting Method ◽  
Bifunctional Catalyst ◽  
Strong Activity ◽  
X Ray ◽  
Transmission Electron

The hydrogen generated via the water splitting method is restricted by the high level of theoretical potential exhibited by the anode. The work focuses on synthesizing a bifunctional catalyst with a high efficiency, that is, a nickel phosphide doped with the reduced graphene oxide nanosheets supported on the Ni foam (Ni2P/rGO/NF), via the hydrothermal approach together with the calcination approach specific to the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). The Raman, X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscope (TEM), Scanning Electron Microscopy (SEM), High-Resolution Transmission Electron Microscopy (HRTEM), as well as elemental mapping, are adopted to study the composition and morphology possessed by Ni2P/rGO/NF. The electrochemical testing is performed by constructing a parallel two-electrode electrolyzer (Ni2P/rGO/NF||Ni2P/rGO/NF). Ni2P/rGO/NF||Ni2P/rGO/NF needs a voltage of only 1.676 V for driving 10 mA/cm2, which is extremely close to Pt/C/NF||IrO2/NF (1.502 V). It is possible to maintain the current density for no less than 30 hours. It can be demonstrated that Ni2P/rGO/NF||Ni2P/rGO/NF has commercial feasibility, relying on the strong activity and high stability.

Synergetic Effect of Ethyl Methyl Carbonate and Trimethyl Phosphate on BF4– Intercalation into a Graphite Electrode

Langmuir ◽  
2019 ◽  
Vol 35 (11) ◽  
pp. 3972-3979 ◽  
Author(s):  
Lei Zhang ◽  
Jiayu Li ◽  
Yuhao Huang ◽  
Dandan Zhu ◽  
Hongyu Wang
Keyword(s):  
Graphite Electrode ◽  
Synergetic Effect ◽  
Trimethyl Phosphate ◽  
Ethyl Methyl ◽  
Ethyl Methyl Carbonate ◽  
Methyl Carbonate

scholarly journals Lead-Free BNT–BT0.08/CoFe2O4 Core–Shell Nanostructures with Potential Multifunctional Applications

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 672
Author(s):  
Marin Cernea ◽  
Roxana Radu ◽  
Harvey Amorín ◽  
Simona Gabriela Greculeasa ◽  
Bogdan Stefan Vasile ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Sol Gel ◽  
Molar Ratio ◽  
Transmission Electron Microscopy Data ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Two Phase ◽  
X Ray ◽  
Shell Nanostructures

Herein we report on novel multiferroic core–shell nanostructures of cobalt ferrite (CoFe2O4)–bismuth, sodium titanate doped with barium titanate (BNT–BT0.08), prepared by a two–step wet chemical procedure, using the sol–gel technique. The fraction of CoFe2O4 was varied from 1:0.5 to 1:1.5 = BNT–BT0.08/CoFe2O4 (molar ratio). X–ray diffraction confirmed the presence of both the spinel CoFe2O4 and the perovskite Bi0.5Na0.5TiO3 phases. Scanning electron microscopy analysis indicated that the diameter of the core–shell nanoparticles was between 15 and 40 nm. Transmission electron microscopy data showed two–phase composite nanostructures consisting of a BNT–BT0.08 core surrounded by a CoFe2O4 shell with an average thickness of 4–7 nm. Cole-Cole plots reveal the presence of grains and grain boundary effects in the BNT–BT0.08/CoFe2O4 composite. Moreover, the values of the dc conductivity were found to increase with the amount of CoFe2O4 semiconductive phase. Both X-ray photoelectron spectroscopy (XPS) and Mössbauer measurements have shown no change in the valence of the Fe3+, Co2+, Bi3+ and Ti4+ cations. This study provides a detailed insight into the magnetoelectric coupling of the multiferroic BNT–BT0.08/CoFe2O4 core–shell composite potentially suitable for magnetoelectric applications.

scholarly journals Heterogeneous Fenton-like oxidation of p-hydroxybenzoic acid using Fe/CeO2-TiO2 catalyst

2019 ◽  
Vol 79 (7) ◽  
pp. 1276-1286 ◽  
Author(s):  
Tijani Hammedi ◽  
Mohamed Triki ◽  
Mayra G. Alvarez ◽  
Jordi Llorca ◽  
Abdelhamid Ghorbel ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Catalytic Properties ◽  
Molar Ratio ◽  
Hydroxybenzoic Acid ◽  
X Ray ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
Temperature Programmed

Abstract This paper is built on the Fenton-like oxidation of p-hydroxybenzoic acid (p–HBZ) in the presence of H2O2 and 3%Fe supported on CeO2-TiO2 aerogels under mild conditions. These catalysts were deeply characterized by X-ray diffraction (XRD), hydrogen temperature programmed reduction (H2-TPR), transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM) and X-ray photoelectron spectroscopy (XPS). The effect of thermal treatment, pH (2–3, 5, 7), H2O2/p–HBZ molar ratio (5, 15, 20, 25) and reaction temperature (25 °C, 40 °C and 60 °C) on the catalytic properties of supported Fe catalysts are studied. Our results highlight the role of CeO2 and the calcination of the catalyst to obtain the highest catalytic properties after 10 min: 73% of p–HBZ conversion and 52% of total organic carbon (TOC) abatement.

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