scholarly journals Screen-Printed Electrodes Modified with Metal Nanoparticles for Small Molecule Sensing

Biosensors ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 9 ◽  
Author(s):  
Daniel Antuña-Jiménez ◽  
María Begoña González-García ◽  
David Hernández-Santos ◽  
Pablo Fanjul-Bolado

Recent progress in the field of electroanalysis with metal nanoparticle (NP)-based screen-printed electrodes (SPEs) is discussed, focusing on the methods employed to perform the electrode surface functionalization, and the final application achieved with different types of metallic NPs. The ink mixing approach, electrochemical deposition, and drop casting are the usual methodologies used for SPEs’ modification purposes to obtain nanoparticulated sensing phases with suitable tailor-made functionalities. Among these, applications on inorganic and organic molecule sensing with several NPs of transition metals, bimetallic alloys, and metal oxides should be highlighted.

2021 ◽  
Vol 8 ◽  
Author(s):  
Emily Kerr ◽  
Richard Alexander ◽  
Paul S. Francis ◽  
Rosanne M. Guijt ◽  
Gregory J. Barbante ◽  
...  

We examined a series of commercially available screen-printed electrodes (SPEs) for their suitability for electrochemical and electrogenerated chemiluminescence (ECL) detection systems. Using cyclic voltammetry with both a homogeneous solution-based and a heterogeneous bead-based ECL assay format, the most intense ECL signals were observed from unmodified carbon-based SPEs. Three commercially available varieties were tested, with Zensor outperforming DropSens and Kanichi in terms of sensitivity. The incorporation of nanomaterials in the electrode did not significantly enhance the ECL intensity under the conditions used in this evaluation (such as gold nanoparticles 19%, carbon nanotubes 45%, carbon nanofibers 21%, graphene 48%, and ordered mesoporous carbon 21% compared to the ECL intensity of unmodified Zensor carbon electrode). Platinum and gold SPEs exhibited poor relative ECL intensities (16% and 10%) when compared to carbonaceous materials, due to their high rates of surface oxide formation and inefficient oxidation of tri-n-propylamine (TPrA). However, the ECL signal at platinum electrodes can be increased ∼3-fold with the addition of a surfactant, which enhanced TPrA oxidation due to increasing the hydrophobicity of the electrode surface. Our results also demonstrate that each SPE should only be used once, as we observed a significant change in ECL intensity over repeated CV scans and SPEs cannot be mechanically polished to refresh the electrode surface.


2017 ◽  
Vol 46 (7) ◽  
pp. 1875-1932 ◽  
Author(s):  
Yuemin Wang ◽  
Christof Wöll

In this review, we highlight recent progress (2008–2016) in infrared reflection absorption spectroscopy (IRRAS) studies on oxide powders achieved by using different types of metal oxide single crystals as reference systems.


2019 ◽  
Vol 317 ◽  
pp. 673-683 ◽  
Author(s):  
Vincenzo Mazzaracchio ◽  
Maria Rita Tomei ◽  
Ilaria Cacciotti ◽  
Angelica Chiodoni ◽  
Chiara Novara ◽  
...  

2011 ◽  
Vol 56 (11) ◽  
pp. 3988-3995 ◽  
Author(s):  
Elena Jubete ◽  
Kamila Żelechowska ◽  
Oscar A. Loaiza ◽  
Pedro J. Lamas ◽  
Estibalitz Ochoteco ◽  
...  

Author(s):  
Robert D. Crapnell ◽  
Whitchuta Jesadabundit ◽  
Alejandro García-Miranda Ferrari ◽  
Nina C. Dempsey-Hibbert ◽  
Marloes Peeters ◽  
...  

2021 ◽  
pp. 101055
Author(s):  
Dora Domnica Baciu ◽  
Ruxandra Bîrjega ◽  
Valentina Mărăscu ◽  
Rodica Zăvoianu ◽  
Andreea Matei ◽  
...  

2012 ◽  
Vol 571 ◽  
pp. 56-59
Author(s):  
Yu Fang Sha ◽  
Mei Zhao ◽  
Ming Quan Yang ◽  
Hai Xin Bai ◽  
Man Zhao

Biological multilayer films of redox polymer and horseradish peroxidase (HRP) were successfully assembled on a screen-printed carbon electrode using layer-by-layer (LBL) assembled method based on the electrostatic interaction. The screen-printed carbon electrode surface was modified by the positively charged redox polymer, and the negatively charged HRP by LBL method.


2003 ◽  
Vol 481 (2) ◽  
pp. 209-211 ◽  
Author(s):  
Christine Bonnet ◽  
Silvana Andreescu ◽  
Jean-Louis Marty

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