scholarly journals Feasibility Study of Using Carbide Slag as In-Bed Desulfurizer in Circulating Fluidized Bed Boiler

2019 ◽  
Vol 9 (21) ◽  
pp. 4517 ◽  
Author(s):  
Zhong Huang ◽  
Jimiao Long ◽  
Lei Deng ◽  
Defu Che

Carbide slag is a waste residue during the production of acetylene. Due to its high content of Ca(OH)2, carbide slag becomes a potential alternative to limestone as the in-bed desulfurizer of circulating fluidized bed (CFB) boilers. In this study, the calcination and sulfation characteristics of carbide slag were investigated by three different facilities, thermogravimetric analyzer (TGA), 1 MWth pilot CFB boiler, and 690 t·h−1 CFB boiler. Pore structures and sulfation behaviors of carbide slag and limestone were investigated for the sake of comparison. The results showed that carbide slag has a lower calcination temperature than limestone. Its calcined product has a better pore structure and desulfurization activity. The carbide slag exhibited a higher desulfurization efficiency than the limestone in the pilot tests. The SO2 emission concentration showed a downward trend with the increase of molar fraction of carbide slag in the desulfurizer. Meanwhile, carbide slag had a better sintering-resistance property, which makes it possible to effectively reduce SO2 emissions even at high combustion temperatures (>910 °C). While the field test results were similar to that of the pilot tests, the desulfurization efficiency of carbide slag with the same Ca/S mole ratio was higher than that of limestone. The fine size of carbide slag particles and the lower separation efficiency of the cyclone on the 690 t·h−1 boiler left the carbide slag with insufficient residence time in the furnace. Therefore, it is necessary to ensure a high separation efficiency of the cyclone if the carbide slag is used as an alternative desulfurizer in furnace.

Author(s):  
Matteo Bruzzone ◽  
Silvia Ravelli

It is well known that the Łagisza power plant in Poland is the world’s first supercritical circulating fluidized bed (CFB) boiler, whose commercial operation started on June 2009. It has attracted a great deal of interest and operational data are publicly available, therefore it has been chosen as the object of the present study aimed at assessing load and fuel flexibility of supercritical CFB plants. First, the thermal cycle was modelled, by means of the commercial code Thermoflex®, at nominal and part load conditions for validation purposes. After having verified the validity of the applied modelling and simulation tool, the advantage of having supercritical steam combined with CFB boiler over subcritical steam and pulverized coal (PC) boiler, respectively, was quantified in terms of electric efficiency. As a next step, the designed fuel, i.e. locally mined hard coal, was replaced with biomass: 100% biomass firing was taken into account in the case of subcritical CFB boiler whereas the maximum share of biomass with coal was set at 50% with supercritical CFB boiler, consistently with the guidelines provided by the world leading manufacturers of CFB units. A broad range of biomass types was tested to conceive mixtures of fuel capable of preserving quite high performance, despite the energy consumption in pretreatment. However, the overall efficiency penalty, due to biomass co-firing, was found to potentially undermine the benefit of supercritical steam conditions compared to conventional subcritical power cycles. Indeed, the use of low-quality biomass in thermal power generation based on steam Rankine cycle may frustrate efforts to push the steam cycle boundaries.


2014 ◽  
Vol 1070-1072 ◽  
pp. 1764-1768
Author(s):  
Zhan Guo Li ◽  
Zhen Ning Zhao ◽  
Zhi Qiang Wen

Based on the aspects of thermal properties, resistance properties, air Leakage Control and boiler output adaptability, the operation modes and their impact of a quad-sector rotary airheater adopted by a 330MWe circulating fluidized bed boiler are analyzed by tests. And the operation methods of Leakage Control System are concluded. In order to improve the reliability of rotary airheater with main and auxiliary motors, recommendations for improvement are extended.


2008 ◽  
Vol 22 (5) ◽  
pp. 3005-3015 ◽  
Author(s):  
Linda S. Johansson ◽  
Bo Leckner ◽  
Claes Tullin ◽  
Lars-Erik Åmand ◽  
Kent Davidsson

2006 ◽  
Vol 128 (2) ◽  
pp. 135-142 ◽  
Author(s):  
Andreas Johansson ◽  
Filip Johnsson ◽  
Bengt-Åke Andersson

High in-bed heat transfer and low corrosive environment imply that the loop seal of a circulating fluidized bed (CFB) boiler is an advantageous location for superheaters. In order to increase the knowledge on the flow pattern and the heat transfer distribution to the tubes within a loop seal, measurements were performed in the loop seal of a 30MW CFB boiler as well as in a 1∕3 scaled-down seal operated according to simplified scaling laws. The scale model measurements show that the solids recirculation flux can be maintained with a substantial decrease of the fluidization flow in the seal compared to that currently used at full load conditions. It was also possible to significantly decrease the fraction of the bottom of the seal that was fluidized without affecting the solids flux through the seal. A gradient in the solids flow were detected in the vertical direction.


2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Chang-Sang Cho ◽  
Jae-Hwan Sa ◽  
Ki-Kyo Lim ◽  
Tae-Mi Youk ◽  
Seung-Jin Kim ◽  
...  

This study makes use of this distinction to analyze the exhaust gas concentration and fuel of the circulating fluidized bed (CFB) boiler that mainly uses wood biomass, and to develop the emission factors of Methane (CH4), Nitrous oxide (N2O). The fuels used as energy sources in the subject working sites are Wood Chip Fuel (WCF), RDF and Refused Plastic Fuel (RPF) of which heating values are 11.9 TJ/Gg, 17.1 TJ/Gg, and 31.2 TJ/Gg, respectively. The average concentrations of CH4and N2O were measured to be 2.78 ppm and 7.68 ppm, respectively. The analyzed values and data collected from the field survey were used to calculate the emission factor of CH4and N2O exhausted from the CFB boiler. As a result, the emission factors of CH4and N2O are 1.4 kg/TJ (0.9–1.9 kg/TJ) and 4.0 kg/TJ (2.9–5.3 kg/TJ) within a 95% confidence interval. Biomass combined with the combustion technology for the CFB boiler proved to be more effective in reducing the N2O emission, compared to the emission factor of the CFB boiler using fossil fuel.


Author(s):  
Zhengshun Wu ◽  
Hanping Chen ◽  
Dechang Liu ◽  
Jie Wang ◽  
Chuangzhi Wu ◽  
...  

The operation performance of circulating fluidized bed combustion (CFBC) boiler was studied in this paper. The experimental results indicate that the load of CFB boiler has linear relation with bed temperature and bed material height of operation. By multiple regression analysis, the relation of the load of CFB boiler with bed temperature and bed material height of operation can be expressed as a formula. The suitable temperature and the bed material height corresponding to the load of CFB boiler can be found using the formula; the problem of the boiler to be blindly operated can be reduced in practice.


Author(s):  
Andreas Kreuzeder ◽  
Christoph Pfeifer ◽  
Hermann Hofbauer

Gasification of biomass is an attractive technology for combined heat and power (CHP) production. A dual fluidized bed steam gasifier is in commercial operation at the biomass CHP plant in Guessing/Austria since 2002. For circulating fluidized bed applications the bed material consumption is economically crucial. Thus, cyclones for circulating fluidized beds need to be designed properly. Some erosion and caking in the cyclone of the gasifier could be observed with increasing hours of operation. The influences of these effects as well as the influence of the solid circulation rate between the two units on the separation efficiency were investigated by fluid-dynamic investigations using a scaled cold model. The results show that due to erosion and caking elutriation rates are increased, especially for smaller particles. However, the cyclone achieves fractional separation efficiencies of more than 99.9%.


2012 ◽  
Vol 516-517 ◽  
pp. 444-447
Author(s):  
Da Fu Ma ◽  
Xiao Hong Hao

The paper is focused on the present situation and the development of large-scale circulating fluidized bed (CFB) boilers. Several developed technology of CFB such as supercritical and ultra supercritical pressure CFB boilers for power plants, oxy-fuel CFB boiler for CO2 capture and high-density circulating fluidized bed gasifier for advanced IGCC/IGFC are introduced in this paper.


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