scholarly journals Effect of Hydrogen Bonding on the Surface Tension Properties of Binary Mixture (Acetone-Water) by Raman Spectroscopy

2019 ◽  
Vol 9 (6) ◽  
pp. 1235 ◽  
Author(s):  
Nannan Wu ◽  
Xin Li ◽  
Shiliang Liu ◽  
Mingzhe Zhang ◽  
Shunli Ouyang
Keyword(s):  
Surface Tension ◽  
Hydrogen Bonding ◽  
Binary Mixture ◽  
Aqueous Solutions ◽  
Experiment Data ◽  
Peak Intensity ◽  
Relative Peak Intensity ◽  
Acetone Water ◽  
Tension Properties ◽  
The Relationship

The structure and properties of water and aqueous solutions have always been the focus of attention. The surface tension of acetone aqueous solutions were measured by using Raman spectra in different molecule environments, and the changes of surface tension were analyzed with hydrogen bonding in the mixtures. In this case, OH stretching bands were fitted into three Gaussian components and then assigned to different hydrogen-bonded structures. Furthermore, it can be concluded that the changes of microstructure on the binary mixture solutions exhibited regularly with the additive acetone, indicating that there showed the correlation between surface tension and relative peak intensity. The results show that the strengthening of hydrogen bonding between acetone and water will gradually weaken the surface tension of the solutions. It was confirmed that there showed the relationship between the microstructure and macroscopic properties of the aqueous solutions by the basis experiment data using a spectroscopy method.

scholarly journals Investigation on the Influence of Microstructure Based on Hydrogen Bonding on Surface Tension by Raman Spectroscopy

2019 ◽  
Vol 2019 ◽  
pp. 1-7
Author(s):  
Nannan Wu ◽  
Shunli Ouyang ◽  
Junjie Cui ◽  
Shiliang Liu ◽  
Mingzhe Zhang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Raman Spectroscopy ◽  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Tracking System ◽  
Binary Solution ◽  
Spectroscopic Method ◽  
Mixed Solution ◽  
Direct Experiment ◽  
The Relationship

Surface tension (http://mts.hindawi.com/update/) in our Manuscript Tracking System and after you have logged in click on the ORCID link at the top of the page. This link will take you to the ORCID website where you will be able to create an account for yourself. Once you have done so, your new ORCID will be saved in our Manuscript Tracking System automatically."?>and Raman spectra containing hydrogen bonding in acetonitrile aqueous solutions with different mole ratios were obtained. Varied surface tension and hydrogen bonding in the mixed solution were discussed. For this purpose, the OH stretching bands were fitted into three Gaussian components to which different hydrogen-bonded water samples were assigned. Furthermore, the microstructures of binary solution were analyzed. The results indicated that the surface tension decreases dramatically with the enhancement of hydrogen bonds in the mixture. A spectroscopic method for studying the macroscopic properties of aqueous solutions was employed. The direct experiment results provided the relationship between surface tension and microstructure in aqueous solutions.

Hydrogen bonding and surface tension properties of aqueous solutions of tetrahydrofuran

2021 ◽  
pp. 1-8
Author(s):  
Fang Liu ◽  
Pianpian Chang ◽  
Yuxuan Zhang ◽  
Mingzhe Zhang ◽  
Shunli Ouyang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Tension Properties

Temperature Influence on Performance of Oxidation Ponds

1991 ◽  
Vol 24 (5) ◽  
pp. 85-96 ◽  
Author(s):  
Qingliang Zhao ◽  
Zijie Zhang
Keyword(s):  
Mathematical Model ◽  
Temperature Influence ◽  
Field Scale ◽  
Experiment Data ◽  
Computer Technique ◽  
Oxidation Pond ◽  
Optimum Model ◽  
Oxidation Ponds ◽  
The Mathematical Model ◽  
The Relationship

By means of simulated tests of a laboratory–scale oxidation pond model, the relationship between BOD5 and temperature fluctuation was researched. Mathematical modelling for the pond's performance and K1determination were systematically described. The calculation of T–K1–CeCe/Ci) was complex but the problem was solved by utilizing computer technique in the paper, and the mathematical model which could best simulate experiment data was developed. On the basis of experiment results,the concept of plug–ratio–coefficient is also presented. Finally the optimum model recommended here was verified with the field–scale pond data.

Intramolecular Hydrogen Bonding Facilitates Electrocatalytic Reduction of Nitrite in Aqueous Solutions

2019 ◽  
Vol 58 (14) ◽  
pp. 9443-9451 ◽  
Author(s):  
Song Xu ◽  
Hyuk-Yong Kwon ◽  
Daniel C. Ashley ◽  
Chun-Hsing Chen ◽  
Elena Jakubikova ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Aqueous Solutions ◽  
Intramolecular Hydrogen Bonding ◽  
Electrocatalytic Reduction ◽  
Intramolecular Hydrogen

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

scholarly journals Surface Thermodynamics, Viscosity, Activation Energy of N-Methyldiethanolamine Aqueous Solutions Promoted by Tetramethylammonium Arginate

Entropy ◽  
2020 ◽  
Vol 22 (12) ◽  
pp. 1337
Author(s):  
Xiangfeng Tian ◽  
Lemeng Wang ◽  
Pan Zhang ◽  
Dong Fu
Keyword(s):  
Activation Energy ◽  
Surface Tension ◽  
Diffusion Coefficient ◽  
Aqueous Solutions ◽  
Quantitative Relationship ◽  
Viscosity Data ◽  
Surface Thermodynamics ◽  
Surface Entropy ◽  
Operation Conditions ◽  
Surface Enthalpy

The surface tension and viscosity values of N-methyldiethanolamine (MDEA) aqueous solutions promoted by tetramethylammonium arginate ([N1111][Arg]) were measured and modeled. The experimental temperatures were 303.2 to 323.2 K. The mass fractions of MDEA (wMDEA) and [N1111][Arg] (w[N1111][Arg]) were 0.300 to 0.500 and 0.025 to 0.075, respectively. The measured surface tension and viscosity values were satisfactorily fitted to thermodynamic models. With the aid of experimentally viscosity data, the activation energy (Ea) and H2S diffusion coefficient (DH2S) of MDEA-[N1111][Arg] aqueous solution were deduced. The surface entropy and surface enthalpy of the solutions were calculated using the fitted model of the surface tension. The quantitative relationship between the calculated values (surface tension, surface entropy, surface enthalpy, viscosity, activation energy, and H2S diffusion coefficient) and the operation conditions (mass fraction and temperature) was demonstrated.

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