scholarly journals Simulation of Coal Gasification in a Low-Temperature, High-Pressure Entrained-Bed Reactor with a Volatiles Condensation and Re-Evaporation Model

2019 ◽  
Vol 9 (3) ◽  
pp. 510
Author(s):  
Ming-Hong Chen ◽  
Yau-Pin Chyou ◽  
Ting Wang
Keyword(s):  
High Pressure ◽  
Coal Gasification ◽  
Simulation Models ◽  
Operating Pressure ◽  
Synthetic Natural Gas ◽  
Gasification Process ◽  
Exit Temperature ◽  
Computational Fluid Dynamics Cfd ◽  
Lower Temperature ◽  
Entrained Flow Gasification

The objective of this study is to implement a tar condensation and re-vaporization sub-model in a previously established Computational Fluid Dynamics (CFD) model for the Entrained Slagging Transport Reactor (E-STR) gasifier, modified from the existing E-Gasifier simulation models in previous studies. The major modifications in E-STR, compared to the existing E-GasTM design, include higher operating pressure and lower temperature, with the aim of achieving a higher H2/CO ratio of syngas, which is more favorable for synthetic natural gas (SNG) production. In this study, the aforementioned sub-model is described by the UDF (User-Defined Function) and incorporated in a previously developed computational model for entrained-flow gasification process, to study the syngas composition without implementing a tars-cracking catalyst in the E-STR gasifier. The results show that incorporating the tar condensation model leads to a formation of approximately 6.47% liquid volatiles and an exit temperature increase about 135 K, due to the release of latent heat. These sub-models have been successfully implemented and will be useful in the condition that the gasifier temperature is intentionally kept low, just as the E-STR gasifier. The results indicate that high pressure and less oxygen feed produce a higher H2/CO ratio, more favorable for SNG production.

scholarly journals Ruhrchemie/Ruhrkohle’s Technical Version of the Texaco Coal Gasifier as Part of a Combined Cycle Plant

1982 ◽  
Author(s):  
B. Cornils ◽  
J. Hibbel ◽  
P. Ruprecht ◽  
R. Dürrfeld ◽  
J. Langhoff
Keyword(s):  
High Pressure ◽  
Power Plants ◽  
Coal Gasification ◽  
Operating Time ◽  
Combined Cycle ◽  
Gas Generation ◽  
Load Following ◽  
Gasification Process ◽  
Steady State Operation ◽  
Combined Cycle Plant

The Ruhrchemie/Ruhrkohle variant of the Texaco Coal Gasification Process (TCGP) has been on stream since 1978. As the first demonstration plant of the “second generation” it has confirmed the advantages of the simultaneous gasification of coal: at higher temperatures; under elevated pressures; using finely divided coal; feeding the coal as a slurry in water. The operating time so far totals 9000 hrs. More than 50,000 tons of coal have been converted to syn gas with a typical composition of 55 percent CO, 33 percent H2, 11 percent CO2 and 0.01 percent of methane. The advantages of the process — low environmental impact, additional high pressure steam production, gas generation at high pressure levels, steady state operation, relatively low investment costs, rapid and reliable turn-down and load-following characteristics — make such entrained-bed coal gasification processes highly suitable for power generation, especially as the first step of combined cycle power plants.

scholarly journals Changes in properties of tar obtained during underground coal gasification process

2021 ◽  
Author(s):  
Marian Wiatowski ◽  
Roksana Muzyka ◽  
Krzysztof Kapusta ◽  
Maciej Chrubasik
Keyword(s):  
Coal Gasification ◽  
Coal Tar ◽  
Liquid Product ◽  
Coke Oven ◽  
Underground Coal Gasification ◽  
Gasification Process ◽  
Dominant Component ◽  
Process Gas ◽  
High Volatility ◽  
Product Separator

AbstractIn this study, the composition of tars collected during a six-day underground coal gasification (UCG) test at the experimental mine ‘Barbara’ in Poland in 2013 was examined. During the test, tar samples were taken every day from the liquid product separator and analysed by the methods used for testing properties of typical coke oven (coal) tar. The obtained results were compared with each other and with the data for coal tar. As gasification progressed, a decreasing trend in the water content and an increasing trend in the ash content were observed. The tars tested were characterized by large changes in the residue after coking and content of parts insoluble in toluene and by smaller fluctuations in the content of parts insoluble in quinoline. All tested samples were characterized by very high distillation losses, while for samples starting from the third day of gasification, a clear decrease in losses was visible. A chromatographic analysis showed that there were no major differences in composition between the tested tars and that none of the tar had a dominant component such as naphthalene in coal tar. The content of polycyclic aromatic hydrocarbons (PAHs) in UCG tars is several times lower than that in coal tar. No light monoaromatic hydrocarbons (benzene, toluene, ethylbenzene and xylenes—BTEX) were found in the analysed tars, which results from the fact that these compounds, due to their high volatility, did not separate from the process gas in the liquid product separator.

Prediction of Key Parameters of Coal Gasification Process Based on Time Delay Mining Fuzzy Time Cognitive Maps

2021 ◽  
Author(s):  
Congbin Jiang ◽  
Dan Wang ◽  
Cuiping Gong ◽  
Gang Zhang ◽  
Wen Gu ◽  
...  
Keyword(s):  
Time Delay ◽  
Coal Gasification ◽  
Cognitive Maps ◽  
Gasification Process

Numerical simulation on the coal gasification process in dry feed entrained gasifier

2020 ◽  
Author(s):  
Lijun Wang ◽  
Xiaocheng Du ◽  
Jiajun Sun ◽  
Shuping Duan ◽  
Xin Xie
Keyword(s):  
Numerical Simulation ◽  
Coal Gasification ◽  
Gasification Process

Testing antifreeze protein from the longhorn beetle Rhagium mordax as a kinetic gas hydrate inhibitor using a high-pressure micro differential scanning calorimeter

2015 ◽  
Vol 93 (9) ◽  
pp. 1025-1030 ◽  
Author(s):  
Nagu Daraboina ◽  
Christine Malmos Perfeldt ◽  
Nicolas von Solms
Keyword(s):  
High Pressure ◽  
Differential Scanning Calorimeter ◽  
Oil And Gas ◽  
Hydrate Formation ◽  
Antifreeze Protein ◽  
Melting Behavior ◽  
Relative Strength ◽  
Operating Pressure ◽  
Longhorn Beetle ◽  
Low Dosage

Low dosage kinetic hydrate inhibitors are employed as alternatives to expensive thermodynamic inhibitors to manage the risk of hydrate formation inside oil and gas pipelines. These chemicals need to be tested at appropriate conditions in the laboratory before deployment in the field. A high pressure micro differential scanning calorimeter HP-μDSC VII (Setaram Inc.) containing two 50 cc high pressure cells (maximum operating pressure 40 MPa; temperature range –40 to 120 °C) was employed to observe methane hydrate formation and decomposition in the presence of hyperactive antifreeze protein from Rhagium mordax (RmAFP) and biodegradable synthetic kinetic inhibitor Luvicap Bio. A systematic capillary dispersion method was used, and this method enhanced the ability to detect the effect of various inhibitors on hydrate formation with small quantities. The presence of RmAFP and Luvicap Bio influence (inhibit) the hydrate formation phenomena significantly. Luvicap Bio (relative strength compared to buffer: 13.3 °C) is stronger than RmAFP (9.8 °C) as a nucleation inhibitor. However, the presence RmAFP not only delays hydrate nucleation but also reduces the amount of hydrate formed (20%–30%) after nucleation significantly. Unlike RmAFP, Luvicap Bio promoted the amount of hydrate formed after nucleation. The superior hydrate growth inhibition capability and predictable hydrate melting behavior compared to complex, heterogeneous hydrate melting with Luvicap Bio shows that RmAFP can be a potential natural green kinetic inhibitor for hydrate formation in pipelines.

scholarly journals Investigation of the Coal Gasification Process Under Various Operating Conditions Inside a Two-Stage Entrained Flow Gasifier

2012 ◽  
Vol 4 (2) ◽  
Author(s):  
Armin Silaen ◽  
Ting Wang
Keyword(s):  
Coal Gasification ◽  
Operating Conditions ◽  
Coal Slurry ◽  
Two Stage ◽  
Heating Value ◽  
Fuel Distribution ◽  
Entrained Flow ◽  
One Stage ◽  
Gasification Process ◽  
Entrained Flow Gasifier

Numerical simulations of the coal gasification process inside a generic 2-stage entrained-flow gasifier fed with Indonesian coal at approximately 2000 metric ton/day are carried out. The 3D Navier–Stokes equations and eight species transport equations are solved with three heterogeneous global reactions, three homogeneous reactions, and two-step thermal cracking equation of volatiles. The chemical percolation devolatilization (CPD) model is used for the devolatilization process. This study is conducted to investigate the effects of different operation parameters on the gasification process including coal mixture (dry versus slurry), oxidant (oxygen-blown versus air-blown), and different coal distribution between two stages. In the two-stage coal-slurry feed operation, the dominant reactions are intense char combustion in the first stage and enhanced gasification reactions in the second stage. The gas temperature in the first stage for the dry-fed case is about 800 K higher than the slurry-fed case. This calls for attention of additional refractory maintenance in the dry-fed case. One-stage operation yields higher H2, CO and CH4 combined than if a two-stage operation is used, but with a lower syngas heating value. The higher heating value (HHV) of syngas for the one-stage operation is 7.68 MJ/kg, compared with 8.24 MJ/kg for two-stage operation with 75%–25% fuel distribution and 9.03 MJ/kg for two-stage operation with 50%–50% fuel distribution. Carbon conversion efficiency of the air-blown case is 77.3%, which is much lower than that of the oxygen-blown case (99.4%). The syngas heating value for the air-blown case is 4.40 MJ/kg, which is almost half of the heating value of the oxygen-blown case (8.24 MJ/kg).

scholarly journals Characteristics of Water Contaminants from Underground Coal Gasification (UCG) Process—Effect of Coal Properties and Gasification Pressure

Energies ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6533
Author(s):  
Magdalena Pankiewicz-Sperka ◽  
Krzysztof Kapusta ◽  
Wioleta Basa ◽  
Katarzyna Stolecka
Keyword(s):  
Bituminous Coal ◽  
Coal Gasification ◽  
Strong Relationship ◽  
Underground Coal Gasification ◽  
Volatile Phenols ◽  
Water Contaminants ◽  
Physicochemical Composition ◽  
Gasification Process ◽  
Anthracite Coal ◽  
Coal Properties

One of the most important issues during UCG process is wastewater production and treatment. Condensed gasification wastewater is contaminated by many hazardous compounds. The composition of the generated UCG-derived wastewater may vary depending on the type of gasified coal and conditions of the gasification process. The main purpose of this study was a qualitative and quantitative characterization of the UCG wastewater produced during four different UCG experiments. Experiments were conducted using semi-anthracite and bituminous coal samples at two distinct pressures, i.e., 20 and 40 bar. The conducted studies revealed significant relationships between the physicochemical composition of the wastewater and the coal properties as well as the gasification pressure. The strongest impact is noticeable in the case of organic pollutants, especially phenols, BTEX and PAH’s. The most abundant group of pollutants were phenols. Conducted studies showed significantly higher concentration levels for bituminous coal: 29.25–49.5 mg/L whereas for semi-anthracite effluents these concentrations were in much lower range 2.1–29.7 mg/L. The opposite situation occurs for BTEX, higher concentrations were in wastewater from semi-anthracite gasification: 5483.1–1496.7 µg/L, while in samples from bituminous coal gasification average BTEX concentrations were: 2514.3–1354.4 µg/L. A similar relationship occurs for the PAH’s concentrations. The higher values were in case of wastewater from semi-anthracite coal experiments and were in range 362–1658 µg/L while from bituminous coal gasification PAH’s values are in lower ranges 407–1090 µg/L. The studies conducted have shown that concentrations of phenols, BTEX and PAH’s decrease with increasing pressure. Pearson’s correlation analysis was performed to enhance the interpretation of the obtained experimental data and showed a very strong relationship between three parameters: phenols, volatile phenols and CODcr.

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