scholarly journals A Rapid Method for the Determination of SBS Content Based on the Principle of Orthogonal Testing

2021 ◽  
Vol 11 (22) ◽  
pp. 10911
Author(s):  
Gang Xu ◽  
Xiaojing Gong ◽  
Yunhong Yu ◽  
Xianhua Chen
Keyword(s):  
Rapid Determination ◽  
Test Accuracy ◽  
Polymer Content ◽  
Modified Asphalt ◽  
Temperature Scanning ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Orthogonal Tests ◽  
Rheometer Test

The performance of Styrene-butadiene-styrene (SBS) modified asphalt is closely related to the content of SBS modifier. In the production process of modified asphalt, a certain amount of additive such as sulfur and rubber oil may be added to reduce the segregation and promote the swelling of the polymer, but the effect of these additives on determining SBS content in asphalt is not yet clear. This paper presents the calibration curves of SBS content based on rutting factor and creep slope and points out its defects according to the temperature scanning test and the bending beam rheometer test. Subsequently, using Fourier transform infrared spectroscopy (FTIR) for rapid determination of polymer content in SBS modified asphalt based on orthogonal test and then the effects of additives such as asphalt type, SBS content, rubber oil and sulfur on the accuracy of polymer content determination by FTIR were investigated. Moreover, in the orthogonal tests of adding sulfur and rubber oil, the multivariate analysis of variance (MANOVA) was firstly used to analyze the additives influence on the test accuracy of FITR. Results indicated that the influencing degree of different additives is different. The influence of sulfur on the determination accuracy is greater than that of rubber oil. Therefore, the rapid determination method needs further improvement.

scholarly journals Evaluation of Properties and Micro-Characteristics of Waste Polyurethane/Styrene-Butadiene-Styrene Composite Modified Asphalt

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng
Keyword(s):  
Low Temperature ◽  
Performance Test ◽  
Permanent Deformation ◽  
Modified Asphalt ◽  
Basic Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
And Storage ◽  
Butadiene Styrene

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

scholarly journals Kajian Penambahan RejIRE pada Aspal Modifikasi Crumb Rubber serta Kinerjanya pada Campuran Beraspal Panas

2019 ◽  
Vol 24 (2) ◽  
pp. 148
Author(s):  
Sri Mulyani ◽  
Nono Nono ◽  
Nyoman Suaryana
Keyword(s):  
Heavy Traffic ◽  
Permanent Deformation ◽  
Crumb Rubber ◽  
High Viscosity ◽  
Asphalt Mixtures ◽  
Modified Asphalt ◽  
Low Viscosity ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Rubber Modification

Asphalt polymer has superior characteristics than conventional asphalt. Styrene Butadiene Styrene (SBS) is a polymer that has proven its performance in heavy traffic, but it must be imported and expensive. Crumb rubber have high potential to be used as an asphalt modifier. Asphalt modified crumb rubber has high viscosity and is not homogeneous, so that the utilization cannot be delayed. This reduces workability in the field. This study aims to obtain asphalt modified crumb rubber which is easier to use by adding materials that do not affect its performance. RejIRE is a low viscosity additive to restore the properties of bitumen on crumb rubber modified. Experiments were carried out by adding variations in RejIRE levels to crumb rubber modified asphalt to determine its characteristics. Continued investigation of the performance of hot paved mixtures for wearing courses compared to asphalt mixtures with Pen 60/70 asphalt and SBS modified asphalt mixtures. The result is the addition of 0.75% RejIRE on asphalt crumb rubber modification have high workability. Overall the performance of the mix with SBS modified asphalt is better, but the mixture of hot paved with modified asphalt crumb rubber has a resistance to permanent deformation superior to the other paved mixtures.

Influence of Carbon Black on Storage Stability of HDPE-SBS Modified Asphalt

2011 ◽  
Vol 374-377 ◽  
pp. 1409-1413
Author(s):  
Xiao Wei Wu ◽  
Dong Wei Cao ◽  
Hai Yan Zhang
Keyword(s):  
Composite Material ◽  
Carbon Black ◽  
High Density Polyethylene ◽  
Storage Stability ◽  
High Density ◽  
Modified Asphalt ◽  
Stable Mechanism ◽  
The Difference ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt

In order to avoid the phase separation of the high density-polyethylene modified asphalt, a composite material modifier was prepared in the melt blending process with High density-Polyethylene (HDPE) and Styrene-butadiene-styrene (SBS) and a filler of Carbon black (CB). The storage stability of composite material (HDPE-SBS) modified asphalt was investigated by hot storage stability test and optical microscopic observation. The storage-stable mechanism of HDPE-SBS modified asphalt was analyzed also. The experimental results indicated that the difference of the softening point after storing at high temperature for 48h was very small. Micrographs of HDPE-SBS modified asphalt demonstrated that HDPE-SBS composite modifier particles dispersed uniformly and compactly and there were no obvious phase separations in the modified asphalt within a certain CB content range.

The Rejuvenating and Aging Performances of Aged SBS Modified Asphalt Treated by Different Rejuvenator Sealer Materials

2013 ◽  
Vol 753-755 ◽  
pp. 734-740 ◽  
Author(s):  
Li Wan ◽  
Shao Peng Wu ◽  
Min Lei ◽  
Kim Jenkins
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Economic Benefits ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Low Performance ◽  
Aged Binder ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

Currently, rejuvenator seal which is one of the preventive maintenance methods is more widely used due to its economic benefits and convenience. This paper described the chemical and rheological evaluation of the aged styrene butadiene styrene modified asphalt (ASMA) treated by two rejuvenator sealer materials (RSMs). First the ASMA was rejuvenated by mixing with the RSMs. Then the ASMA and two rejuvenated binders were re-aged by 10h PAV test. At last, the new binder, ASMA, rejuvenated ASMAs, re-aged binders were tested by Dynamic shear rheometer (DSR) and Fourier Transform Infrared Spectroscopy (FTIR). The results showed that the first aging of the new binder had a significant decrease of the low temperature performance and slight improvement of the high temperature performance. In addition, the high temperature performance increased obviously after 10h PAV test. Two RSMs could significantly soften the aged binder due to increase of maltene content existing in the RSMs, and the rejuvenated binder exhibited a better low performance after the 10h PAV test. However they cannot restore the low temperature completely because that RSMs cannot remedy the degradation of SBS modifier and remove the carbonyl produced in the aging progress.

Behavior of Carbon Nano-Tubes (CNTs) as Modifier to Resist Aging and Moisture Damage in Asphalt

2020 ◽  
Vol 10 ◽  
Author(s):  
Md Arifuzzaman ◽  
R. A. Tarefder ◽  
Muhammad Saiful Islam
Keyword(s):  
Asphalt Binder ◽  
Moisture Damage ◽  
Crumb Rubber ◽  
Outdoor Environment ◽  
Adhesion Forces ◽  
Modified Asphalt ◽  
Road Pavement ◽  
Carbon Nano Tubes ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt

Background: Moisture damage and aging take place together in asphalt binder as it is on road-pavement in service life and therefore quite difficult to overcome. Various techniques, such as crumb rubber, fibres, etc., have been applied to improve the behaviour of asphalt materials Use of nano materials was found as one of the effective techniques to develop temperature performances of asphalt binder. Methods: This study investigated moisture damage and aging of asphalt binder mixing with the carbon nano tubes (CNTs) using Atomic Force Microscopy (AFM). The base binder was primarily modified with 4% SBS polymer. Later on, CNTs were mixied in different percentages (i.e., 0.5%, 1%, and 1.5%) by weight with the 4% styrene–butadiene–styrene (SBS) modified binders. A special functionalized (-NH3) AFM probe with spring constant 3.44 N/m was utilised to complete the study. Results: The results were compared with 4% SBS modified asphalt with and without CNT addition.The adhesion forces of dry samples were found smaller as compared to wet and aged asphalt samples of with and without CNT. However, the adhesion forces of wet and aged samples with investigated percentage of CNT performed considerably better than those without CNT. Conclusion: This result clearly indicated significant improvement of asphalt to overcome moisture damage and aging owing to exposure in outdoor environment as a paving material. This study recommends any dosage (i.e., 0.5 to 1.5% by weight) of CNT with 4% SBS modified asphalt to resist moisture damage and aging in field.

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