scholarly journals Investigation of the Kinetic Regularities of the Process of Biodegradation of Betaine Surfactant by Bacteria of the Genus Pseudomonas

2021 ◽  
Vol 11 (19) ◽  
pp. 8939
Author(s):  
Anastasia S. Burlachenko ◽  
Olesya V. Salishcheva ◽  
Lyubov S. Dyshlyuk ◽  
Alexander Y. Prosekov
Keyword(s):  
Kinetic Data ◽  
Industrial Wastewater ◽  
Surfactant Concentration ◽  
Time Interval ◽  
Organic Substances ◽  
High Concentration ◽  
First Order ◽  
High Concentrations ◽  
Biological Decomposition ◽  
Toxic Organic Substances

Surfactants are extremely common organic compounds that enter the environment in large quantities in the form of household and industrial wastewater. The toxicity of surfactants for biological systems, the high concentration of substances and the duration of the bioremediation process of polluted ecosystems requires improving the biotechnology of microbial wastewater treatment for surfactants. The purpose of this work is to study the kinetic laws of the reaction of the biological decomposition of betaine surfactants. Pseudomonas bacteria were used as bio-destructors of the surfactants. Kinetic data were obtained to create the possibility of further optimization of research on the biodegradation of toxic organic substances. The strains that were promising destructors of cocamidopropylbetaine were selected. The toxicity of high concentrations of surfactants in relation to microorganisms of the genus Pseudomonas was proven. Safe values of the surfactant concentration for conducting biodegradation tests were found. A kinetic model of the biodestructive process was constructed. It proves that the processes of biodegradation are described by a kinetic equation of the first order. With the derived equation, it is possible to determine the time interval of biodegradation of cocamidopropylbetaine to the specified values by means of mathematical calculations.

Alkaline Activated Material as the Adsorbent for Uptake of High Concentration of Zinc from Wastewater

2016 ◽  
Vol 721 ◽  
pp. 123-127 ◽  
Author(s):  
Kamila Gruskevica ◽  
Girts Bumanis ◽  
Kristina Tihomirova ◽  
Diana Bajare ◽  
Tālis Juhna
Keyword(s):  
Industrial Waste ◽  
Industrial Wastewater ◽  
Cementitious Material ◽  
Organic Substances ◽  
New Materials ◽  
Binding Agent ◽  
High Concentration ◽  
Complex Composition ◽  
Standard Solution ◽  
Post Industrial

The use of wastes for developing of new materials is a sustainable approach. In current study filter media produced from industrial waste was tested for an ability to decrease high concentration of zinc in standard solution and industrial wastewater. The geopolymer production requires mixing of post-industrial waste with naturally occurred aluminosilicate materials by using binding agent at the ambient or slightly increased temperature in order to produce a long lasting eco-friendly cementitious material. The tested media decreased concentration of zinc in standard solution from 72,9 to 19,6 mg/L in 30 min showing similar performance as commercially available zeolite material. In experiments with wastewater the adsorption of Zn by AAM was much lower, which can be explained by the fact that wastewater contained generous amounts of different metal ions, organic substances and oils. Despite complex composition of wastewater AAM was able to immobilize at minimum 22 mg/L (32%) Zn from the solution.

scholarly journals A model of bubble coalescence in the presence of a nonionic surfactant with a low bubble approach velocity

2021 ◽  
Author(s):  
Yuelin Wang ◽  
Huahai Zhang ◽  
Tiefeng Wang
Keyword(s):  
Nonionic Surfactant ◽  
Surfactant Concentration ◽  
Bubble Coalescence ◽  
Bulk Concentration ◽  
High Concentration ◽  
Coalescence Time ◽  
Approach Velocity ◽  
Marangoni Stress ◽  
High Concentrations ◽  
High Concentration Range

A bubble coalescence model for a solution with a nonionic surfactant and with a small bubble approach velocity was developed, in which the mechanism of how coalescence is hindered by Marangoni stress was quantitatively analyzed. The bubble coalescence time calculated for ethanol-water and MIBC-water systems were in good agreement with experimental data. At low surfactant concentrations, the Marangoni stress and bubble coalescence time increased with bulk concentration increase. Conversely, in the high concentration range, the Marangoni stress and coalescence time decreased with bulk concentration. Numerical results showed that the nonlinear relationship between coalescence time and surfactant concentration is determined by the mass transport flux between the film and its interface, which tends to diminish the spatial concentration variation of the interface, i.e., it acts as a “damper”. This damping effect increases with increased surfactant concentration, therefore decreasing the coalescence time at high concentrations.

scholarly journals Study of initial stage of mechanochemical transformation in pyrite

2007 ◽  
Vol 43 (1) ◽  
pp. 57-70 ◽  
Author(s):  
D. Paneva ◽  
D. Mitova ◽  
E. Manova ◽  
H. Kolev ◽  
B. Kunev ◽  
...  
Keyword(s):  
Powder Diffraction ◽  
Photoelectron Spectroscopy ◽  
Kinetic Data ◽  
Time Interval ◽  
X Ray ◽  
First Order ◽  
Initial Stage ◽  
Mechanochemical Transformation ◽  
Shrinking Core ◽  
Core Reaction

The initial stage of transformation of pyrite to Fe(II)-sulfate as a result of mechanical milling is studied by X-ray powder diffraction (XRD), Moessbauer spectroscopy (MS), Infrared (IR) and X-ray photoelectron spectroscopy (XPS) techniques. A degree of conversion of 0.071 is achieved in the time interval of 0 36 min. The kinetic data satisfy the equation of a shrinking core reaction 1-(1-?)1/3=kt. The reaction is of the first order. The calculated rate constant is k=6.434.10-4 min-1. .

scholarly journals Determination of the diffusion coefficient of some highly toxic organic substances by using a diffusion tube CA Hemijska industrija

2003 ◽  
Vol 57 (1) ◽  
pp. 9-14
Author(s):  
Jelena Bastic ◽  
Dejan Skala ◽  
Slavica Ivanovic
Keyword(s):  
Diffusion Coefficient ◽  
Gas Phase ◽  
Flow Rate ◽  
Dynamic Method ◽  
Time Interval ◽  
Test Substance ◽  
Organic Substances ◽  
Toxic Organic Substances ◽  
Diffusion Tube

The determination of specific characteristics of materials commonly used in the preparation of cloths for the protection of the human body, lungs and other human organs, based on the principles of the effective adsorption of highly toxic organic vapors initially requires the development of specific and reliable techniques for the preparation of a gas stream with the relevant highly toxic organic substances. The dynamic method, one of the techniques commonly used for material characterization, is based on the procedure of determining the concentration of different substances in the gas stream at the inlet and after passing through a specific thin layer of the adsorption material (outlet). Therefore, the generation of a gas phase containing highly toxic organic substances in a defined quantity during a specific time interval, is the requirement that must previously be fulfilled before using the dynamic method for testing specific materials for protection of the human body. Usually, a dynamic method of determining the quality of cloths prepared with specific adsorbents requires a relatively low volumetric flow rate of the gas phase containing the test substance which may be achieved by using a diffusion tube (DT) as the standard equipment for the generation of test substances. A very wide range of concentrations of the test substances in a specific gas phase (inert, air) can be obtained by varying the working conditions (temperature, pressure, gas flow rate) and the geometrical size of the diffusion tube, taking into account that the concentration of toxic substances, is determined as the ratio of their diffusion rate and from the DT and the carrier gas flow rate. The diffusion rate of the test substances from the DT is caused by the concentration gradient between the partial pressure of the saturated vapor at one end of the DT capillary and the partial pressure at the outlet of the diffusion tube according to Fick's law. The mass rate of the generated test substances from the DT is constant for constant conditions (temperature and pressure) in the reservoir of the DT On the basis of a detailed theoretical calculation such a rate (R) may be defined by the equation: R = 16.624 DM(P/T)(A/L)log [P/(P- pv)l, mg/min where: D - the diffusion coefficient, cm/s; M - the molar mass of the test substance, g/mol; P - the pressure in the DT kPa; pv - the vapor pressure of the test substance, kPa; A - the cross sectional area of the capillary of the DT cm2: L - the length of the capillary of the DT cm; T - the temperature, K. A procedure for the constant isothermal vapor generation of hydrogen cyanide (HCN) and 2-bromo-2-chloro-1,1,1-trifluoroethane (halotane) into air by a using diffusion tube is described. The DT was placed into a thermostat 0.5?C) and the diffusion rates of the substance were measured during some time interval and the above equation was used for the determination of the diffusion coefficient. The obtained data were correlated with the calculated ones on the basis of an empirical correlation from the literature. The relative differences in the experimentally determined and theoretically calculated values of the diffusion coefficient for hydrogen cyanide at different temperature (19-23.2?C) were 26-31 % and for halotane (26-45?C) 8-14%.

scholarly journals Radiocatalytic degradation of dissolved organic compounds in wastewater

Nukleonika ◽  
2016 ◽  
Vol 61 (4) ◽  
pp. 473-476 ◽  
Author(s):  
Jaime Jiménez-Becerril ◽  
Anabel Moreno-López ◽  
Melania Jiménez-Reyes
Keyword(s):  
Organic Compounds ◽  
Mineral Content ◽  
Municipal Wastewater ◽  
Order Kinetic ◽  
Organic Substances ◽  
High Concentration ◽  
First Order ◽  
Gamma Radiolysis ◽  
Order Kinetic Model ◽  
Dissolved Organic Compounds

Abstract Wastewater containing a high concentration of organic substances was exposed to gamma radiolysis in the presence and absence of a catalyst (TiO2); radiolysis and radiocatalysis were performed by means of continuous and discontinuous irradiation. Dissolved organic carbon (DOC) was the parameter used to estimate the concentration of organic compounds without interference by the high mineral content. The data was well fitted to the pseudo-first-order kinetic model of Langmuir-Hinshelwood. From a [DOC]0 = 140 ± 7 mg/L, the higher DOC degradation (74%) and apparent rate constant (Kapp = 0.083 h-1) were found using discontinuous radiocatalysis. This process could be an alternative method of treatment of industrial or municipal wastewater

The Toxicity of Castor Beans and its Treatment with Doxycycline in Local Rabbits

2018 ◽  
Vol 9 (2) ◽  
Author(s):  
Nael Mohammed Sarheed ◽  
Osamah Faisal Kokas ◽  
Doaa Abd Alabas Muhammed Ridh
Keyword(s):  
Castor Bean ◽  
The Body ◽  
Control Group ◽  
High Concentration ◽  
Biochemical Tests ◽  
Doxycycline Treatment ◽  
High Concentrations ◽  
Physiological Tests ◽  
Animal House ◽  
Physiological And Biochemical

The plant of castor is widely spread in the Iraqi land, and characterized with containing ricin toxin, which has a very serious effects, and because the seeds of this plant scattered in the agricultural soil and rivers water, which increases the exposure of humans and animals to these beans. Objective: This experiment was designed to study the effect of high concentration of castor bean powder in some physiological and biochemical parameters and changes in some tissues of the body, as well as trying to use doxycycline to reduce the effects of ingestion of these seeds. Materials and Methods: In the experiment, 24 local rabbits were raised and fed in the Animal House of the Faculty of Medicine / Al-Muthanna University, then divided into four groups and treated for three weeks (21 days), Control group: treated with normal saline solution (0.9) orally throughout the experiment, G1: was treated orally with a concentration of 25 mg / kg of castor bean powder daily during the experiment, G2 : orally treated 25 mg / kg of castor bean and 25 mg / kg of doxycycline, G3: orally treated 25 mg / kg of castor powder with 50 mg / kg of doxycycline daily throughout the trial period. Results: The results of the experiment showed significant changes (P less than 0.05) in all physiological and biochemical blood tests when compared with control group. There was a significant decrease in PCV, Hb, RBC, T.protein and body weights, while demonstrated a significant increase in WBC, Urea, Creatinine, ALT, AST and ALP, with distortions in liver and kidney of animals that treated with Castor beans. In contrast, the treatment with doxycycline and caster beans showed significant improvement reflected by a normal proportion in physiological tests and biochemical tests with improvement in the tissues when compared to control group. Conclusions: It can be concluded from this study that castor bean has high toxic and pathogenic effects that may be dangerous to the life of the organism. Therefore, it is advisable to be cautious of these pills and avoid exposure to them, also recommended to take high concentrations of doxycycline treatment when infected with castor bean poisoning.

The Effects of Shock Vancomycin Concentrations on the Formation of Heteroresistance in Staphylococcus aureus

2020 ◽  
Vol 65 (9-10) ◽  
pp. 3-7
Author(s):  
V. V. Gostev ◽  
Yu. V. Sopova ◽  
O. S. Kalinogorskaya ◽  
M. E. Velizhanina ◽  
I. V. Lazareva ◽  
...  
Keyword(s):  
Staphylococcus Aureus ◽  
In Vitro Selection ◽  
Methicillin Resistant Staphylococcus Aureus ◽  
High Concentration ◽  
Short Term ◽  
High Concentrations ◽  
Selection Of ◽  
Selection Of Resistance ◽  
Test Cultures

Glycopeptides are the basis of the treatment of infections caused by MRSA (Methicillin-Resistant Staphylococcus aureus). Previously, it was demonstrated that antibiotic tolerant phenotypes are formed during selection of resistance under the influence of high concentrations of antibiotics. The present study uses a similar in vitro selection model with vancomycin. Clinical isolates of MRSA belonging to genetic lines ST8 and ST239, as well as the MSSA (ATCC29213) strain, were included in the experiment. Test isolates were incubated for five hours in a medium with a high concentration of vancomycin (50 μg/ml). Test cultures were grown on the medium without antibiotic for 18 hours after each exposure. A total of ten exposure cycles were performed. Vancomycin was characterized by bacteriostatic action; the proportion of surviving cells after exposure was 70–100%. After selection, there was a slight increase in the MIC to vancomycin (MIC 2 μg/ml), teicoplanin (MIC 1.5–3 μg/ml) and daptomycin (MIC 0.25–2 μg/ml). According to the results of PAP analysis, all strains showed an increase in the area under curve depending on the concentration of vancomycin after selection, while a heteroresistant phenotype (with PAP/AUC 0.9) was detected in three isolates. All isolates showed walK mutations (T188S, D235N, E261V, V380I, and G223D). Exposure to short-term shock concentrations of vancomycin promotes the formation of heteroresistance in both MRSA and MSSA. Formation of VISA phenotypes is possible during therapy with vancomycin.

Growth responses of periphyton and chironomids exposed to biologically treated bleached kraft pulp mill effluent

1997 ◽  
Vol 35 (2-3) ◽  
pp. 339-345 ◽  
Author(s):  
M. G. Dubé ◽  
J. M. Culp
Keyword(s):  
Kraft Pulp ◽  
Pulp Mill ◽  
Pulp Mill Effluent ◽  
Growth Responses ◽  
High Concentration ◽  
Wood Extractives ◽  
Kraft Pulp Mill ◽  
Bleached Kraft Pulp ◽  
Low Levels ◽  
High Concentrations

Experiments were conducted in artificial streams to determine the effects of increasing concentrations of biologically treated bleached kraft pulp mill effluent (BKPME) on periphyton and chironomid growth in the Thompson River, British Columbia. Periphyton growth, as determined by increases in chlorophyll a, was significantly stimulated at all effluent concentrations tested (0.25%, 0.5%, 1.0%, 5.0% and, 10.0%). Chironomid growth (individual weight) was also significantly stimulated at low effluent concentrations (≤1.0%). At higher concentrations (5.0% and 10.0%), chironomid growth was inhibited relative to the 1.0% treatment streams. Increases in growth were attributed to the effects of nutrient and organic enrichment from BKPME. The effluent contained high concentrations of phosphorus and appears to be an important source of carbon for benthic insects grazing on the biofilm. In high concentration effluent streams, chironomid growth decreased despite low levels of typical pulp mill contaminants. This suggests that other compounds in the effluent, such as wood extractives, may be inhibiting chironomid growth. These results support findings of field monitoring studies conducted in the Thompson River where changes in periphyton and chironomid abundance occurred downstream of the bleached kraft pulp mill.

scholarly journals Spatial Analysis (Measurements at Heights of 10 m and 20 m above Ground Level) of the Concentrations of Particulate Matter (PM10, PM2.5, and PM1.0) and Gaseous Pollutants (H2S) on the University Campus: A Case Study

Atmosphere ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 62
Author(s):  
Robert Cichowicz ◽  
Maciej Dobrzański
Keyword(s):  
Spatial Distribution ◽  
Hydrogen Sulfide ◽  
Particulate Matter ◽  
Air Quality ◽  
Spatial Analysis ◽  
Ground Level ◽  
Leeward Side ◽  
High Concentration ◽  
Above Ground Level ◽  
High Concentrations

Spatial analysis of the distribution of particulate matter PM10, PM2.5, PM1.0, and hydrogen sulfide (H2S) gas pollution was performed in the area around a university library building. The reasons for the subject matter were reports related to the perceptible odor characteristic of hydrogen sulfide and a general poor assessment of air quality by employees and students. Due to the area of analysis, it was decided to perform measurements at two heights, 10 m and 20 m above ground level, using measuring equipment attached to a DJI Matrice 600 unmanned aerial vehicle (UAV). The aim of the measurements was air quality assessment and investigate the convergence of the theory of air flow around the building with the spatial distribution of air pollutants. Considerable differences of up to 63% were observed in the concentrations of pollutants measured around the building, especially between opposite sides, depending on the direction of the wind. To explain these differences, the theory of aerodynamics was applied to visualize the probable airflow in the direction of the wind. A strong convergence was observed between the aerodynamic model and the spatial distribution of pollutants. This was evidenced by the high concentrations of dust in the areas of strong turbulence at the edges of the building and on the leeward side. The accumulation of pollutants was also clearly noticeable in these locations. A high concentration of H2S was recorded around the library building on the side of the car park. On the other hand, the air turbulence around the building dispersed the gas pollution, causing the concentration of H2S to drop on the leeward side. It was confirmed that in some analyzed areas the permissible concentration of H2S was exceeded.

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