scholarly journals Impact of Chelating Agent Salt Type on the Enhanced Oil Recovery from Carbonate and Sandstone Reservoirs

2021 ◽  
Vol 11 (15) ◽  
pp. 7109
Author(s):  
Amjed Hassan ◽  
Mohamed Mahmoud ◽  
Shirish Patil
Keyword(s):  
Contact Angle ◽  
Acetic Acid ◽  
Oil Recovery ◽  
Chelating Agents ◽  
Chelating Agent ◽  
Recovery Process ◽  
Rock Surface ◽  
Dynamic Adsorption ◽  
Sandstone Reservoirs ◽  
The Impact

In this paper, chelating agents were introduced as standalone fluids for enhancing the oil recovery from carbonate and sandstone reservoirs. Chelating agents such as glutamic acid di-acetic acid (GLDA), ethylene-diamine-tetra acetic acid (EDTA), and hydroxyl-ethylethylene-diamine-tri-acetic acid (HEDTA) were used. Chelating agents can be found in different forms such as sodium, potassium, or calcium salts. There is a significant gap in the literature about the influence of salt type on the hydrocarbon recovery from carbonate and sandstone reservoirs. In this study, the impact of the salt type of GLDA chelating agent on the oil recovery was investigated. Potassium-, sodium-, and calcium-based high-pH GLDA solutions were used. Coreflooding experiments were conducted at high-pressure high-temperature (HPHT) conditions using carbonate and sandstone cores. The used samples had porosity values of 15%–18%, and permeability values were between 10 and 75 mD. Seawater was injected as a secondary recovery process. Thereafter, a GLDA solution was injected in tertiary mode, until no more oil was recovered. In addition to the recovery experiments, the collected effluent was analyzed for cations concentrations such as calcium, magnesium, and iron. Moreover, dynamic adsorption, interfacial tension, and contact angle measurements were conducted for the different forms of GLDA chelating agent solutions. The results of this study showed that incremental oil recovery between 19% and 32% of the Original Oil in Place (OOIP) can be achieved, based on the salt type and the rock lithology. Flooding carbonate rocks with the calcium-based GLDA chelating agent yielded the highest oil recovery (32% of OOIP), followed by that with potassium-based GLDA chelating agent, and the sodium-based GLDA chelating agent yielded the lowest oil recovery. The reason behind that was the adsorption of the calcium-based GLDA on the rock surface was the highest without reducing the rock permeability, which was indicated by the contact angle, dynamic adsorption, and flooding experiments. The outcome of this study will help in maximizing the oil recovery from carbonate and sandstone reservoirs by suggesting the most suitable salt type of chelating agents.

Wettability Alteration of Dolomite Rock Using Nanofluids for Enhanced Oil Recovery

2016 ◽  
Vol 864 ◽  
pp. 194-198 ◽  
Author(s):  
Mohd Shahrizan Moslan ◽  
Wan Rosli Wan Sulaiman ◽  
Abdul Razak Ismail ◽  
Mohd Zaidi Jaafar ◽  
Issham Ismail
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Ion Pairs ◽  
Adsorption Rate ◽  
Wettability Alteration ◽  
Rock Surface ◽  
Wet Condition ◽  
The Impact

Wettability alteration of rock by surfactant has been considered as feasible method for recovery of oil reservoirs by modifying the wettability of rock surface from oil-wet to water-wet condition. The impact of surfactant can be enhanced by adding nanoparticles. Cationic surfactant performed well in carbonate rock by forming ion pairs between cationic head and acidic component of the crude. Meanwhile, nanoparticles will form continuous wedge film between the liquid and solid surface. In this paper, Al2O3 and ZrO2 nanoparticles were used as enhanced oil recovery (EOR) agents. The impact of these two nanoparticles on contact angle and interfacial tension was studied. Besides that, adsorption Cetyltrimethylammonium Bromide (CTAB) surfactant on rock surface was also investigated. The results show a significant change in water-oil contact angle after application of surfactant and nanoparticles. Initial water-oil contact angle for 6 dolomites demonstrate oil-wet condition. Then, the dolomites were submerged in prepared solution for 48 hours. The result shows that, dolomites 2, 5 and 6 changes drastically to more water-wet condition with contact angle 56°, 40° and 47° respectively. For surfactant adsorption, the adsorption is very fast at the beginning. The adsorption rate after 5 minutes was 50 mg/g and after 60 minutes the adsorption rate was 310 mg/g. The adsorption rate slowed down after 60 minutes and after 180 minutes the adsorption rate was 315 mg/g in which the rate of adsorption achieve equilibrium. Nanoparticles retention test and Zeta potential shows that Al2O3 is more stable than ZrO2. The results for interfacial tension (IFT) also show a significant reduction. The IFT value reduces from 8.46 mN/m to 1.65 mN/m and 1.85 mN/m after the application of Al2O3 and ZrO2 nanofluids respectively

scholarly journals Carbon dioxide adsorption and interaction with formation fluids of Jordanian unconventional reservoirs

2021 ◽  
Author(s):  
H. Samara ◽  
T. V. Ostrowski ◽  
F. Ayad Abdulkareem ◽  
E. Padmanabhan ◽  
P. Jaeger
Keyword(s):  
Carbon Dioxide ◽  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Gas Adsorption ◽  
Sessile Drop ◽  
Global Climate ◽  
Gravimetric Method ◽  
Rock Surface ◽  
Operating Pressure

AbstractShales are mostly unexploited energy resources. However, the extraction and production of their hydrocarbons require innovative methods. Applications involving carbon dioxide in shales could combine its potential use in oil recovery with its storage in view of its impact on global climate. The success of these approaches highly depends on various mechanisms taking place in the rock pores simultaneously. In this work, properties governing these mechanisms are presented at technically relevant conditions. The pendant and sessile drop methods are utilized to measure interfacial tension and wettability, respectively. The gravimetric method is used to quantify CO2 adsorption capacity of shale and gas adsorption kinetics is evaluated to determine diffusion coefficients. It is found that interfacial properties are strongly affected by the operating pressure. The oil-CO2 interfacial tension shows a decrease from approx. 21 mN/m at 0.1 MPa to around 3 mN/m at 20 MPa. A similar trend is observed in brine-CO2 systems. The diffusion coefficient is observed to slightly increase with pressure at supercritical conditions. Finally, the contact angle is found to be directly related to the gas adsorption at the rock surface: Up to 3.8 wt% of CO2 is adsorbed on the shale surface at 20 MPa and 60 °C where a maximum in contact angle is also found. To the best of the author’s knowledge, the affinity of calcite-rich surfaces toward CO2 adsorption is linked experimentally to the wetting behavior for the first time. The results are discussed in terms of CO2 storage scenarios occurring optimally at 20 MPa.

Chelating-Agent Enhanced Oil Recovery for Sandstone and Carbonate Reservoirs

SPE Journal ◽  
2015 ◽  
Vol 20 (03) ◽  
pp. 483-495 ◽  
Author(s):  
M. A. Mahmoud ◽  
K. Z. Abdelgawad
Keyword(s):  
Zeta Potential ◽  
Oil Recovery ◽  
Chelating Agents ◽  
Water Injection ◽  
Chelating Agent ◽  
Carbonate Reservoirs ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water ◽  
Core Permeability

Summary Recently low-salinity waterflooding was introduced as an effective enhanced-oil-recovery (EOR) method in sandstone and carbonate reservoirs. The recovery mechanisms that use low-salinity-water injection are still debatable. The suggested possible mechanisms are: wettability alteration, interfacial-tension (IFT) reduction, multi-ion exchange, and rock dissolution. In this paper, we introduce a new chemical EOR method for sandstone and carbonate reservoirs that will give better recovery than the low-salinity-water injection without treating or diluting seawater. In this study, we introduce a new chemical EOR method that uses chelating agents such as ethylenediaminetetraacetic acid (EDTA), hydroxyethylethylenediaminetriacetic acid (HEDTA), and diethylenetriaminepentaacetic acid (DTPA) at high pH values. This is the first time for use of chelating agents as standalone EOR fluids. Coreflood experiments, interfacial and surface tensions, and zeta-potential measurements are performed with DTPA, EDTA, and HEDTA chelating agents. The chelating-agent concentrations used in the study were prepared by diluting the initial concentration of 40 wt% with seawater and injecting it into Berea-sandstone and Indiana-limestone cores of a 6-in. length and a 1.5-in. diameter saturated with crude oil. The coreflooding experiments were performed at 100°C and a 1,000-psi backpressure. Low-salinity-water and seawater injections caused damage to the reservoir because of the calcium sulfate scale deposition during the flooding process. The newly introduced EOR method did not cause calcium sulfate precipitation, and the core permeability was not affected. The core permeability was measured after the flooding process, and the final permeability was higher than the initial permeability in the case of chelating-agent injection. The coreflooding effluent was analyzed for cations with the inductively coupled plasma (ICP) spectroscopy to explain the dissolution-recovery mechanism. The effect of iron minerals on the rock-surface charge was investigated through the measurements of zeta potential for different rocks containing different iron minerals. HEDTA and EDTA chelating agents at 5 wt% concentration prepared in seawater were able to recover more than 20% oil from the initial oil in place from sandstone and carbonate cores. ICP measurements supported the rock-dissolution mechanism because the calcium, magnesium, and iron concentrations in the effluent samples were more than those in the injected fluids. The IFT-reduction mechanism was confirmed by the low IFT values obtained in the case of chelating agents. The type and concentration of chelating agents affected the IFT value. Higher concentrations yielded lower IFT values because of the increase in carboxylic-group concentration. We found that the high-pH chelating agents increased the negative value of zeta potential, which will change the rock toward more water-wet.

Effect of Chlorite Clay-Mineral Dissolution on the Improved Oil Recovery From Sandstone Rocks During Diethylenetriaminepentaacetic Acid Chelating-Agent Flooding

SPE Journal ◽  
2018 ◽  
Vol 23 (05) ◽  
pp. 1880-1898 ◽  
Author(s):  
Mohamed Ahmed El-Din Mahmoud
Keyword(s):  
Contact Angle ◽  
Surface Charge ◽  
Clay Minerals ◽  
Oil Recovery ◽  
Chelating Agent ◽  
Oil Reservoirs ◽  
Diethylenetriaminepentaacetic Acid ◽  
Improved Oil Recovery ◽  
Angle Measurements ◽  
Contact Angle Measurements

Summary Sandstone oil reservoirs consist of different clay minerals, such as kaolinite, illite, and chlorite. While these clay minerals can highly affect oil recovery from sandstone oil reservoirs, no attention has been given to investigating the effects of clay minerals during such oil recovery, and no solution has been introduced to alleviate the effects. In this study, and for the first time, the effect of chlorite clay-mineral content on the improved oil recovery (IOR) from different sandstone rock samples was investigated. A new solution was proposed to eliminate the effect of chlorite on the oil recovery from sandstone rocks. Different sandstone cores were used, such as Berea (BSS), Bandera (BND), Kentucky (KSS), and Scioto (SCS) sandstone rocks with different clay minerals. ζ-potential measurements were used to investigate the surface charge of the different clays and different sandstone rocks with different fluids. Fluids such as seawater (SW), low-salinity water (LSW), fresh water, and chelating agents were used. Diethylenetriaminepentaacetic acid (DTPA) chelating agent was introduced to mitigate the chlorite effect on oil recovery from sandstone rocks. The wettability was evaluated using contact-angle measurements and the Amott test for different solutions and different rocks in the presence of actual crude oil. Coreflooding experiments were conducted using these fluids with different sandstone rocks to identify the effect of chlorite on the oil recovery. Coreflooding experiments showed that sandstone cores with high chlorite content yielded the lowest oil recovery when SW and LSW were used. The effect of chlorite on the oil recovery from the two sandstone rocks was minimized with 3 wt% DTPA chelating agent. More oil was recovered in the case of DTPA because of the iron chelation from chlorite. ζ-potential showed that sandstone with high chlorite content has a surface charge close to zero in the case of SW and fresh water. In addition, contact-angle measurements showed that samples with high chlorite content have less water-wetness, which will reduce oil recovery. Contact-angle measurements on chlorite sheets showed that chlorite is oil-wet compared with mica at the same conditions. The addition of high-pH DTPA chelating agent sequestered the iron from the chlorite clay minerals and changed the surface charge to very high negative value, and the contact angle confirmed that the rock changed to water-wet after adding the chelating agent. The Amott index showed that adding DTPA increased the water-wetness for SCS that contains 4 wt% chlorite.

scholarly journals Comparative Study of Using Sea-Water for Enhanced Oil Recovery in Carbonate and Sandstone Reservoirs: Effects of Temperature and Aging Time on Oil Recovery

2018 ◽  
Vol 7 (2) ◽  
pp. 1-13
Author(s):  
Madi Abdullah Naser ◽  
Mohamed Erhayem ◽  
Ali Hegaig ◽  
Hesham Jaber Abdullah ◽  
Muammer Younis Amer ◽  
...  
Keyword(s):  
Aging Time ◽  
Oil Recovery ◽  
Sea Water ◽  
Essential Element ◽  
Recovery Process ◽  
Spontaneous Imbibition ◽  
Effect Of Temperature ◽  
Injection Process ◽  
Reservoir Conditions ◽  
The Impact

Oil recovery process is an essential element in the oil industry, in this study, a laboratory study to investigate the effect of temperature and aging time on oil recovery and understand some of the mechanisms of seawater in the injection process. In order to do that, the sandstone and carbonate cores were placed in the oven in brine to simulate realistic reservoir conditions. Then, they were aged in crude oil in the oven. After that, they were put in the seawater to recover, and this test is called a spontaneous imbibition test. The spontaneous imbibition test in this study was performed at room temperature to oven temperature 80 oC with different sandstone and carbonate rock with aging time of 1126 hours. The result shows that the impact of seawater on oil recovery in sandstone is higher than carbonate. At higher temperature, the oil recovery is more moderate than low temperature. Likewise, as the aging time increase for both sandstone and carbonate rocks the oil recovery increase. 

scholarly journals Decontamination of Nickel Toxicity of Soil by Chelate Assisted Remediation using Brachiaria Mutica (FORSSK.) STAPF

2019 ◽  
Vol 8 (3) ◽  
pp. 8199-8203
Keyword(s):  
Acetic Acid ◽  
Contaminated Soils ◽  
Metal Uptake ◽  
Chelating Agents ◽  
Chelating Agent ◽  
Cost Effective ◽  
Wild Plant ◽  
Treated Soil ◽  
Cost Effective Method ◽  
Brachiaria Mutica

Phytoremediation is an environment friendly and cost effective method for remediation of heavy metals from contaminated soils by using plants. Chelate assisted metal uptake by plant has only been discovered in the sector of phytoremediation. It is a potential technology for accumulation of heavy metal by plants after application of chelating agents to soil which enhances the level of metal uptake in phytoremediation processes. Chelating agents are commonly used to form complexes with different metal contaminants within the natural environment. The novelty of this work is to reduce the pollution load by ecofriendly method. The research gap adresses in this study is the reduction of nickel pollution by using chelating agent. In this study two chelating agents namely EDTA (Ethylene diamine tetra acetic acid) and DTPA (Diethylene triamine penta acetic acid) were used along with the nickel treated soil and also with soil without containing nickel to determine the efficiency of decontamination by a wild plant "Para grass" [Brachiaria mutica (Forssk.) Stapf] towards phytoremediation of nickel. In this experiment it was observed that the plant which were subjected to grow in EDTA with nickel treated soil accumulated more nickel than the other two sets which were subjected to grow in nickel treated soil with DTPA and also without chelating agent.

scholarly journals An Experimental Investigation the Optimum of Salinity and Ph of Sea-Water to Improve Oil Recovery from Sandstone Reservoir as A Secondary Recovery Process

2020 ◽  
Vol 1 (2) ◽  
pp. 83
Author(s):  
Madi Abdullah Naser ◽  
Mohammed A Samba ◽  
Yiqiang Li
Keyword(s):  
Oil Recovery ◽  
Sea Water ◽  
Recovery Process ◽  
Water Flooding ◽  
Core Flooding ◽  
Low Salinity ◽  
Seawater Salinity ◽  
Secondary Recovery ◽  
Two Parameters ◽  
The Impact

Laboratory tests and field applications shows that the salinity of water flooding could lead to significant reduction of residual oil saturation. There has been a growing interest with an increasing number of low-salinity water flooding studies. However, there are few quantitative studies on seawater composition change and it impact on increasing or improving oil recovery.  This study was conducted to investigate only two parameters of the seawater (Salinity and pH) to check their impact on oil recovery, and what is the optimum amount of salinity and ph that we can use to get the maximum oil recovery.  Several core flooding experiments were conducted using sandstone by inject seawater (high, low salinity and different pH). The results of this study has been shown that the oil recovery increases as the injected water salinity down to 6500 ppm and when the pH is around 7. This increase has been found to be supported by an increase in the permeability. We also noticed that the impact of ph on oil recovery is low when the pH is less than 7.

scholarly journals A complete workflow applied on an oil reservoir analogue to evaluate the ability of 4D seismics to anticipate the success of a chemical enhanced oil recovery process

2020 ◽  
Vol 75 ◽  
pp. 18 ◽  
Author(s):  
Noalwenn Dubos-Sallée ◽  
André Fourno ◽  
Jeanneth Zarate-Rada ◽  
Véronique Gervais ◽  
Patrick N. J. Rasolofosaon ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Recovery Process ◽  
Seismic Monitoring ◽  
Reservoir Modeling ◽  
Chemical Eor ◽  
Outcrop Analog ◽  
4D Seismic ◽  
The Impact ◽  
Water Front

In an Enhanced Oil Recovery (EOR) process, one of the main difficulties is to quickly evaluate if the injected chemical products actually improve oil recovery in the reservoir. The efficiency of the process can be monitored in the vicinity of wells, but it may take time to estimate it globally in the reservoir. The objective of this paper is to investigate the ability of 4D seismics to bridge this gap and to help predict the success or breakdown of a production strategy at reservoir scale. To that purpose, we consider a complete workflow for simulating realistic reservoir exploitation using chemical EOR and 4D seismic modeling. This workflow spans from geological description to seismic monitoring simulation and seismic attributes analysis, through geological and reservoir modeling. It is applied here on a realistic case study derived from an outcrop analog of turbiditic reservoirs, for which the efficiency of chemical EOR by polymer and surfactant injection is demonstrated. For this specific field monitoring application, the impact of both waterflooding and proposed EOR injection is visible on the computed seismics. However, EOR injection induces a more continuous water front that can be clearly visible on seismics. In this case, the EOR efficiency can thus be related to the continuity of the water front as seen on seismics. Nevertheless, in other cases, chemical EOR injections may have more moderate impacts, or the field properties may be less adapted to seismic monitoring. This points out the importance of the proposed workflow to check the relevance of seismic monitoring and to design the most adapted monitoring strategy. Numerous perspectives are proposed at the end of the paper. In particular, experts of the different disciplines involved in the proposed workflow can benefit from the availability of a complete set of well-controlled data of various types to test and improve their own tools. In contrast, the non-experts can easily and quickly benefit from “hands-on” experiments for understanding the involved phenomena. Furthermore, the proposed workflow can be directly applied to geological reservoirs all over the world.

scholarly journals Numerical Simulation of Residual Oil Flooded by Polymer Solution in Microchannels

Geofluids ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Yang Liu ◽  
Jiawei Fan ◽  
Lili Liu ◽  
Shuren Yang
Keyword(s):  
Contact Angle ◽  
Polymer Solution ◽  
Oil Recovery ◽  
Wetting Angle ◽  
Polymer Flooding ◽  
Residual Oil ◽  
Receding Contact ◽  
Advancing Contact Angle ◽  
Receding Contact Angle ◽  
The Impact

This paper establishes a flow equation using non-Newtonian fluid mechanics and defines the deformation of residual oil using numerical computation in order to conduct a study on the flow law of residual oil in microchannels of rock during polymer flooding, the influence of flooding fluid elasticity on the deformation of residual oil, and flooding mechanism of viscoelastic displacing fluid. Computation shows that advancing contact angle increases and receding contact angle decreases as the viscosity ratio decreases. The higher elasticity of polymer solution with higher concentration or molecular weight leads to significantly more obvious deformation of residual oil and benefits migration and stripping of residual oil. The impact of the initial wetting angle of residual oil film on deformation is analyzed. A smaller initial wetting angle corresponds to a bigger change of advancing contact angle and smaller change of receding contact angle. A better understanding of the flooding process is gained via a study on residual oil deformation in polymer flooding. Consequently, oil flooding efficiency and oil recovery can be enhanced. This is the hydrodynamic mechanism of enhanced oil recovery (EOR) by polymer flooding.

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