scholarly journals Raman Spectrometry as a Tool for an Online Control of a Phototrophic Biological Nutrient Removal Process

2021 ◽  
Vol 11 (14) ◽  
pp. 6600
Author(s):  
Rita D. G. Franca ◽  
Virgínia C. F. Carvalho ◽  
Joana C. Fradinho ◽  
Maria A. M. Reis ◽  
Nídia D. Lourenço
Keyword(s):  
Raman Spectroscopy ◽  
Nutrient Removal ◽  
Latent Variables ◽  
Cross Validation ◽  
Online Monitoring ◽  
Biological Nutrient Removal ◽  
Raman Shift ◽  
Bioprocess Monitoring ◽  
Efficient Operation ◽  
Total P

Real-time bioprocess monitoring is crucial for efficient operation and effective bioprocess control. Aiming to develop an online monitoring strategy for facilitating optimization, fault detection and decision-making during wastewater treatment in a photo-biological nutrient removal (photo-BNR) process, this study investigated the application of Raman spectroscopy for the quantification of total organic content (TOC), volatile fatty acids (VFAs), carbon dioxide (CO2), ammonia (NH3), nitrate (NO3), phosphate (PO4), total phosphorus (total P), polyhydroxyalkanoates (PHAs), total carbohydrates, total and volatile suspended solids (TSSs and VSSs, respectively). Specifically, partial least squares (PLS) regression models were developed to predict these parameters based on Raman spectra, and evaluated based on a full cross-validation. Through the optimization of spectral pre-processing, Raman shift regions and latent variables, 8 out of the 11 parameters that were investigated—namely TOC, VFAs, CO2, NO3, total P, PHAs, TSSs and VSSs—could be predicted with good quality by the respective Raman-based PLS calibration models, as shown by the high coefficient of determination (R2 > 90.0%) and residual prediction deviation (RPD > 5.0), and relatively low root mean square error of cross-validation. This study showed for the first time the high potential of Raman spectroscopy for the online monitoring of TOC, VFAs, CO2, NO3, total P, PHAs, TSSs and VSSs in a photo-BNR reactor.

The significance of denitrifying polyphosphate accumulating organisms in biological nutrient removal activated sludge systems

2002 ◽  
Vol 46 (1-2) ◽  
pp. 129-138 ◽  
Author(s):  
Z.-R. Hu ◽  
M.C. Wentzel ◽  
G.A. Ekama
Keyword(s):  
Experimental Data ◽  
Activated Sludge ◽  
Nutrient Removal ◽  
P Uptake ◽  
Biological Nutrient Removal ◽  
Advantages And Disadvantages ◽  
Polyphosphate Accumulating Organisms ◽  
Very High ◽  
Total P ◽  
Activated Sludge Systems

In this paper the advantages and disadvantages of denitrifying PAOs (polyphosphat accumulating organisms) in conventional BNRAS (biological nutrient removal activated sludge) and external nitrification BNRAS (ENBNRAS) systems are evaluated, with experimental data exhibiting a range of anoxic P uptake from low (<10%) to very high (>60%). The results indicate that the specific denitrification rate of the PAOs on internally stored PHB COD is about 1/5th of that of the “ordinary” heterotrophic organisms on SBCOD, and the PAOs contribute little (maximum 20%) to the denitrification in BNRAS systems even when the anoxic P uptake is high (60% of the total P uptake). Considering the unpredictable nature of anoxic P uptake and the reduction in BEPR it causes compared with aerobic P uptake BEPR, it is concluded that anoxic P uptake does not add a significant advantage to the BNR system.

Spectrophotometric Techniques: A Versatile Tool for Bioprocess Monitoring

2020 ◽  
Vol 09 ◽  
Author(s):  
Chandni Chandarana ◽  
Jyoti Suthar ◽  
Aman Goyel
Keyword(s):  
Raman Spectroscopy ◽  
Online Monitoring ◽  
Uv Spectroscopy ◽  
Continuous Process ◽  
Review Article ◽  
Bioprocess Monitoring ◽  
Spectroscopic Methods ◽  
Sample Analysis ◽  
Online Analysis ◽  
Versatile Tool

Abstract:: Online analysis of bioprocesses by analytical spectroscopic methods is used to produce fast sample analysis. Bio-transformations are directly controlled by continuous process. It improves management of quality. Various methods for online analysis have been reported. This review article majorly covers applications for infrared (NIR and MIR); Fluorescence; Ultraviolet (UV) Spectroscopy and Raman Spectroscopy for online monitoring of bioprocesses.

Nutrient removal from industrial wastewater using single tank sequencing batch reactors

1997 ◽  
Vol 35 (6) ◽  
pp. 137-144 ◽  
Author(s):  
J. Keller ◽  
K. Subramaniam ◽  
J. Gösswein ◽  
P. F. Greenfield
Keyword(s):  
Nutrient Removal ◽  
Industrial Wastewater ◽  
Batch Reactor ◽  
Pilot Scale ◽  
Phosphorus Compounds ◽  
Biological Nutrient Removal ◽  
Batch Reactors ◽  
Nitrogen And Phosphorus ◽  
High Degree ◽  
Total P

Biological Nutrient Removal (BNR) has been developed in recent years to achieve high quality effluent in regards to carbon, nitrogen and phosphorus compounds. However, most of these results have been achieved on domestic sewage. In treating industrial wastewater, additional challenges are facing the process designer and operator due to the substantially higher concentrations of both carbon and nutrients. This research and demonstration project is addressing the issue for abattoir (slaughterhouse) effluent. The technology used should be as simple as possible yet still achieve a high degree of BNR. The process used in laboratory and pilot scale is a single tank Sequencing Batch Reactor (SBR). The results from the laboratory work have been excellent but have to be confirmed in the pilot plant studies. It was found that a certain degree of anaerobic pretreatment (e.g. in anaerobic ponds) can reduce part of the carbon concentration most efficiently while still leaving sufficient COD required for successful BNR. Despite high influent concentrations of approximately 190 mg L−1 N and 50 mg L−1 total P, good effluent quality of less than 20 mg L−1 N and less than 5 mg L−1 total P has been achieved. Furthermore the operation of the small SBR systems has proved to be simple and reliable.

PREDIKSI KUALITAS AIR SUNGAI CILIWUNG DENGAN MENGGUNAKAN ALGORITMA POHON KEPUTUSAN

2021 ◽  
Vol 12 (2) ◽  
Author(s):  
Mohammad Haekal ◽  
Henki Bayu Seta ◽  
Mayanda Mega Santoni
Keyword(s):  
Data Mining ◽  
Decision Tree ◽  
Cross Validation ◽  
Online Monitoring ◽  
Training Set ◽  
Microsoft Excel ◽  
Test Set

Untuk memprediksi kualitas air sungai Ciliwung, telah dilakukan pengolahan data-data hasil pemantauan secara Online Monitoring dengan menggunakan Metode Data Mining. Pada metode ini, pertama-tama data-data hasil pemantauan dibuat dalam bentuk tabel Microsoft Excel, kemudian diolah menjadi bentuk Pohon Keputusan yang disebut Algoritma Pohon Keputusan (Decision Tree) mengunakan aplikasi WEKA. Metode Pohon Keputusan dipilih karena lebih sederhana, mudah dipahami dan mempunyai tingkat akurasi yang sangat tinggi. Jumlah data hasil pemantauan kualitas air sungai Ciliwung yang diolah sebanyak 5.476 data. Hasil klarifikasi dengan Pohon Keputusan, dari 5.476 data ini diperoleh jumlah data yang mengindikasikan sungai Ciliwung Tidak Tercemar sebanyak 1.059 data atau sebesar 19,3242%, dan yang mengindikasikan Tercemar sebanyak 4.417 data atau 80,6758%. Selanjutnya data-data hasil pemantauan ini dievaluasi menggunakan 4 Opsi Tes (Test Option) yaitu dengan Use Training Set, Supplied Test Set, Cross-Validation folds 10, dan Percentage Split 66%. Hasil evaluasi dengan 4 opsi tes yang digunakan ini, semuanya menunjukkan tingkat akurasi yang sangat tinggi, yaitu diatas 99%. Dari data-data hasil peneltian ini dapat diprediksi bahwa sungai Ciliwung terindikasi sebagai sungai tercemar bila mereferensi kepada Peraturan Pemerintah Republik Indonesia nomor 82 tahun 2001 dan diketahui pula bahwa penggunaan aplikasi WEKA dengan Algoritma Pohon Keputusan untuk mengolah data-data hasil pemantauan dengan mengambil tiga parameter (pH, DO dan Nitrat) adalah sangat akuran dan tepat. Kata Kunci : Kualitas air sungai, Data Mining, Algoritma Pohon Keputusan, Aplikasi WEKA.

The invisible BNR plant provides high quality effluent and recreational area for densely populated urban area

2009 ◽  
Vol 4 (1) ◽  
Author(s):  
E. Choi ◽  
Z. Yun ◽  
K.S. Min
Keyword(s):  
Nutrient Removal ◽  
Operating Temperature ◽  
Treatment Plant ◽  
Ground Level ◽  
Biological Nutrient Removal ◽  
High Quality ◽  
Sand Filter ◽  
Sport Facilities ◽  
Final Effluent ◽  
Removal System

In a densely populated area, a large wastewater treatment plant (WWTP) has been constructed in the underground. The plant is practically “invisible” to visitors and neighbours, and the ground level is used as a park and sport facilities in order to avoid the “not in my backyard” phenomenon. The WWTP has a 5-stage biological nutrient removal system utilizing the denitrifying PAO (dPAO) with a step feed in order to treat the weak sewage with higher nutrient removal requirement. Although the underground installation could be expected to increase plant operating temperature, the temperature increase was only 1°C. The polished final effluent from a sand filter produced average TN and TP concentrations of 5.11 mg/L and 0.91 mg/L, respectively with SS concentrations of 0.61 mg/L, indicating that the dPAO system combined with sand filter effectively produced a high quality effluent.

Upgrading Wastewater Treatment Plants for Biological Nutrient Removal

1990 ◽  
Vol 22 (7-8) ◽  
pp. 53-60 ◽  
Author(s):  
B. Rabinowitz ◽  
T. D. Vassos ◽  
R. N. Dawson ◽  
W. K. Oldham
Keyword(s):  
Wastewater Treatment ◽  
Nutrient Removal ◽  
Wastewater Treatment Plants ◽  
Design Flow ◽  
Biological Nutrient Removal ◽  
Nitrogen And Phosphorus ◽  
Conventional Activated Sludge ◽  
Recent Developments ◽  
Removal Technology ◽  
Biological Nitrogen

A brief review of recent developments in biological nitrogen and phosphorus removal technology is presented. Guidelines are outlined of how current understanding of these two removal mechanisms can be applied in the upgrading of existing wastewater treatment plants for biological nutrient removal. A case history dealing with the upgrading of the conventional activated sludge process located at Penticton, British Columbia, to a biological nutrient removal facility with a design flow of 18,200 m3/day (4.0 IMGD) is presented as a design example. Process components requiring major modification were the headworks, bioreactors and sludge handling facilities.

Survey of filamentous populations in nutrient removal plants in four European countries

1998 ◽  
Vol 37 (4-5) ◽  
pp. 281-289 ◽  
Author(s):  
Dick H. Eikelboom ◽  
Andreas Andreadakis ◽  
Kjaer Andreasen
Keyword(s):  
Nutrient Removal ◽  
Seasonal Pattern ◽  
Plug Flow ◽  
Phosphate Removal ◽  
Particulate Fraction ◽  
Biological Nutrient Removal ◽  
Process Conditions ◽  
Minor Importance ◽  
Filamentous Microorganisms ◽  
Short Period

A joint EU research project aimed at solving activated sludge bulking in nutrient removal plants was initiated in 1993. The project started with a survey of the size and composition of the filamentous population in nutrient removal plants in Denmark, Germany, Greece and the Netherlands. The results show that biological nutrient removal process conditions indeed favour filamentous microorganisms in their competition with floc forming organisms. An increase in the size of the filamentous population resulted in a deterioration of the settling properties of the biomass, except for plants with Bio-P removal conditions. It is assumed that in the latter case the dense clusters of Bio-P bacteria increase the weight of the flocs, and compensate for the effect of the larger number of filaments. Although exceptions frequently occur, the following sequence in decreasing filamentous organism population size was observed for the process conditions indicated: - completely mixed + simultaneous denitrification; - completely mixed + intermittent aeration/denitrification; - alternating anoxic/oxic process conditions, with an anaerobic tank for biological phosphate removal (Bio-Denipho); - alternating anoxic/oxic process conditions (Bio-Denitro); - predenitrification The surveys provided little information about the effect of nutrient removal in plants with plug flow aeration basins. Simultaneous precipitation with aluminium salts nearly always resulted in a low number of filaments and a good settling sludge. The size of the filamentous organism population showed a seasonal pattern with a maximum in winter/early spring and a minimum during summer (in Greece: during autumn). This seasonal variation is primarily caused by the effect of the season on the population sizes of M. parvicella, N. limicola and Type 0092. M. parvicella is by far the most important filamentous species in nutrient removal plants. In Denmark only, Type 0041 also frequently dominates the filamentous population, but seldom causes severe bulking. Considering their frequency of occurrence, approx. 10 other filamentous micro-organisms are of minor importance. Growth of some of these species, viz. those which use soluble substrate, can be prevented by the introduction of Bio-P process conditions. M. parvicella and Type 0041 (and probably also Actinomycetes and the Types 1851 and 0092) seem to compete for the same substrates i.e. the influent particulate fraction. Most of the differences in composition of the filamentous microorganism population can be explained by whether or not premixing of influent and recycled sludge is used. In general, premixing for a short period of time followed by anoxic conditions favours Type 0041. M. parvicella seems to proliferate if the particulate fraction is first hydrolysed or if it enters the plant via an oxic zone. It is concluded that bulking in nutrient removal plants is mainly caused by filamentous species requiring the particulate fraction for their growth.

Effect of addition of anaerobic fermented OFMSW (organic fraction of municipal solid waste) on biological nutrient removal (BNR) process: preliminary results

1998 ◽  
Vol 38 (1) ◽  
pp. 327-334 ◽  
Author(s):  
P. Pavan ◽  
P. Battistoni ◽  
P. Traverso ◽  
A. Musacco ◽  
F. Cecchi
Keyword(s):  
Nutrient Removal ◽  
Fermentation Process ◽  
Organic Waste ◽  
Anaerobic Fermentation ◽  
Pilot Scale ◽  
Biological Nutrient Removal ◽  
Organic Fraction ◽  
P Release ◽  
Pure Methanol ◽  
P Removal

The paper presents results coming from experiments on pilot scale plants about the possibility to integrate the organic waste and wastewater treatment cycles, using the light organic fraction produced via anaerobic fermentation of OFMSW as RBCOD source for BNR processes. The effluent from the anaerobic fermentation process, with an average content of 20 g/l of VFA+ lactic acid was added to wastewater to be treated in order to increase RBCOD content of about 60-70 mg/l. The results obtained in the BNR process through the addition of the effluent from the fermentation unit are presented. Significant increase of denitrification rate was obtained: 0.06 KgN-NO3/KgVSS d were denitrified in the best operative conditions studied. -Vmax shows values close to those typical of the pure methanol addition (about 0.3 KgN-NO3/KgVSS d). A considerable P release (35%) was observed in the anaerobic step of the BNR process, even if not yet a completely developed P removal process.

Experience with nutrient removal in a fixed-film system at full-scale wastewater treatment plants

1997 ◽  
Vol 36 (1) ◽  
pp. 129-137 ◽  
Author(s):  
Vibeke R. Borregaard
Keyword(s):  
Wastewater Treatment ◽  
Surface Area ◽  
Nutrient Removal ◽  
Wastewater Treatment Plants ◽  
High Specific Surface Area ◽  
Biological Nutrient Removal ◽  
Growth Processes ◽  
Total N ◽  
Attached Growth ◽  
On Line

In the upgrade of wastewater treatment plants to include biological nutrient removal the space available is often a limiting facor. It may be difficult to use conventional suspended growth processes (i.e. activated sludge) owing to the relatively large surface area required for these processes. Recent years have therefore seen a revived interest in treatment technologies using various types of attached growth processes. The “new” attached growth processes, like the Biostyr process, utilise various kinds of manufactured media, e.g. polystyrene granules, which offer a high specific surface area, and are therefore very compact. The Biostyr plants allow a combination of nitrification-denitrification and filtration in one and the same unit. The results obtained are 8 mg total N/l and an SS content normally below 10 mg/l. The plants in Denmark which have been extended with a Biostyr unit have various levels of PLC control and on-line instrumentation.

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