scholarly journals Hydrogen Permeability of Epoxy Composites as Liners in Lined Rock Caverns—Experimental Study

2021 ◽  
Vol 11 (9) ◽  
pp. 3885
Author(s):  
Dawid Gajda ◽  
Marcin Lutyński
Keyword(s):  
Hydrogen Storage ◽  
Epoxy Resin ◽  
Hydrogen Permeability ◽  
Gas Storage ◽  
Green Energy ◽  
Creep Process ◽  
Polymer Concrete ◽  
Salt Rock ◽  
Liner Material ◽  
Rock Cavern

Energy production from renewable energy sources is not stable and any fluctuations in energy productions need to be eliminated with underground energy storage. Demand of underground gas storage will be increasing, due to the switching to green energy, while the availability of underground storage sites, especially salt caverns suitable for hydrogen storage, is limited. The purpose of this paper is to compare the hydrogen permeability of different materials and select a proper liner material for hydrogen storage in Liner Rock Caverns or post mine workings. A variety of materials, like concrete, polymer concrete, epoxy resin, salt rock, and mudstone, were tested for gas permeability/hydrogen diffusion, using the combined Steady-State Flow/Carrier Gas methods. Results are shown in different units, providing the opportunity to compare the results with literature data. The permeability value of investigated epoxy resin is comparable to the salt rock (after creep process), which makes the epoxy resin a promising sealing liner for hydrogen and potential substitution of stainless-steel in Lined Rock Cavern (LRC) gas storage.

Failure Probability of Salt Rock Underground Gas Storage Cavern Based on Random Field Model of Material Parameters

2010 ◽  
Vol 163-167 ◽  
pp. 3336-3342
Author(s):  
Jian Liu ◽  
Juan Song ◽  
Qiang Yong Zhang
Keyword(s):  
Random Field ◽  
Failure Probability ◽  
Field Model ◽  
Gas Storage ◽  
Middle Part ◽  
Salt Rock ◽  
Underground Gas Storage ◽  
Random Field Model ◽  
Material Parameters ◽  
Rock Cavern

For the safety of salt rock underground gas storage cavern, uncertainties of material parameters and their influence to structure must be considered. In this paper, random field method is used for failure probability analysis of gas storage cavern. Random field model of material parameters is introduced firstly, local average method is used in discretization of random field, then Monte-Carlo stochastic finite element method is used in failure probability calculation. Conclusions can be drawn as follow: Failure probability in middle part of the cavern is higher than that of upside and underside, and failure probability decreases when operation pressure increasing. Middle part of cavern in release process is the most dangerous. Failure probability of cavern computed by random field model and random variable model based on response surface method are campared. It is obviously that failure prabability computed by random field is lower than that of by RSM. As variation coefficient and fluctuation range increasing, failure probability of salt rock cavern will increase.

scholarly journals Review of the Hydrogen Permeability of the Liner Material of Type IV On-Board Hydrogen Storage Tank

2021 ◽  
Vol 12 (3) ◽  
pp. 130
Author(s):  
Ying Su ◽  
Hong Lv ◽  
Wei Zhou ◽  
Cunman Zhang
Keyword(s):  
Hydrogen Storage ◽  
Storage Tank ◽  
Prediction Models ◽  
Hydrogen Permeation ◽  
Hydrogen Permeability ◽  
Gas Permeation ◽  
Future Research ◽  
Hydrogen Fuel Cell ◽  
Liner Material ◽  
Type Iv

The hydrogen storage tank is a key parameter of the hydrogen storage system in hydrogen fuel cell vehicles (HFCVs), as its safety determines the commercialization of HFCVs. Compared with other types, the type IV hydrogen storage tank which consists of a polymer liner has the advantages of low cost, lightweight, and low storage energy consumption, but meanwhile, higher hydrogen permeability. A detailed review of the existing research on hydrogen permeability of the liner material of type IV hydrogen storage tanks can improve the understanding of the hydrogen permeation mechanism and provide references for following-up researchers and research on the safety of HFCVs. The process of hydrogen permeation and test methods are firstly discussed in detail. This paper then analyzes the factors that affect the process of hydrogen permeation and the barrier mechanism of the liner material and summarizes the prediction models of gas permeation. In addition to the above analysis and comments, future research on the permeability of the liner material of the type IV hydrogen storage tank is prospected.

scholarly journals Emerging Technology for a Green, Sustainable Energy Promising Materials for Hydrogen Storage, from Nanotubes to Graphene—A Review

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2499
Author(s):  
Krzysztof Jastrzębski ◽  
Piotr Kula
Keyword(s):  
Energy Source ◽  
Hydrogen Storage ◽  
Mobile Applications ◽  
Emerging Technology ◽  
Green Energy ◽  
Point Of View ◽  
Energy Industry ◽  
Volumetric Density ◽  
Potential Use ◽  
Carbon Based

The energetic and climate crises should pose a challenge for scientists in finding solutions in the field of renewable, green energy sources. Throughout more than two decades, the search for new opportunities in the energy industry made it possible to observe the potential use of hydrogen as an energy source. One of the greatest challenges faced by scientists for the sake of its use as an energy source is designing safe, usable, reliable, and effective forms of hydrogen storage. Moreover, the manner in which hydrogen is to be stored is closely dependent on the potential use of this source of green energy. In stationary use, the aim is to achieve high volumetric density of the container. However, from the point of view of mobile applications, an extremely important aspect is the storage of hydrogen, using lightweight tanks of relatively high density. That is why, a focus of scientists has been put on the use of carbon-based materials and graphene as a perspective solution in the field of H2 storage. This review focuses on the comparison of different methods for hydrogen storage, mainly based on the carbon-based materials and focuses on efficiently using graphene and its different forms to serve a purpose in the future H2-based economy.

Development and analysis of composite overwrapped pressure vessels for hydrogen storage

2021 ◽  
pp. 002199832110335
Author(s):  
Osman Kartav ◽  
Serkan Kangal ◽  
Kutay Yücetürk ◽  
Metin Tanoğlu ◽  
Engin Aktaş ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Damage Model ◽  
Pressure Vessels ◽  
Filament Winding ◽  
Burst Pressure ◽  
Fe Model ◽  
Fe Method ◽  
Liner Material ◽  
Mechanical Performances ◽  
Metallic Liner

In this study, composite overwrapped pressure vessels (COPVs) for high-pressure hydrogen storage were designed, modeled by finite element (FE) method, manufactured by filament winding technique and tested for burst pressure. Aluminum 6061-T6 was selected as a metallic liner material. Epoxy impregnated carbon filaments were overwrapped over the liner with a winding angle of ±14° to obtain fully overwrapped composite reinforced vessels with non-identical front and back dome layers. The COPVs were loaded with increasing internal pressure up to the burst pressure level. During loading, deformation of the vessels was measured locally with strain gauges. The mechanical performances of COPVs designed with various number of helical, hoop and doily layers were investigated by both experimental and numerical methods. In numerical method, FE analysis containing a simple progressive damage model available in ANSYS software package for the composite section was performed. The results revealed that the FE model provides a good correlation as compared to experimental strain results for the developed COPVs. The burst pressure test results showed that integration of doily layers to the filament winding process resulted with an improvement of the COPVs performance.

scholarly journals Effect of Gravel-sand Ratio on Physico-mechanical, Thermal and Macrostructural Properties of Micro Epoxy Polymer Concrete based on a Mixture of Alluvial-dune Sand

2020 ◽  
Vol 14 (1) ◽  
pp. 247-261
Author(s):  
Zineb Kerrida ◽  
Hichem Berkak ◽  
Zoubir Makhloufi ◽  
Madani Bederina ◽  
Ahmida Ferhat
Keyword(s):  
Thermal Conductivity ◽  
Water Absorption ◽  
Epoxy Resin ◽  
Epoxy Polymer ◽  
Polymer Concrete ◽  
Dune Sand ◽  
Optimal Values ◽  
Compressive And Flexural Strengths ◽  
Mechanical Performances ◽  
Crushed Limestone

Introduction: In the Polymer Concrete (PC) composites, aggregates are the most important constituent, which considerably affect their performance. The purpose of this experimental study is to examine the effect of Gravel-to-Sand (G/S) ratio on the physico-mechanical, thermal and microstructural properties of epoxy micro-polymer concrete made up of local aggregates. Materials & Methods: The Micro Epoxy Polymer Concrete (MEPC) studied consists of epoxy resin as a binder and a mixture of two types of sands (alluvial (0/0.63 mm) and dune (0/4 mm) sands), as well as crushed limestone gravel (3/8 mm). Six compositions were prepared with two epoxy resin contents (10% and 14% of the total weight of mixture) and three G/S ratios (0.25, 0.50 and 0.75). The studied properties are density, water absorption, compressive and flexural strengths, thermal conductivity, thermal diffusivity, specific heat and macrostructure. Results & Discussion: The obtained results show that the G/S ratio, as well as the epoxy resin content, has a significant influence on the properties of MEPC. In addition, 14% epoxy resin and the G/S ratio of 0.75 can be considered as optimal values, which lead to very interesting physico-mechanical performances (denser and less porous material, more resistant with almost similar thermal conductivity). Moreover, the density, the water absorption and the optical microscopic observation confirm that mixes containing 14% epoxy are more impermeable, compact and homogeneous than those containing 10% epoxy. Conclusion: Finally, it should be noted that the incorporation of aggregates being relatively coarse decreases the grains’ specific surface and reduces the porosity of the granular mix, which enable the epoxy product to completely cover the surface of mineral grains. A perfect covering of aggregate grains with a bender improves the adhesion between the aggregates and the polymer matrix.

scholarly journals Durability analysis of underground structures based on various creep models of the enclosing salt rock massif

2020 ◽  
Vol 201 ◽  
pp. 01007
Author(s):  
Mikhail Zhuravkov ◽  
Sergey Hvesenya ◽  
Siarhei Lapatsin
Keyword(s):  
Underground Structure ◽  
Primary Creep ◽  
Rock Massif ◽  
Initial Time ◽  
Creep Process ◽  
Secondary Creep ◽  
Salt Rock ◽  
Mine Shaft ◽  
Durability Analysis ◽  
Creep Models

The results of the durability analysis of a complex underground structure and surrounding multilayered rock massif are presented. The research is conducted based on an applied stress-strain state problem for a salt rock massif in the vicinity of an underground cavity of a large cross-section which is in conjunction with a mine shaft. The main aim of the research is to perform a comparative analysis of various mathematical models of the creep process. The problem is solved using finite element method to achieve this goal. Regularity in the development of deformation processes of the enclosing rock massif is established as a result of the study. According to this regularity, both primary creep and primary-secondary creep models show that the main increase of creep deformations occurs during a short initial time period after which creep strain rate decreases sharply.

scholarly journals Creep Properties and Constitutive Model of Salt Rock

2021 ◽  
Vol 2021 ◽  
pp. 1-29
Author(s):  
Qiang Zhang ◽  
Zhanping Song ◽  
Junbao Wang ◽  
Yuwei Zhang ◽  
Tong Wang
Keyword(s):  
Mechanical Properties ◽  
Constitutive Model ◽  
Effect Of Temperature ◽  
Creep Process ◽  
Underground Storage ◽  
Self Healing ◽  
Salt Rock ◽  
Creep Properties ◽  
Term Operation ◽  
Rock Creep

Due to the advantages of low porosity, low permeability, high ductility, and excellent capacities for creep and damage self-healing, salt rock is internationally considered as the ideal medium for underground storage of energy and disposal of radioactive waste. As one of the most important mechanical properties of salt rock, creep properties are closely related to the long-term operation stability and safety of salt rock underground storage cavern. A comprehensive review on the creep properties and constitutive model of salt rock is put forward in this paper. The opinions and suggestions on the research priority and direction of salt rock's mechanical properties in the future are put forward: (1) permeability variation of salt rock under the coupling effect of temperature and stress; (2) damage mechanism and evolution process under the effect of creep-fatigue interaction and low frequency cyclic loading; (3) microdeformation mechanisms of salt rock and the relationship between microstructure variations and macrocreep behavior during creep process; (4) the establishment of the creep damage constitutive model with simple form, less parameters, easy application, and considering the damage self-healing ability of salt rock simultaneously.

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