scholarly journals Light-Induced Photoluminescence Quenching and Degradation in Quasi 2D Perovskites Film of (C6H5C2H4NH3)2 (CH3NH3)2[Pb3I10]

2021 ◽  
Vol 11 (6) ◽  
pp. 2683
Author(s):  
Shu Hu ◽  
Xiaoliang Yan ◽  
Yang Zhang ◽  
Bo Yang ◽  
Heng Li ◽  
...  
Keyword(s):  
Photon Energy ◽  
Laser Intensity ◽  
Red Light ◽  
Ambient Air ◽  
The Other ◽  
Light Illumination ◽  
Two Dimensional ◽  
Photoluminescence Quenching ◽  
Moisture Stability ◽  
Pl Quenching

Quasi-two-dimensional (2D) perovskites recently came into the focus because of their moisture stability. In addition to ambient air, light illumination could also cause degradation for the film of 2D perovskites; however, few studies have investigated their photostability. Here, we work on light-induced photoluminescence quenching, as well as the degradation of quasi-2D perovskites of PEA2MAn−1PbnI3n+1 (n = 3 nominally, PEA+ = C6H5(CH2)2NH3+, MA+ = CH3NH3+). Light-induced photoluminescence (PL) quenching generally happens with different speeds, depending on the wavelength and intensity of the laser as well as the film’s environment. With red light (635 nm) illumination, the film does not decompose into ambient air with an intensity below ~500 mW/cm2, although in general, a higher laser intensity and/or higher photon energy (447 nm) could render the decomposition process easier and faster. On the other hand, when the film is in a vacuum, both light-induced PL quenching and film degradation are significantly suppressed. Furthermore, we find that the multiphase of n = 1, 2, 3 in the PEA2MA2Pb3I10 film decomposes together and that the degradation processes begin with the collapses of the crystalline structures.

Three-Dimensional Reconstruction of Two Forms of the Chaperonin GRO EL

1990 ◽  
Vol 48 (1) ◽  
pp. 258-259
Author(s):  
J.L. Carrascosa ◽  
G. Abella ◽  
S. Marco ◽  
M. Muyal ◽  
J.M. Carazo
Keyword(s):  
Three Dimensional ◽  
The Other ◽  
Two Dimensional ◽  
Series Method ◽  
Three Dimensional Reconstruction ◽  
Structural Components ◽  
E Coli ◽  
Dimensional Reconstruction ◽  
Morphogenetic Factors ◽  
Tilt Series

Chaperonins are a class of proteins characterized by their role as morphogenetic factors. They trantsiently interact with the structural components of certain biological aggregates (viruses, enzymes etc), promoting their correct folding, assembly and, eventually transport. The groEL factor from E. coli is a conspicuous member of the chaperonins, as it promotes the assembly and morphogenesis of bacterial oligomers and/viral structures.We have studied groEL-like factors from two different bacteria:E. coli and B.subtilis. These factors share common morphological features , showing two different views: one is 6-fold, while the other shows 7 morphological units. There is also a correlation between the presence of a dominant 6-fold view and the fact of both bacteria been grown at low temperature (32°C), while the 7-fold is the main view at higher temperatures (42°C). As the two-dimensional projections of groEL were difficult to interprete, we studied their three-dimensional reconstruction by the random conical tilt series method from negatively stained particles.

Polymer-Graphene Nanoassemblies and their Applications in Cancer Theranostics

2020 ◽  
Vol 20 (11) ◽  
pp. 1340-1351 ◽  
Author(s):  
Ponnurengam M. Sivakumar ◽  
Matin Islami ◽  
Ali Zarrabi ◽  
Arezoo Khosravi ◽  
Shohreh Peimanfard
Keyword(s):  
Mechanical Stability ◽  
Chemical Properties ◽  
The Other ◽  
Hydrophilic Polymer ◽  
Two Dimensional ◽  
Normal Tissues ◽  
Physical Chemical ◽  
Anti Cancer ◽  
Good Biocompatibility ◽  
Cancer Theranostics

Background and objective: Graphene-based nanomaterials have received increasing attention due to their unique physical-chemical properties including two-dimensional planar structure, large surface area, chemical and mechanical stability, superconductivity and good biocompatibility. On the other hand, graphene-based nanomaterials have been explored as theranostics agents, the combination of therapeutics and diagnostics. In recent years, grafting hydrophilic polymer moieties have been introduced as an efficient approach to improve the properties of graphene-based nanomaterials and obtain new nanoassemblies for cancer therapy. Methods and results: This review would illustrate biodistribution, cellular uptake and toxicity of polymergraphene nanoassemblies and summarize part of successes achieved in cancer treatment using such nanoassemblies. Conclusion: The observations showed successful targeting functionality of the polymer-GO conjugations and demonstrated a reduction of the side effects of anti-cancer drugs for normal tissues.

scholarly journals On the Kirchhoff-Love Hypothesis (Revised and Vindicated)

2021 ◽  
Author(s):  
Olivier Ozenda ◽  
Epifanio G. Virga
Keyword(s):  
Free Energy ◽  
Dimension Reduction ◽  
Three Dimensional ◽  
Energy Functional ◽  
The Other ◽  
Variational Model ◽  
Two Dimensional ◽  
Elastic Plates ◽  
Kinematic Constraint ◽  
Free Energy Functional

AbstractThe Kirchhoff-Love hypothesis expresses a kinematic constraint that is assumed to be valid for the deformations of a three-dimensional body when one of its dimensions is much smaller than the other two, as is the case for plates. This hypothesis has a long history checkered with the vicissitudes of life: even its paternity has been questioned, and recent rigorous dimension-reduction tools (based on standard $\varGamma $ Γ -convergence) have proven to be incompatible with it. We find that an appropriately revised version of the Kirchhoff-Love hypothesis is a valuable means to derive a two-dimensional variational model for elastic plates from a three-dimensional nonlinear free-energy functional. The bending energies thus obtained for a number of materials also show to contain measures of stretching of the plate’s mid surface (alongside the expected measures of bending). The incompatibility with standard $\varGamma $ Γ -convergence also appears to be removed in the cases where contact with that method and ours can be made.

scholarly journals Long way to Ricci flatness

2020 ◽  
Vol 2020 (10) ◽  
Author(s):  
Jin Chen ◽  
Chao-Hsiang Sheu ◽  
Mikhail Shifman ◽  
Gianni Tallarita ◽  
Alexei Yung
Keyword(s):  
Sigma Model ◽  
Ultra Violet ◽  
The Other ◽  
Target Space ◽  
Linear Sigma Model ◽  
Close Relative ◽  
Two Dimensional ◽  
World Sheet ◽  
Ricci Flat ◽  
The World

Abstract We study two-dimensional weighted $$ \mathcal{N} $$ N = (2) supersymmetric ℂℙ models with the goal of exploring their infrared (IR) limit. 𝕎ℂℙ(N,$$ \tilde{N} $$ N ˜ ) are simplified versions of world-sheet theories on non-Abelian strings in four-dimensional $$ \mathcal{N} $$ N = 2 QCD. In the gauged linear sigma model (GLSM) formulation, 𝕎ℂℙ(N,$$ \tilde{N} $$ N ˜ ) has N charges +1 and $$ \tilde{N} $$ N ˜ charges −1 fields. As well-known, at $$ \tilde{N} $$ N ˜ = N this GLSM is conformal. Its target space is believed to be a non-compact Calabi-Yau manifold. We mostly focus on the N = 2 case, then the Calabi-Yau space is a conifold. On the other hand, in the non-linear sigma model (NLSM) formulation the model has ultra-violet logarithms and does not look conformal. Moreover, its metric is not Ricci-flat. We address this puzzle by studying the renormalization group (RG) flow of the model. We show that the metric of NLSM becomes Ricci-flat in the IR. Moreover, it tends to the known metric of the resolved conifold. We also study a close relative of the 𝕎ℂℙ model — the so called zn model — which in actuality represents the world sheet theory on a non-Abelian semilocal string and show that this zn model has similar RG properties.

scholarly journals Artificial complementary chromatic acclimation gene expression system in Escherichia coli

2021 ◽  
Vol 20 (1) ◽  
Author(s):  
Dwi Ariyanti ◽  
Kazunori Ikebukuro ◽  
Koji Sode
Keyword(s):  
Gene Expression ◽  
Escherichia Coli ◽  
Light Exposure ◽  
Expression System ◽  
Red Light ◽  
Green Light ◽  
Light Illumination ◽  
Multiple Gene ◽  
Gene Expression System ◽  
Chromatic Acclimation

Abstract Background The development of multiple gene expression systems, especially those based on the physical signals, such as multiple color light irradiations, is challenging. Complementary chromatic acclimation (CCA), a photoreversible process that facilitates the control of cellular expression using light of different wavelengths in cyanobacteria, is one example. In this study, an artificial CCA systems, inspired by type III CCA light-regulated gene expression, was designed by employing a single photosensor system, the CcaS/CcaR green light gene expression system derived from Synechocystis sp. PCC6803, combined with G-box (the regulator recognized by activated CcaR), the cognate cpcG2 promoter, and the constitutively transcribed promoter, the PtrcΔLacO promoter. Results One G-box was inserted upstream of the cpcG2 promoter and a reporter gene, the rfp gene (green light-induced gene expression), and the other G-box was inserted between the PtrcΔLacO promoter and a reporter gene, the bfp gene (red light-induced gene expression). The Escherichia coli transformants with plasmid-encoded genes were evaluated at the transcriptional and translational levels under red or green light illumination. Under green light illumination, the transcription and translation of the rfp gene were observed, whereas the expression of the bfp gene was repressed. Under red light illumination, the transcription and translation of the bfp gene were observed, whereas the expression of the rfp gene was repressed. During the red and green light exposure cycles at every 6 h, BFP expression increased under red light exposure while RFP expression was repressed, and RFP expression increased under green light exposure while BFP expression was repressed. Conclusion An artificial CCA system was developed to realize a multiple gene expression system, which was regulated by two colors, red and green lights, using a single photosensor system, the CcaS/CcaR system derived from Synechocystis sp. PCC6803, in E. coli. The artificial CCA system functioned repeatedly during red and green light exposure cycles. These results demonstrate the potential application of this CCA gene expression system for the production of multiple metabolites in a variety of microorganisms, such as cyanobacteria.

Sight distance red zones on combined horizontal and sag vertical curves

1998 ◽  
Vol 25 (4) ◽  
pp. 621-630 ◽  
Author(s):  
Yasser Hassan ◽  
Said M Easa
Keyword(s):  
Quantitative Analysis ◽  
Three Dimensional ◽  
The Other ◽  
Two Dimensional ◽  
Horizontal Curve ◽  
Sight Distance ◽  
Stopping Sight Distance ◽  
Three Dimensional Models ◽  
Highway Alignment ◽  
Current Standards

Coordination of highway horizontal and vertical alignments is based on subjective guidelines in current standards. This paper presents a quantitative analysis of coordinating horizontal and sag vertical curves that are designed using two-dimensional standards. The locations where a horizontal curve should not be positioned relative to a sag vertical curve (called red zones) are identified. In the red zone, the available sight distance (computed using three-dimensional models) is less than the required sight distance. Two types of red zones, based on stopping sight distance (SSD) and preview sight distance (PVSD), are examined. The SSD red zone corresponds to the locations where an overlap between a horizontal curve and a sag vertical curve should be avoided because the three-dimensional sight distance will be less than the required SSD. The PVSD red zone corresponds to the locations where a horizontal curve should not start because drivers will not be able to perceive it and safely react to it. The SSD red zones exist for practical highway alignment parameters, and therefore designers should check the alignments for potential SSD red zones. The range of SSD red zones was found to depend on the different alignment parameters, especially the superelevation rate. On the other hand, the results showed that the PVSD red zones exist only for large values of the required PVSD, and therefore this type of red zones is not critical. This paper should be of particular interest to the highway designers and professionals concerned with highway safety.Key words: sight distance, red zone, combined alignment.

scholarly journals THE ENERGY EIGENVALUES OF THE TWO DIMENSIONAL HYDROGEN ATOM IN A MAGNETIC FIELD

2006 ◽  
Vol 15 (06) ◽  
pp. 1263-1271 ◽  
Author(s):  
A. SOYLU ◽  
O. BAYRAK ◽  
I. BOZTOSUN
Keyword(s):  
Magnetic Field ◽  
Hydrogen Atom ◽  
Iteration Method ◽  
Weak Magnetic Field ◽  
The Other ◽  
Asymptotic Iteration Method ◽  
Iterative Approach ◽  
Two Dimensional ◽  
Energy Eigenvalues ◽  
The Magnetic Field

In this paper, the energy eigenvalues of the two dimensional hydrogen atom are presented for the arbitrary Larmor frequencies by using the asymptotic iteration method. We first show the energy eigenvalues for the case with no magnetic field analytically, and then we obtain the energy eigenvalues for the strong and weak magnetic field cases within an iterative approach for n=2-10 and m=0-1 states for several different arbitrary Larmor frequencies. The effect of the magnetic field on the energy eigenvalues is determined precisely. The results are in excellent agreement with the findings of the other methods and our method works for the cases where the others fail.

Coupled systems of two-dimensional turbulence

2013 ◽  
Vol 732 ◽  
Author(s):  
Rick Salmon
Keyword(s):  
Hamiltonian System ◽  
Energy Conservation ◽  
Strong Correlation ◽  
Conservation Law ◽  
Hamiltonian Dynamics ◽  
Coupled Systems ◽  
The Other ◽  
Two Dimensional ◽  
Coherent Vortices ◽  
Fluid Particles

AbstractOrdinary two-dimensional turbulence corresponds to a Hamiltonian dynamics that conserves energy and the vorticity on fluid particles. This paper considers coupled systems of two-dimensional turbulence with three distinct governing dynamics. One is a Hamiltonian dynamics that conserves the vorticity on fluid particles and a quantity analogous to the energy that causes the system members to develop a strong correlation in velocity. The other two dynamics considered are non-Hamiltonian. One conserves the vorticity on particles but has no conservation law analogous to energy conservation; the other conserves energy and enstrophy but it does not conserve the vorticity on fluid particles. The coupled Hamiltonian system behaves like two-dimensional turbulence, even to the extent of forming isolated coherent vortices. The other two dynamics behave very differently, but the behaviours of all four dynamics are accurately predicted by the methods of equilibrium statistical mechanics.

scholarly journals The influence of resistivity gradients on shock conditions for a Petschek reconnection geometry

2016 ◽  
Vol 34 (4) ◽  
pp. 421-425
Author(s):  
Christian Nabert ◽  
Karl-Heinz Glassmeier
Keyword(s):  
Magnetic Field ◽  
Necessary Conditions ◽  
The Other ◽  
Diffusion Region ◽  
Two Dimensional ◽  
Characteristic Velocity ◽  
Magnetohydrodynamic Equations ◽  
One Dimensional ◽  
The Magnetic Field ◽  
Alfven Velocity

Abstract. Shock waves can strongly influence magnetic reconnection as seen by the slow shocks attached to the diffusion region in Petschek reconnection. We derive necessary conditions for such shocks in a nonuniform resistive magnetohydrodynamic plasma and discuss them with respect to the slow shocks in Petschek reconnection. Expressions for the spatial variation of the velocity and the magnetic field are derived by rearranging terms of the resistive magnetohydrodynamic equations without solving them. These expressions contain removable singularities if the flow velocity of the plasma equals a certain characteristic velocity depending on the other flow quantities. Such a singularity can be related to the strong spatial variations across a shock. In contrast to the analysis of Rankine–Hugoniot relations, the investigation of these singularities allows us to take the finite resistivity into account. Starting from considering perpendicular shocks in a simplified one-dimensional geometry to introduce the approach, shock conditions for a more general two-dimensional situation are derived. Then the latter relations are limited to an incompressible plasma to consider the subcritical slow shocks of Petschek reconnection. A gradient of the resistivity significantly modifies the characteristic velocity of wave propagation. The corresponding relations show that a gradient of the resistivity can lower the characteristic Alfvén velocity to an effective Alfvén velocity. This can strongly impact the conditions for shocks in a Petschek reconnection geometry.

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