scholarly journals Polylactic Acid/Carbon Nanoparticle Composite Filaments for Sensing

2021 ◽  
Vol 11 (6) ◽  
pp. 2580
Author(s):  
Mariana M. Silva ◽  
Paulo E. Lopes ◽  
Yilong Li ◽  
Petra Pötschke ◽  
Fernando N. Ferreira ◽  
...  

Polylactic acid (PLA) is a bio-based, biodegradable polymer that presents high potential for biomedical and sensing applications. Ongoing works reported in the literature concern mainly applications based on 3D printing, while textile applications are hindered by the limited flexibility of PLA and its composite filaments. In the present work, PLA/multiwall carbon nanotube (MWCNT) composite filaments were produced with enhanced flexibility and electrical conductivity, which may be applied on a textile structure. A biodegradable plasticizer was incorporated in the nanocomposites, aiming at improving MWCNT dispersion and increasing the flexibility of the filaments. Filaments were produced with a range of compositions and their morphology was characterized as well as their thermal, thermomechanical, and electrical properties. Selected compositions were tested for sensing activity using saturated acetone vapor, demonstrating a suitable response and potential for the application in fabrics with sensing capacity.

2020 ◽  
Vol 143 (5) ◽  
Author(s):  
Felicia Stan ◽  
Nicoleta-Violeta Stanciu ◽  
Adriana-Madalina Constantinescu ◽  
Catalin Fetecau

Abstract This paper reports on the 3D printing of flexible and stretchable parts based on multiwall carbon nanotube (MWCNT)/polyester-based thermoplastic polyurethane (TPU) nanocomposites. The rheological properties of the WCNT/TPU nanocomposites with different wt% of MWCNTs (0.1–3) were determined and used as guidance for the extrusion and 3D printing processes. MWCNT/TPU filaments were extruded and used for 3D printing of different flexible and stretchable parts. The mechanical, electrical, and piezoresistive response of the MWCNT/TPU nanocomposite filaments and 3D printed parts under static and monotonic loading was studied. The experimental results show that with increasing temperature and shear rate, respectively, the shear viscosity of the MWCNT/TPU nanocomposite decreases, whereas the viscosity increases with increasing wt% of MWCNTs. With the addition of MWCNTs, the elastic modulus and tensile strength of the feedstock filament all increase, enhancing the printability of TPU by increasing the buckling resistance and the stability of the 3D printed layer. The electrical conductivity of the 3D printed MWCNT/TPU nanocomposites increases with increasing wt% of MWCNTs and exceeds the conductivity of the filaments. The 3D printed MWCNT/TPU nanocomposites with 3 wt% show an electrical conductivity about 10 S/m, irrespective of the printing direction. Moreover, the 3D printed MWCNT/TPU nanocomposites exhibit good mechanical properties and high piezoresistive sensitivity with gauge factor (50–600) dependent on both strain and printing direction.


RSC Advances ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 5678-5684 ◽  
Author(s):  
Shaobo Zhang ◽  
Feiran Zhang ◽  
Yanfei Pan ◽  
Liping Jin ◽  
Bo Liu ◽  
...  

MWCNT-cellulose/cellulose composite fibers with enhanced mechanical and conducting properties were preparedviafacilitating the dispersion of MWCNTs in fibers.


2013 ◽  
Vol 737 ◽  
pp. 183-190 ◽  
Author(s):  
Anne Zulfia ◽  
Sutopo ◽  
Bangkit Indriyana ◽  
M.E. Albar ◽  
S. Rohman

Polypropylene can be improved an electrical conductivity by addition of carbon and multiwall carbon nanotube (MWCNT) as well as combination with copper (Cu) powder. Multiwall carbon nanotube used from 0.1 wt%, 0.5 wt% to 1 wt% while the addition of Cu powder into PP/C was various from 0.1 wt%, 0.2wt% to 0.5wt% respectively. This research focuses on material design of composite based on polymer and carbon to improve an electrical conductivity according to electrical conductivity requirement for bipolar plate. Bipolar plate is one of the components in PEMFC constituted a crucial component that collects and transfers electron from the anode to the cathode, therefore it should possess high electrical conductivity. The main discussion in this research is to analyze the role of multiwall carbon nano tube (MWCNT) and copper on electrical conductivity of polymer composites produced. Functional groups analysis using Fourier Transform Infrared Spectroscopy (FTIR) was also carried out to investigate whether carbon has been mixed perfectly within polypropylene. It is found that the effect of adding a small amount of MWCNT and Cu have improved their electrical conductivity of composites up to 15.62 S/cm.


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