scholarly journals Detection of Density Changes in Soils with Impedance Spectroscopy

2021 ◽  
Vol 11 (4) ◽  
pp. 1568
Author(s):  
Christoph Clemens ◽  
Mario Radschun ◽  
Annette Jobst ◽  
Jörg Himmel ◽  
Olfa Kanoun
Keyword(s):  
Impedance Spectroscopy ◽  
Volume Change ◽  
Experimental Investigations ◽  
Soil Parameters ◽  
Impedance Change ◽  
Material Transport ◽  
Contact Zones ◽  
Contact Erosion ◽  
The Stability ◽  
Volume Decrease

Measurement of soil parameters, such as moisture, density and density change, can provide important information for evaluating the stability of earthwork structures and for structural health monitoring. To ensure the stability of flood protection dikes, erosion at the contact zones of different soil zones must be avoided. In this work we propose the use of impedance spectroscopy to measure changes in density and volume caused by contact erosion. Erosion leads generally to a volume decrease in the contact zones between soils with different grain sizes and, consequently, to cavities in the dike structure. For this purpose, a proctor mould was developed for emulating contact erosion and the realisation of impedance measurements. Experimental investigations show a correlation between volume change of the soils in the proctor mould and impedance value. For a volume change of soil in the range of approximately 1.5% to 5.3%, an impedance change arises in the range of 17.2% to 29.8%. With several investigations we proof, that it is possible to detect material transport by impedance spectroscopy.

scholarly journals Distribution and ecological segregation on regional and microgeographic scales of the diploidCentaurea asperaL., the tetraploidC. seridisL., and their triploid hybrids (Compositae)

PeerJ ◽  
2018 ◽  
Vol 6 ◽  
pp. e5209 ◽  
Author(s):  
Alfonso Garmendia ◽  
Hugo Merle ◽  
Pablo Ruiz ◽  
Maria Ferriol
Keyword(s):  
Anthropogenic Disturbance ◽  
Large Scale ◽  
Latitudinal Gradient ◽  
Soil Parameters ◽  
Fine Scale ◽  
Contact Zones ◽  
Ecological Requirements ◽  
Adaptive Processes ◽  
Sympatric Cytotypes

Although polyploidy is considered a ubiquitous process in plants, the establishment of new polyploid species may be hindered by ecological competition with parental diploid taxa. In such cases, the adaptive processes that result in the ecological divergence of diploids and polyploids can lead to their co-existence. In contrast, non-adaptive processes can lead to the co-existence of diploids and polyploids or to differentiated distributions, particularly when the minority cytotype disadvantage effect comes into play. Although large-scale studies of cytotype distributions have been widely conducted, the segregation of sympatric cytotypes on fine scales has been poorly studied. We analysed the spatial distribution and ecological requirements of the tetraploidCentaurea seridisand the diploidCentaurea asperain east Spain on a large scale, and also microspatially in contact zones where both species hybridise and give rise to sterile triploid hybrids. On the fine scale, the position of eachCentaureaindividual was recorded along with soil parameters, accompanying species cover and plant richness. On the east Spanish coast, a slight latitudinal gradient was found. TetraploidC. seridisindividuals were located northerly and diploidC. asperaindividuals southerly. Tetraploids were found only in the habitats with strong anthropogenic disturbance. In disturbed locations with well-developed semi-fixed or fixed dunes, diploids and tetraploids could co-exist and hybridise. However, on a fine scale, although taxa were spatially segregated in contact zones, they were not ecologically differentiated. This finding suggests the existence of non-adaptive processes that have led to their co-existence. Triploid hybrids were closer to diploid allogamous mothers (C. aspera) than to tetraploid autogamous fathers (C. seridis). This may result in a better ability to compete for space in the tetraploid minor cytotype, which might facilitate its long-term persistence.

scholarly journals Extracellular Vesicles: “Stealth Transport Aircrafts” for Drugs

2020 ◽  
Author(s):  
Chunying Liu ◽  
Xuejing Lin ◽  
Changqing Su
Keyword(s):  
Extracellular Vesicles ◽  
Drug Carrier ◽  
Drug Loading ◽  
Source Material ◽  
Material Transport ◽  
Disease Treatment ◽  
Small Molecule Drugs ◽  
Viral Particles ◽  
The Stability

Extracellular vesicles (EVs) can deliver many types of drugs with their natural source material transport properties, inherent long-term blood circulation capabilities and excellent biocompatibility, and have great potential in the field of drug carrier. Modification of the content and surface of EVs according to the purpose of treatment has become a research focus to improve the drug load and the targeting of EVs. EVs can maximize the stability of the drugs, prevent immune clearance and achieve accurate delivery. Therefore, EVs can be described as \" stealth transport aircrafts \" for drugs. This chapter will respectively introduce the application of natural EVs as cell substitutes in cell therapy and engineered EVs as carriers of nucleic acids, proteins, small molecule drugs and therapeutic viral particles in disease treatment. It will also explain the drug loading and modification strategies of EVs, the source and characteristics of EVs. In addition, the commercialization progress of EVs drugs will be mentioned here, and the problems in their applications will be discussed in conjunction with the application of EVs in the treatment of COVID-19.

Dynamics and Stability of Partial Immersion Milling Operations

1999 ◽  
Author(s):  
M. X. Zhao ◽  
B. Balachandran ◽  
M. A. Davies ◽  
J. R. Pratt
Keyword(s):  
Hopf Bifurcation ◽  
Time Variation ◽  
Periodic Motion ◽  
Contact Time ◽  
Period Doubling ◽  
Experimental Investigations ◽  
Partial Immersion ◽  
Milling Operations ◽  
Wide Range ◽  
The Stability

Abstract In this paper, numerical and experimental investigations conducted into the dynamics and stability of partial immersion milling operations are presented. A mechanics based model is used for simulations of a wide range of milling operations and instabilities that arise due to regeneration and/or impact effects are studied. Poincaré sections are used to assess the stability of motions. The studies reveal that apart from Hopf bifurcation of a periodic motion, a period-doubling bifurcation of a periodic motion may also lead to chatter in partial immersion milling operations. Issues such as tooth contact time variation and structure of stability charts are also discussed.

Sequence, Salt, Charge, and the Stability of DNA at High Pressure

1996 ◽  
Author(s):  
Robert B. Macgregor Jr ◽  
John Q. Wu
Keyword(s):  
Molar Volume ◽  
Volume Change ◽  
Salt Concentration ◽  
Electrostatic Interactions ◽  
Proposed Model ◽  
Dna Strands ◽  
Positive Volume ◽  
Ion Radius ◽  
The Stability ◽  
Kinetics Of

The effect of pressure on the helix-coil transition temperature (Tm) is reported for the double-stranded polymers poly(dA)poly(dT), poly[d(A-T)], poly[d(l-C], and poly[d(G-C] and triple-stranded poly(dA)2poly(dT). The Tm increases as a function of pressure, implying a positive volume change for the transition and leading to the conclusion that the molar volume of the coil form is larger than the molar volume of the helix. From the change in Tm as a function of pressure, molar volume changes of the transition (ΔVt) are calculated using the Clapeyron equation and calorimetrically determined enthalpies. For the doublestranded polymers, ΔVt, increases in the order poly[d(l-C] < polyt[d(A-T)] < poly(dA)-poly(dT) < polylcl(G-C)]. The value of ΔVt, for the triple-stranded to single-stranded transition of poly(dA) 2poly(dT) is larger than that of poly[d(G-C)I. The magnitude of ΔVt increases with salt concentration in all cases studied; however, the change of ΔVt with salt concentration depends on the sequence of the DNA and the number of strands involved in the transition. In the model proposed to explain the results, the overall molar volume change of the transition is a function of a negative volume change arising from changes in the electrostatic interactions of the DNA strands, and a positive volume change due to unstacking the bases. The model predicted the direction of the change in the ΔVt for several experiments. The magnitude of AVJ increases with counter ion radius, thus for polyld(A-T)], ΔVt, increases in the series Na+ , K+, Cs+, The ΔVt also increases if the charge on the phosphodiester groups is removed. The kinetics of the formation of double-stranded (dA)19(dT)19 in 50 mM NaCI are slowed approximately 14-fold at 200 MPa relative to atmospheric pressure. The implied volume of activation of +37 ml mol−l in the direction of this change is also in agreement with the proposed model. The stability of double- and triple-stranded DNA helices in water around neutral pH depends on the base composition and sequence, as well as on the ionic strength of the solution. Each of these dependencies also defines how DNA interacts with water.

Experimental Investigations of Lean Stability Limits of a Prototype Syngas Burner for Low Calorific Value Gases

2011 ◽  
Author(s):  
Ivan R. Sigfrid ◽  
Ronald Whiddon ◽  
Marcus Alde´n ◽  
Jens Klingmann
Keyword(s):  
Equivalence Ratio ◽  
Coal Gasification ◽  
Stability Limit ◽  
Calorific Value ◽  
Kinetic Mechanism ◽  
Experimental Investigations ◽  
Stirred Reactor ◽  
Wobbe Index ◽  
The Stability ◽  
Experimental Values

The lean stability limit of a prototype syngas burner is investigated. The burner is a three sector system, consisting of a separate igniter, stabilizer and Main burner. The ignition sector, Rich-Pilot-Lean (RPL), can be operated with both rich or lean equivalence values, and serves to ignite the Pilot sector which stabilizes the Main combustion sector. The RPL and Main sectors are fully premixed, while the Pilot sector is partially premixed. The complexity of this burner design, especially the ability to vary equivalence ratios in all three sectors, allows for the burner to be adapted to various gases and achieve optimal combustion. The gases examined are methane and a high H2 model syngas (10% CH4, 22.5% CO, 67.5% H2). Both gases are combusted at their original compositions and the syngas was also diluted with N2 to a low calorific value fuel with a Wobbe index of 15 MJ/m3. The syngas is a typical product of gasification of biomass or coal. Gasification of biomass can be considered to be CO2 neutral. The lean stability limit is localized by lowering the equivalence ratio from stable combustion until the limit is reached. To get a comparable blowout definition the CO emissions is measured using a non-dispersive infrared sensor analyzer. The stability limit is defined when the measured CO emissions exceed 200 ppm. The stability limit is measured for the 3 gas mixtures at atmospheric pressure. The RPL equivalence ratio is varied to investigate how this affected the lean blowout limit. A small decrease in stability limit can be observed when increasing the RPL equivalence ratio. The experimental values are compared with values from a perfectly stirred reactor modeled (PSR), under burner conditions, using the GRI 3.0 kinetic mechanism for methane and the San Diego mechanism for the syngas fuels.

scholarly journals Chiral Discrimination of Tryptophan Enantiomers via (1R, 2R)-2-Amino-1, 2-Diphenyl Ethanol Modified Interface

2011 ◽  
Vol 2011 ◽  
pp. 1-6 ◽  
Author(s):  
Juan Zhou ◽  
Qiao Chen ◽  
Li-lan Wang ◽  
Yong-hua Wang ◽  
Ying-zi Fu
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Chiral Discrimination ◽  
Characteristic Analysis ◽  
Tryptophan Enantiomers ◽  
Sensitive Property ◽  
The Stability ◽  
Relative Change

The paper reported that a simple chiral selective interface constructed by (1R, 2R)-2-amino-1, 2-diphenyl ethanol had been developed to discriminate tryptophan enantiomers. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used for the characteristic analysis of the electrode. The results indicated that the interface showed stable and sensitive property to determine the tryptophan enantiomers. Moreover, it exhibited the better stereoselectivity for L-tryptophan than that for D-tryptophan. The discrimination characteristics of the chiral selective interface for discriminating tryptophan enantiomers, including the response time, the effect of tryptophan enantiomers concentration, and the stability, were investigated in detail. In addition, the chiral selective interface was used to determine the enantiomeric composition of L- and D-tryptophan enantiomer mixtures by measuring the relative change of the peak current as well as in pure enantiomeric solutions. These results suggested that the chiral selective interface has the potential for enantiomeric discrimination of tryptophan enantiomers.

scholarly journals Interaction of Lorazepam with Planar Bilayer Lipid Membrane and Development of Impedimetric Sensor

2019 ◽  
Vol 31 (5) ◽  
pp. 1169-1175
Author(s):  
S. Sivakumar ◽  
S. Rameshkumar ◽  
S. Sathishkumar ◽  
A. Sankar
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Electrical Properties ◽  
Impedance Spectroscopy ◽  
Lipid Membrane ◽  
Electrochemical Impedance ◽  
Bilayer Lipid Membrane ◽  
Phospholipid Membrane ◽  
Planar Bilayer ◽  
Bilayer Lipid ◽  
The Stability

Artificial planar bilayer phospholipid membrane was formed in KCl bath solutions and its electrical properties have been analyzed using electrochemical impedance spectroscopy. The stability of planar bilayer lipid membrane depends on concentration of KCl in the bath. Changes in the electrical properties of planar bilayer lipid membrane with the addition of lorazepam were also studied using electrochemical impedance spectroscopy. Lorazepam gets partitioned into bilayer lipid membrane and exhibited a fluidization effect. The ionic conductance across the bilayer lipid membrane increased with the addition of lorazepam to the bath. An impedimetric sensor was developed for quantification of lorazepam in solution.

Stability and Conductivity of Gd2((Mo1/3Mn2/3)xTi1-x)2O7

1997 ◽  
Vol 500 ◽  
Author(s):  
J. J. Sprague ◽  
O. Porat ◽  
H. L. Tuller
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Impedance Spectroscopy ◽  
Stability Region ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Stability ◽  
Stability Limits ◽  
Composite Solid ◽  
Solid State Electrochemical Device

ABSTRACTA composite solid state electrochemical device, with (Gd1-xCax)2Ti2O7 serving as the electrolyte and Gd2(Ti1-xMox)2O7 (GT-Mo) as the anode has recently been proposed. The latter exhibits high levels of mixed conduction under reducing atmospheres, but decomposes at high Po2. We have recently succeeded in extending the stability limits of the GT-Mo to higher Po2 with the addition of Mn. In this study, we report on the conductivity and stability of Gd2((Mo13Mn2/3)xTi1-x)207 (GMMT) as a function of Po2, T, and composition utilizing impedance spectroscopy and x-ray diffraction. The addition of Mn extends the stability region of the material to Po2 = 1 atm with little change in the magnitude of the conductivity. Defect models explaining the dependence of the conductivity on oxygen partial pressure are presented. Preliminary results from the use of an electronic blocking sandwich cell used to isolate the ionic conductivity of GMMT are also presented.

scholarly journals High Response Performance of a Tuned-Mass Damper for Vibration Suppression of Offshore Platform under Earthquake Loads

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Qiong Wu ◽  
Xilu Zhao ◽  
Rencheng Zheng ◽  
Keisuke Minagawa
Keyword(s):  
Vibration Suppression ◽  
Initial Period ◽  
Offshore Platform ◽  
High Response ◽  
Experimental Investigations ◽  
Offshore Platforms ◽  
Earthquake Loads ◽  
Response Characteristics ◽  
Response Performance ◽  
The Stability

Currently, tuned-mass dampers (TMDs) are widely applied to maintain the stability of offshore platforms in hostile environments; however, the stability system of offshore platforms faces considerable challenges under critical earthquake loads of the initial period. Therefore, this study concentrated on the high response performance of a simple passive TMD system, and numerical and experimental investigations were performed using a 1 : 200-scale prototype. The obtained results indicated that the displacement, acceleration, and their power spectral density all decreased significantly for the offshore platform with the TMD system. By further analyses of its high response characteristics, it was validated that the TMD reactions can commence within the first 3 s of earthquake excitation, while the fundamental natural frequency was consistently tuned for the TMD system dependent on the dynamic magnification factor. The evaluation indices also confirmed that this method is effective in reducing the overall vibration level and the maximum peak values of the offshore platform exposed to earthquake excitations, mainly because of its high response characteristics.

Experimental Study on Journal Gas Bearing with Axial Slot for a Miniature Air Turboexpander

2012 ◽  
Vol 220-223 ◽  
pp. 611-614
Author(s):  
Ru Gang Chen ◽  
Ya Jun Nie ◽  
Quan Zhou ◽  
Chao Gong ◽  
Tao Chen
Keyword(s):  
Experimental Study ◽  
Instability Threshold ◽  
Radial Clearance ◽  
Experimental Investigations ◽  
New Type ◽  
The Stability ◽  
The Relationship ◽  
Gas Bearing

A new type of hydrostatic journal gas bearing with axial slot of tangential gas entry for miniature air turboexpander is firstly developed in this paper. This bearing configuration is presented and constructed to fit manufacture simplicity. The experimental investigations are carried out to reveal the relationship between bearing parameters and instability threshold speed. It is feasible to increase the stability of hydrostatic journal gas bearing by adopting this kind of configuration with axial slot of tangential gas entry. Some valuable tested results are obtained to reveal the optimum slot height and radial clearance for this miniature air turboexpander.

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