scholarly journals Measuring the Hyperfine Splitting and Deriving the Hyperfine Interaction Constants of the Cesium 5p67d 2D5/2 Excited State

2020 ◽  
Vol 10 (22) ◽  
pp. 8178
Author(s):  
Zerong Wang ◽  
Xiaokai Hou ◽  
Jiandong Bai ◽  
Junmin Wang
Keyword(s):  
Excited State ◽  
Hyperfine Interaction ◽  
Hyperfine Splitting ◽  
Room Temperature ◽  
Double Resonance ◽  
Interaction Constant ◽  
Probe Laser ◽  
Frequency Interval ◽  
Atomic Vapor ◽  
Vapor Cell

The measurement of the cesium (Cs) 5p67d2D5/2 excited state’s hyperfine splitting intervals and hyperfine interaction constants was experimentally investigated using a ladder-type (852 nm + 698 nm) three-level Cs system (5p66s2S1/2–5p66p2P3/2–5p67d2D5/2) with a room-temperature Cs atomic vapor cell. By scanning the 698 nm coupling laser’s frequency, the Doppler-free high-resolution electromagnetically-induced transparency (EIT)-assisted double-resonance optical pumping (DROP) spectra were demonstrated via transmission enhancement of the locked 852 nm probe laser. The EIT-assisted DROP spectra were employed to study the hyperfine splitting intervals for the Cs 5p67d2D5/2 excited state with a room-temperature Cs atomic vapor cell, and the radio-frequency modulation sideband of a waveguide-type electro-optic phase modulator (EOPM) was introduced for frequency calibration to improve the accuracy of frequency interval measurement. The existence of EIT makes the DROP spectral linewidth much narrower, and it is very helpful to significantly improve the spectroscopic resolution. Benefiting from the higher signal-to-noise ratio (SNR) and much better resolution of the EIT-assisted DROP spectra, the hyperfine splitting intervals between the hyperfine folds of (F” = 6), (F” = 5), and (F” = 4) of the Cs 5p67d2D5/2 state (HFS6″–5″ = −10.60(17) MHz and HFS5″–4″ = −8.54(15) MHz) were measured and, therefore, the magnetic dipole hyperfine interaction constant (A = −1.70(03) MHz) and the electrical quadrupole hyperfine interaction constant (B = −0.77(58) MHz) were derived for the Cs 5p67d2D5/2 state. These constants constitute an important reference value for an improvement of the precise measurement and determination of basic physical constants.

scholarly journals Measurement of87Rb Rydberg-state hyperfine splitting in a room-temperature vapor cell

2013 ◽  
Vol 87 (4) ◽  
Author(s):  
Atreju Tauschinsky ◽  
Richard Newell ◽  
H. B. van Linden van den Heuvell ◽  
R. J. C. Spreeuw
Keyword(s):  
Hyperfine Splitting ◽  
Room Temperature ◽  
Rydberg State ◽  
Vapor Cell

scholarly journals Precise Measurement of Hyperfine Structure of Cesium 7S1/2 Excited State

2020 ◽  
Vol 10 (2) ◽  
pp. 525 ◽  
Author(s):  
Yunhui He ◽  
Jiabei Fan ◽  
Liping Hao ◽  
Yuechun Jiao ◽  
Jianming Zhao
Keyword(s):  
Excited State ◽  
Hyperfine Structure ◽  
Precise Measurement ◽  
Double Resonance ◽  
Probe Laser ◽  
Transition Line ◽  
Coupling Laser ◽  
Electro Optic ◽  
Fabry Perot ◽  
Optical Double Resonance

We present a precise measurement of the hyperfine structure of cesium 7 S 1 / 2 excited state by employing electromagnetically induced spectroscopy (EIS) with a cesium three-level cascade ( 6 S 1 / 2 − 6 P 3 / 2 − 7 S 1 / 2 ) atom in a room temperature vapor cell. A probe laser, λ p = 852 nm, was coupled to a transition | 6 S 1 / 2 ⟩ → | 6 P 3 / 2 ⟩ , related frequency locked to the resonance hyperfine transition of | 6 S 1 / 2 ⟩ → | 6 P 3 / 2 ⟩ with a Fabry–Perot (FP) cavity and an electro-optic modulator (EOM). A coupling laser, λ c = 1470 nm, drove the | 6 P 3 / 2 ⟩ → | 7 S 1 / 2 ⟩ transition with the frequency scanned over the | 6 P 3 / 2 ⟩ → | 7 S 1 / 2 ⟩ transition line. The hyperfine level interval was extracted to be 2183.61 ± 0.50 MHz by analyzing EIS spectroscopy. The optical–optical double-resonance (OODR) spectroscopy is also presented for comparison, with the corresponding value of the hyperfine level interval being 2183.48 MHz ± 0.04 MHz, and the measured hyperfine splitting of excited 7 S 1 / 2 state is shown to be in excellent agreement with the previous work.

scholarly journals Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp3-linked donor-acceptor electronic coupling

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Tao Wang ◽  
Zhubin Hu ◽  
Xiancheng Nie ◽  
Linkun Huang ◽  
Miao Hui ◽  
...  
Keyword(s):  
Excited State ◽  
Room Temperature ◽  
Electronic Coupling ◽  
Temperature Dependent ◽  
Molecular Systems ◽  
Donor And Acceptor ◽  
Theoretical Investigations ◽  
Donor Acceptor ◽  
And Control ◽  
Two Temperature

AbstractAggregation-induced emission (AIE) has proven to be a viable strategy to achieve highly efficient room temperature phosphorescence (RTP) in bulk by restricting molecular motions. Here, we show that by utilizing triphenylamine (TPA) as an electronic donor that connects to an acceptor via an sp3 linker, six TPA-based AIE-active RTP luminophores were obtained. Distinct dual phosphorescence bands emitting from largely localized donor and acceptor triplet emitting states could be recorded at lowered temperatures; at room temperature, only a merged RTP band is present. Theoretical investigations reveal that the two temperature-dependent phosphorescence bands both originate from local/global minima from the lowest triplet excited state (T1). The reported molecular construct serves as an intermediary case between a fully conjugated donor-acceptor system and a donor/acceptor binary mix, which may provide important clues on the design and control of high-freedom molecular systems with complex excited-state dynamics.

scholarly journals Ultra long‐lived triplet excited state in water at room temperature: Insights on the molecular design of tridecafullerenes

2021 ◽  
Author(s):  
Javier Ramos-Soriano ◽  
Alfonso Pérez-Sánchez ◽  
Sergio Ramírez-Barroso ◽  
Beatriz M. Illescas ◽  
Khalid Azmani ◽  
...  
Keyword(s):  
Excited State ◽  
Room Temperature ◽  
Molecular Design ◽  
Triplet Excited State

Chapter Open for the Excited-State Intramolecular Thiol Proton Transfer in the Room-Temperature Solution

2021 ◽  
Author(s):  
Chun-Hsiang Wang ◽  
Zong-Ying Liu ◽  
Chun-Hao Huang ◽  
Chao-Tsen Chen ◽  
Fan-Yi Meng ◽  
...  
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Room Temperature ◽  
Temperature Solution

Paramagnetic Defects in Benitoite

1991 ◽  
Vol 46 (7) ◽  
pp. 579-582 ◽  
Author(s):  
A. B. Vassilikou-Dova ◽  
K. Eftaxias
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Hyperfine Interaction ◽  
Relative Intensity ◽  
Room Temperature ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic ◽  
Magnetic Defects

Abstract In clear, blue, transparent bipyramidal crystals of the rare mineral benitoite, BaTiSi3O9, para­ magnetic defects have been investigated by electron paramagnetic resonance at room temperature and 9.43 GHz. They are attributed to Sn3+ and Fe3+ . A pair of satellites recorded for a wide angular rage around B0 || c (~40°) and a relative intensity of ~ 13% to the central signal is most likely due to hyperfine interaction with 117Sn and 119Sn isotopes. Attempts to bleach the colour of the crystal were unsuccessful.

scholarly journals Nonperturbative generation of above-threshold harmonics from pre-excited argon atoms in intense mid-infrared laser fields

2017 ◽  
Vol 5 ◽  
Author(s):  
Guihua Li ◽  
Hongqiang Xie ◽  
Ziting Li ◽  
Jinping Yao ◽  
Wei Chu ◽  
...  
Keyword(s):  
Excited State ◽  
Femtosecond Laser ◽  
Pulse Energy ◽  
Laser Pulses ◽  
Infrared Laser ◽  
Femtosecond Laser Pulses ◽  
Probe Laser ◽  
Laser Fields ◽  
Mid Infrared ◽  
Highly Nonlinear

We experimentally investigate the generation of above-threshold harmonics completely from argon atoms on an excited state using mid-infrared femtosecond laser pulses. The highly nonlinear dependences of the observed signal on the pulse energy and polarization of the probe laser pulses indicate its nonperturbative characteristic.

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