scholarly journals Rapid Laser Reactive Sintering Synthesis of Colossal Dielectric CCTO Ceramics

2020 ◽  
Vol 10 (10) ◽  
pp. 3510
Author(s):  
Jiayang He ◽  
Yanwei Huang ◽  
Guang Feng ◽  
Si Shen ◽  
Ming Yan ◽  
...  

Calcium copper titanate (CCTO) ceramics were successfully synthesized using a rapid laser reactive sintering method without conventional long heat treatment times. The microstructure, dielectric properties, and impedance spectroscopy results for CCTO sintered at laser power rates of 25–85 W were investigated in detail. The X-ray diffractometry results showed that prepared CCTO is polycrystalline in a cubic structure with high purity. Scanning electron microscopy showed that CCTO sintered at 85 W has a dense microstructure with an average grain size of 30 nm. The dielectric permittivity of CCTO ceramics increased with increasing laser power over the entire frequency range and achieved a value of almost 105 in the low-frequency region. The dielectric permittivity maintained almost constant values from 102 Hz to 107 Hz, with lower dielectric loss (~0.1) from 103 Hz to 106 Hz, demonstrating good frequency stability. The impedance spectroscopy study showed that grain and grain boundary resistance decreased with rising laser power based on two parallel Resistor-Capacitance (RC) equivalent circuits in series. The activation energies for the grain boundaries were calculated from the impedance using the slope of ln σ versus 1/T and were found to be in the range of 0.53–0.63 eV. CCTO synthesized by rapid laser reactive sintering is competitive for practical applications.

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1173
Author(s):  
Ilze Beverte ◽  
Ugis Cabulis ◽  
Sergejs Gaidukovs

As a non-metallic composite material, widely applied in industry, rigid polyurethane (PUR) foams require knowledge of their dielectric properties. In experimental determination of PUR foams’ dielectric properties protection of one-side capacitive sensor’s active area from adverse effects caused by the PUR foams’ test objects has to be ensured. In the given study, the impact of polytetrafluoroethylene (PTFE) films, thickness 0.20 mm and 0.04 mm, in covering or simulated coating the active area of one-side access capacitive sensor’ electrodes on the experimentally determined true dielectric permittivity spectra of rigid PUR foams is estimated. Penetration depth of the low frequency excitation field into PTFE and PUR foams is determined experimentally. Experiments are made in order to evaluate the difference between measurements on single PUR foams’ samples and on complex samples “PUR foams + PTFE film” with two calibration modes. A modification factor and a small modification criterion are defined and values of modifications are estimated in numerical calculations. Conclusions about possible practical applications of PTFE films in dielectric permittivity measurements of rigid PUR foams with one-side access capacitive sensor are made.


2007 ◽  
Vol 561-565 ◽  
pp. 551-555 ◽  
Author(s):  
Lai Jun Liu ◽  
Hui Qing Fan

The effect of stoichiometry, i.e. Ca/Cu ratios (CaCu3xTi4O12, x = 0.8, 0.9, 1.0, 1.1 and 1.2) on the microstructure and electrical properties was investigated. The grain sizes of CaCu3xTi4O12 composition increased sharply with the increase of copper, from ~1 μm with x = 0.8 to ~50 μm with x = 1.2. The real part of dielectric permittivity changed dramatically, the pellet with x = 1.0 had the highest dielectric permittivity ~160, 000 at 1 kHz. Furthermore, the dielectric permittivity of all pellets was impressively large values (between 10, 000 to 1, 000,000 at 100 Hz) and was nearly constant over a wide frequency range between 100 Hz to ~100 MHz. However, the dielectric permittivity of CaCu3xTi4O12 composition is not consistent with the amount of copper and cell parameters and grain sizes. Impedance spectroscopy exhibited that the CaCu3xTi4O12 composition had two semicircle at least at high frequency (~ 107 Hz) and low frequency (<100 Hz), respectively. The grain and grain boundary of the compositions had different impedance and relaxation behavior.


Electronics ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 60
Author(s):  
Mario Ponce-Silva ◽  
Daniel Salazar-Pérez ◽  
Oscar Miguel Rodríguez-Benítez ◽  
Luis Gerardo Vela-Valdés ◽  
Abraham Claudio-Sánchez ◽  
...  

The main contribution of this paper is to show a new AC/DC converter based on the rearrangement of the flyback converter. The proposed circuit only manages part of the energy and the rest is delivered directly from the source to the load. Therefore, with the new topology, the efficiency is increased, and the stress of the components is reduced. The rearrangement consist of the secondary of the flyback is placed in parallel with the load, and this arrangement is connected in series with the primary side and the rectified voltage source. The re-arranged flyback is only a reductive topology and with no magnetic isolation. It was studied as a power supply for LEDs. A low frequency averaged analysis (LFAA) was used to determine the behavior of the proposed circuit and an equivalent circuit much easier to analyze was obtained. To validate the theoretical analysis, a design methodology was developed for the re-arranged flyback converter. The designed circuit was implemented in a 10 W prototype. Experimental results showed that the converter has a THDi = 21.7% and a PF = 0.9686.


Author(s):  
Riaz Ahmed ◽  
Kenneth Reifsnider

Electrochemical Impedance Spectroscopy (EIS) is a powerful and proven tool for analyzing AC impedance response. A conventional three electrode EIS method was used to perform the investigation in the present study. Saturated potassium chloride solution was used as the electrolyte and three different material rods were used as working electrodes. Different configurations of electrode area were exposed to the electrolyte as an active area to investigate electrode geometry effects. Counter to working electrode distance was also altered while keeping the working electrode effective area constant to explore the AC response dependence on the variation of ion travel distance. Some controlled experiments were done to validate the experimental setup and to provide a control condition for comparison with experimental results. A frequency range of 100 mHz to 1 MHz was used for all experiments. In our analysis, we have found a noteworthy influence of electrode geometry on AC impedance response. For all electrodes, impedance decreases with the increase of effective area of the electrolyte. High frequency impedance is not as dependent on geometry as low frequency response. The observed phase shift angle drops in the high frequency region with increased working electrode area, whereas at low frequency the reverse is true. Resistance and capacitive reactance both decrease with an increase of area, but resistance response is more pronounce than reactance. For lower frequencies, small changes in working area produce very distinctive EIS variations. Electrode material as well as geometry was systematically varied in the present study. From these and other studies, we hope to develop a fundamental foundation for understanding specific changes in local geometry in fuel cell (and other) electrodes as a method of designing local morphology for specific performance.


2021 ◽  
Author(s):  
Ping Zhang ◽  
◽  
Wael Abdallah ◽  
Gong Li Wang ◽  
Shouxiang Mark Ma ◽  
...  

It is desirable to evaluate the possibility of developing a deeper dielectric permittivity based Sw measurement for various petrophysical applications. The low frequency, (< MHz), resistivity-based method for water saturation (Sw) evaluation is the desired method in the industry due to its deepest depth of investigation (DOI, up to 8 ft). However, the method suffers from higher uncertainty when formation water is very fresh or has mixed salinity. Dielectric permittivity and conductivity dispersion have been used to estimate Sw and salinity. The current dielectric dispersion tools, however, have very shallow DOI due to their high measurement frequency up to GHz, which most likely confines the measurements within the near wellbore mud-filtrate invaded zones. In this study, effective medium-model simulations were conducted to study different electromagnetic (EM) induced-polarization effects and their relationships to rock petrophysical properties. Special attention is placed on the complex conductivity at 2 MHz due to its availability in current logging tools. It is known that the complex dielectric saturation interpretation at the MHz range is quite difficult due to lack of fully understood of physics principles on complex dielectric responses, especially when only single frequency signal is used. Therefore, our study is focused on selected key parameters: water-filled porosity, salinity, and grain shape, and their effects on the modeled formation conductivity and permittivity. To simulate field logs, some of the petrophysical parameters mentioned above are generated randomly within expected ranges. Formation conductivity and permittivity are then calculated using our petrophysical model. The calculated results are then mixed with random noises of 10% to make them more realistic like downhole logs. The synthetic conductivity and permittivity logs are used as inputs in a neural network application to explore possible correlations with water-filled porosity. It is found that while the conductivity and permittivity logs are generated from randomly selected petrophysical parameters, they are highly correlated with water-filled porosity. Furthermore, if new conductivity and permittivity logs are generated with different petrophysical parameters, the correlations defined before can be used to predict water-filled porosity in the new datasets. We also found that for freshwater environments, the conductivity has much lower correlation with water-filled porosity than the one derived from the permittivity. However, the correlations are always improved when both conductivity and permittivity were used. This exercise serves as proof of concept, which opens an opportunity for field data applications. Field logs confirm the findings in the model simulations. Two propagation resistivity logs measured at 2 MHz are processed to calculate formation conductivity and permittivity. Using independently estimated water-filled porosity, a model was trained using a neural network for one of the logs. Excellent correlation between formation conductivity and permittivity and water-filled porosity is observed for the trained model. This neural network- generated model can be used to predict water content from other logs collected from different wells with a coefficient of correlation up to 96%. Best practices are provided on the performance of using conductivity and permittivity to predict water-filled porosity. These include how to effectively train the neural network correlation models, general applications of the trained model for logs from different fields. With the established methodology, deep dielectric-based water saturation in freshwater and mixed salinity environments is obtained for enhanced formation evaluation, well placement, and reservoir saturation monitoring.


Micromachines ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1380
Author(s):  
Binfeng Yin ◽  
Xinhua Wan ◽  
Changcheng Qian ◽  
A. S. M. Muhtasim Fuad Sohan ◽  
Teng Zhou ◽  
...  

Metal ions in high concentrations can pollute the marine environment. Human activities and industrial pollution are the causes of Cu2+ contamination. Here, we report our discovery of an enzyme method-based microfluidic that can be used to rapidly detect Cu2+ in seawater. In this method, Cu2+ is reduced to Cu+ to inhibit horseradish peroxidase (HRP) activity, which then results in the color distortion of the reaction solution. The chip provides both naked eye and spectrophotometer modalities. Cu2+ concentrations have an ideal linear relationship, with absorbance values ranging from 3.91 nM to 256 μM. The proposed enzyme method-based microfluidic chip detects Cu2+ with a limit of detection (LOD) of 0.87 nM. Other common metal ions do not affect the operation of the chip. The successful detection of Cu2+ was achieved using three real seawater samples, verifying the ability of the chip in practical applications. Furthermore, the chip realizes the functions of two AND gates in series and has potential practical implementations in biochemical detection and biological computing.


2004 ◽  
Vol 1 (3) ◽  
pp. 89-98 ◽  
Author(s):  
Vesna Paunovic ◽  
Ljiljana Zivkovic ◽  
Ljubomir Vracar ◽  
Vojislav Mitic ◽  
Miroslav Miljkovic

In this paper comparative investigations of microstructure and dielectric properties of BaTiO3 ceramics doped with 1.0 wt% of Nb2O5, MnCO3 and CaZrO3 have been done. BaTiO3 samples were prepared using conventional method of solid state sintering at 13000C for two hours. Two distinguish micro structural regions can be observed in sample doped with Nb2O5. The first one, with a very small grained microstructure and the other one, with a rod like grains. In MnCO3 and CaZrO3 doped ceramics the uniform microstructure is formed with average grain size about 0.5- 2?m and 3-5?m respectively. The highest value of dielectric permittivity at room temperature and the greatest change of permittivity in function of temperature were observed in MnCO3/BaTiO3. In all investigated samples dielectric constant after initially large value at low frequency attains a constant value at f = 6kHz. A dissipation factor is independent of frequency greater than 10 kHz and, depending of systems, lies in the range from 0.035 to 0.25. At temperatures above Curie temperatures, the permittivity of all investigated samples follows a Curie- Weiss law. A slight shift of Curie temperature to the lower temperatures, in respect of Curie temperature for undoped BaTiO3, was observed in all investigated samples.


2019 ◽  
Vol 8 (3) ◽  
pp. 209
Author(s):  
Fatima Zahra Krimech ◽  
Salaheddine Sayouri ◽  
Taj-Edine Lamcharfi ◽  
Fatima Zahra Ahjyaje

<p>Pure phase Li<sub>2</sub>TiO<sub>3 </sub>nano-particles were synthesized by the sol-gel method and the structural properties were examined with X-ray diffraction (XRD) technique. The latter showed that these materials, heat treated at relatively low temperature 900°C during 4h compared to the conventional solid-state reaction which calcination temperature is about 900–1100°C for 10 h; crystallize in the monoclinic phase without the presence of secondary phases. The microstructure of the LT ceramic (sintered at 1100°C) were determined by SEM and a good crystalline nature was observed with an average of granular size 2 μm. Moreover, the impedance spectroscopy showed at a higher temperature of 500°C the low-frequency arc due either to the grain boundary or sample-electrode charge transport processes.</p>


Sign in / Sign up

Export Citation Format

Share Document