scholarly journals Comparative Study on the Corrosion Inhibitive Effect of 2-Mecraptobenzothiazole and Na2HPO4 on Industrial Conveying API 5L X42 Pipeline Steel

2019 ◽  
Vol 10 (1) ◽  
pp. 290 ◽  
Author(s):  
Ioannis A. Kartsonakis ◽  
Panagiota Stamatogianni ◽  
Evangelia K. Karaxi ◽  
Costas A. Charitidis
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibition ◽  
Pipeline Steel ◽  
Low Carbon Steel ◽  
Industrial Applications ◽  
Molar Ratio ◽  
Low Carbon ◽  
Construction Machinery ◽  
Protective Layers ◽  
Protection Mechanisms

Mild or low-carbon steel has an increasing utilization and is widely used for building construction, machinery parts, and pipelines, because it can be machined easily and has enhanced weldability as well as a low price. In any case, the corrosion resistance of mild steel under the conditions in industrial applications or in atmosphere is a thoughtful concern. This study inquires into the application of 2-mecraptobenzothiazole (MBT) and Na2HPO4 as corrosion inhibitors for the protection of API 5L X42 pipeline steel in 3.5 wt % NaCl as well as in water from the Athens city supply system. The electrochemical/morphological characterizations of the aforementioned mild steel proved that the corrosion protection mechanisms can be assigned to the protective layers created onto the metal surface because of the presence of the inhibitors, which prevent chloride’s penetration. The synergistic effect of the MBT and Na2HPO4 corrosion inhibition behavior, in a molar ratio of 1:1, revealed that the additives performed effectively with corrosion inhibition efficiency above 90%.

The effect of microstructure and elemental content on corrosion and corrosion inhibition of mild steel in a 0.5 M H2SO4 environment

RSC Advances ◽  
2015 ◽  
Vol 5 (114) ◽  
pp. 93907-93916 ◽  
Author(s):  
Maduabuchi A. Chidiebere ◽  
Emeka E. Oguzie ◽  
Li Liu ◽  
Ying Li ◽  
Akram N. Alshawabkeh ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Corrosion Behavior ◽  
Electrochemical Techniques ◽  
Low Carbon Steel ◽  
Elemental Content ◽  
Surface Microstructure ◽  
Low Carbon ◽  
Surface Probe

The effect of composition and surface microstructure on the corrosion behavior of low carbon steel specimens from Nigeria (NCS) and China (CCS) in a 0.5 M H2SO4 solution has been studied using electrochemical techniques and surface probe techniques.

Crystallographic Texture Control Helps Improve Pipeline Steel Resistance to Hydrogen-Induced Cracking

2010 ◽  
Author(s):  
V. Venegas ◽  
O. Herrera ◽  
F. Caleyo ◽  
J. M. Hallen ◽  
T. Baudin
Keyword(s):  
Grain Boundaries ◽  
Crystallographic Texture ◽  
Pipeline Steel ◽  
Low Carbon Steel ◽  
Rolling Process ◽  
Warm Rolling ◽  
American Petroleum Institute ◽  
Low Carbon ◽  
Steel Rolling ◽  
Hydrogen Induced Cracking

Low-carbon steel specimens, all within API (American Petroleum Institute) specifications, were produced following different thermomechanical paths. After austenization, the samples were rolled and recrystallized. The rolling process was carried out using different reduction-in-thickness degrees and finishing temperatures. The investigated steels showed similar microstructural features but differed considerably in their crystallographic textures and grain boundary distributions. After cathodic hydrogen charging, hydrogen-induced cracking (HIC) was detected in the hot-rolled recrystallized steels, whereas the cold and warm-rolled recrystallized steels proved resistant to this damage. Among the investigated specimens, the HIC-stricken show either the strongest {001}ND texture fiber, the smallest fraction of low-angle grain boundaries, or the weakest {111}ND (γ) texture fiber ({hkl}ND representing crystallographic orientations with {hkl} planes parallel to the steel rolling plane). In contrast, the HIC-resistant steels show the weakest {001}ND texture fiber, the largest fraction of low-angle grain boundaries, and the strongest γ fiber. These results support the hypothesis of this and previous works, that crystallographic texture control, through warm rolling schedules, helps improve pipeline steel resistance to hydrogen-induced cracking.

Joint effect of Fe(II) and Fe(III) cations on corrosion of low-carbon steel in mixture of sulfuric and phosphoric acids containing composite inhibitors based on IFKhAN-92

2021 ◽  
pp. 18-29
Author(s):  
Ya.G. Avdeev ◽  
◽  
A.V. Panova ◽  
T.E. Andreeva ◽  
Yu.I. Kuznetsov ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Joint Effect ◽  
Molar Ratio ◽  
Protective Effects ◽  
Low Carbon ◽  
Experimental Conditions ◽  
Component Mixture ◽  
Similar Solutions

Corrosion of 08PS low-carbon steel was studied in a wide temperature range t = 25—100 °C in 1 M H2SO4 + 1 M H3PO4, 2 M H2SO4 и 2 M H3PO4, inhibited by the binary mixture IFKhAN-92 + KNCS (a molar ratio of components 9:1) and a three-component mixture IFKhAN-92 + KNCS + urotropine (9:1:400), in the presence of high concentrations of Fe(III) and Fe(II) salts, as well as in their joint presence. It is shown that under experimental conditions the corrosion inhibitors under study provide effective protection of steel in 1 M H2SO4 + 1 M H3PO4 even in the presence of Fe(III), Fe(II) salts or their mixtures. The highest protective effects are provided by a three-component inhibitor mixture. Under similar conditions in individual 2 M H3PO4 and, especially, 2 M H2SO4, the protective effects of inhibitors are lower. A stronger deceleration of steel corrosion by composite inhibitors based on IFKhAN-92 in H2SO4 + H3PO4 solutions containing Fe(III) salts in comparison with similar solutions of individual H2SO4, is largely due to the binding of Fe(III) cations by phosphate anions into complexes, that significantly reduces their chemical activity and, as a result the corrosion rate of steel.

scholarly journals Impact of Degree of Hydrophilicity of Pyridinium Bromide Derivatives on HCl Pickling of X-60 Mild Steel: Experimental and Theoretical Evaluations

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 185 ◽  
Author(s):  
Nurudeen A. Odewunmi ◽  
Mohammad A. Jafar Mazumder ◽  
Shaikh A. Ali ◽  
Norah A. Aljeaban ◽  
Bader G. Alharbi ◽  
...  
Keyword(s):  
Mild Steel ◽  
Low Carbon Steel ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Log P ◽  
Low Carbon ◽  
Pyridinium Bromide ◽  
Langmuir Isotherm Model ◽  
Edx Analyses ◽  
Pyridinium Nitrogen

Dodecyl pyridinium bromide (DDPB), tetradecyl pyridinium bromide (TDPB) and dodecyl 1,1′-bispyridinium dibromide (DDBPB) were successfully synthesized, characterized and evaluated for HCl pickling of X-60 low carbon steel. Order of corrosion inhibitions efficiencies, as revealed by both electrochemical and gravimetric studies, is TDPB > DDPB > DDBPB. The degree of hydrophilicity of inhibitors as predicted by a partition coefficient (Log P) and supported by a contact angle measurement was found to be responsible for their order of corrosion inhibition efficiencies. Adsorption of DDPB, TDPB, and DDBPB through the pyridinium nitrogen on mild steel surface was confirmed by ATR-FTIR and SEM-EDX analyses. The pyridinium nitrogen was found not to be the only factor responsible for their efficiency, but hydrophobes and the orientation of the hydrophilic ring were responsible, which incline to the deviation of experimental results and the order of Monte Carlo simulation adsorption energies. DDPB, TDPB, and DDBPB obey the Langmuir isotherm model despite major contributions of the film formed on the surface of X-60 mild steel on their overall inhibition corrosion resistance.

scholarly journals Corrosion Inhibition of Mild Steel in Acidic Media by N-[(3,4-Dimethoxyphenyl)Methyleneamino]-4-Hydroxy-Benzamide

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Kashmitha Muthamma ◽  
Preethi Kumari ◽  
M. Lavanya ◽  
Suma A. Rao
Keyword(s):  
Dft Calculations ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Density Functional ◽  
Surface Characterization ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Low Carbon ◽  
Acid Media

Abstract Mild steel (a low carbon steel) is an affordable engineering material used for many purposes in various environments including mild acidic environment with some precautions. The corrosion behaviour of mild steel (MS) in 0.5 M H2SO4 and 0.5 M HCl, in the temperature range (303–323 K) without and with the inhibitor N-[(3,4-dimethoxyphenyl) methyleneamino]-4-hydroxy-benzamide (DMHB), was investigated using Potentiodynamic polarization and Electrochemical impedance spectroscopy (EIS) techniques supplementing with surface characterization study using scanning electron microscope (SEM) and atomic force spectroscopy (AFM). Experimental observations were found to be in agreement with Density functional theory (DFT) calculations. The inhibition efficiency increases with increase in DMHB concentration and showed maximum inhibition efficiency of 86% in 0.5 M H2SO4 and 81% in 0.5 M HCl, respectively, at concentration of 3 × 10─3 M at 303 K. The inhibition efficiency of DMHB obtained relatively at its lower concentration (3 × 10─3 M) compared to other reported related compounds confirms its potential towards corrosion inhibition. The variation in the kinetic and thermodynamic parameters indicated physisorption of DMHB on MS and its mixed type inhibitive action followed Langmuir’s isotherm model. DFT calculations go along with the experimental results, signifying the potential corrosion inhibition behaviour of DMHB for MS in both the acid media.

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