scholarly journals Chemo- and Stereoselective Reduction of Polyfunctional Carbonyl Compounds by Mucor rouxii

Molecules ◽  
2000 ◽  
Vol 5 (12) ◽  
pp. 370-371
Author(s):  
Constanza Mangone ◽  
Elba Pereyra ◽  
Silvia Moreno de Colonna ◽  
Alicia Baldessari
Keyword(s):  
Carbonyl Compounds ◽  
Mucor Rouxii ◽  
Stereoselective Reduction

Stereoselective reduction of non-cyclic carbonyl compounds by some eumycetes

1986 ◽  
Vol 24 (2) ◽  
pp. 175-177 ◽  
Author(s):  
Fabrizio Aragozzini ◽  
Elisabetta Maconi ◽  
Renato Craveri
Keyword(s):  
Carbonyl Compounds ◽  
Stereoselective Reduction

Stereoselective reduction of non-cyclic carbonyl compounds by some eumycetes

1986 ◽  
Vol 24 (2) ◽  
pp. 175-177 ◽  
Author(s):  
Fabrizio Aragozzini ◽  
Elisabetta Maconi ◽  
Renato Craveri
Keyword(s):  
Carbonyl Compounds ◽  
Stereoselective Reduction

Chemo- and stereoselective reduction of β-keto esters by spores and various morphological forms of Mucor rouxii

2002 ◽  
Vol 30 (5) ◽  
pp. 596-601 ◽  
Author(s):  
Constanza P Mangone ◽  
Elba N.Pereyra ◽  
Silvia Argimón ◽  
Silvia Moreno ◽  
Alicia Baldessari
Keyword(s):  
Mucor Rouxii ◽  
Stereoselective Reduction ◽  
Keto Esters

New Active Iron Based Reducing System for Carbonyl Compounds and Imines. Stereoselective Reduction of Cyclic Ketones.

ChemInform ◽  
2006 ◽  
Vol 37 (26) ◽  
Author(s):  
Yanina Moglie ◽  
Francisco Alonso ◽  
Cristian Vitale ◽  
Miguel Yus ◽  
Gabriel Radivoy
Keyword(s):  
Carbonyl Compounds ◽  
Cyclic Ketones ◽  
Stereoselective Reduction ◽  
Active Iron ◽  
Iron Based

Eco-friendly stereoselective reduction of α,β-unsaturated carbonyl compounds by Er(OTf)3/NaBH4 in 2-MeTHF

Tetrahedron ◽  
2015 ◽  
Vol 71 (7) ◽  
pp. 1132-1135 ◽  
Author(s):  
Monica Nardi ◽  
Giovanni Sindona ◽  
Paola Costanzo ◽  
Manuela Oliverio ◽  
Antonio Procopio
Keyword(s):  
Carbonyl Compounds ◽  
Stereoselective Reduction

scholarly journals Stereoselective Reduction of α-Keto Ester and α-Keto Amide with Marine Actinomycetes, Salinispora strains, as Novel Biocatalysts

2011 ◽  
Vol 4 ◽  
pp. BCI.S7877 ◽  
Author(s):  
Kohji Ishihara ◽  
Hirokazu Nagai ◽  
Kazunari Takahashi ◽  
Mariko Nishiyama ◽  
Nobuyoshi Nakajima
Keyword(s):  
Carbonyl Compounds ◽  
Ethyl Pyruvate ◽  
Conversion Ratio ◽  
High Conversion ◽  
Marine Actinomycetes ◽  
Stereoselective Reduction ◽  
Keto Ester ◽  
Keto Esters ◽  
Salinispora Tropica ◽  
High Conversion Ratio

To clarify the potential ability of marine actinomycetes as biocatalysts, the stereoselective reduction of α-keto esters and α-keto amide using Salinispora arenicola and Salinispora tropica was tested. The reduction of ethyl pyruvate and ethyl 2-oxobutanoate by S. tropica gave corresponding alcohol with high conversion ratio and in high e.e. (96% e.e. ( S) and 99% e.e. ( S), respectively). In the presence of l-glutamate as an additive, the reduction of ethyl pyruvate by S. tropica afforded the corresponding ( S)-ethyl lactate with >99% e.e. Furthermore, 2-chlorobenzoylformamide was reduced by S. tropica to the corresponding ( R)-2-chloromandelamide with high conversion ratio and excellent enantioselectivity (>99% e.e.). Thus, it was found that marine actinomycetes, Salinispora strains, had high ability for the stereoselective reduction of carbonyl compounds as useful biocatalysts.

Sign in / Sign up

Export Citation Format

Share Document