scholarly journals Selective Extraction of Red Phosphor (Y2O3:Eu3+) Constituents from Waste Fluorescent Lamps Phosphor Using Acid Leaching

2018 ◽  
Vol 15 (3) ◽  
Author(s):  
Parul Johar ◽  
Vishal Jangir ◽  
Yogita Choudhary ◽  
Sudhanshu Mallick
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Acid Leaching ◽  
Xrd Analysis ◽  
Selective Extraction ◽  
Phosphor Powder ◽  
Red Phosphor ◽  
Fluorescent Lamps ◽  
Refinement Method ◽  
Lamp Phosphor

Modern fluorescent lamp phosphor powder contains tricolor phosphor. This tricolor phosphor consists of three different types of rare earth phosphors: red (YOX), green (CMAT/LAP) and blue (BAM); mixed in varying proportions. The exact separation of these three rare earth phosphors is essential in order to precisely recover the contained rare earth elements from waste lamps phosphor. In this present work, we reported an efficient methodology for the separation of these three tricolor phosphors and the selective extraction of predominantly presented red phosphor (YOX) constituents using acid leaching. The waste phosphor powder was leached with different acids: both organic and inorganic type. The 3 M H2SO4 leaching was found to be most suitable for the selective extraction of red phosphor constituents, i.e. Y and Eu. The recovered phosphor powder was analyzed with SEM/EDS and XRD analysis. The obtained XRD pattern was refined using Rietveld refinement method for the quantification of phases present. Recovered red phosphor powder contained three main crystalline phases Y2O3, Eu2O3 and Y2OS2. KEYWORDS: Waste Lamp Phosphor; Tricolor Phosphor; Rare Earth Elements; Acid Leaching

Leaching of rare earth elements from waste lamp phosphor mixtures by reduced alkali fusion followed by acid leaching

2016 ◽  
Vol 163 ◽  
pp. 99-103 ◽  
Author(s):  
Yong Liang ◽  
Yuanxin Liu ◽  
Rudan Lin ◽  
Doudou Guo ◽  
Chunfa Liao
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Acid Leaching ◽  
Alkali Fusion ◽  
Lamp Phosphor

scholarly journals Production of Porous Ceramic Materials from Spent Fluorescent Lamps

2021 ◽  
Vol 11 (13) ◽  
pp. 6056
Author(s):  
Egle Rosson ◽  
Acacio Rincón Rincón Romero ◽  
Denis Badocco ◽  
Federico Zorzi ◽  
Paolo Sgarbossa ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
High Speed ◽  
Porous Ceramic ◽  
Ceramic Materials ◽  
Porous Ceramics ◽  
Fluorescent Lamps ◽  
Naoh Solution ◽  
Commercial Glass ◽  
Triton X

Spent fluorescent lamps (SFL) are classified as hazardous materials in the European Waste Catalogue, which includes residues from various hi-tech devices. The most common end-of-life treatment of SFL consists in the recovery of rare earth elements from the phosphor powders, with associated problems in the management of the glass residues, which are usually landfilled. This study involves the manufacturing of porous ceramics from both the coarse glass-rich fraction and the phosphor-enriched fraction of spent fluorescent lamps. These porous materials, realizing the immobilization of Rare Earth Elements (REEs) within a glass matrix, are suggested for application in buildings as thermal and acoustic insulators. The proposed process is characterized by: (i) alkaline activation (2.5 M or 1 M NaOH aqueous solution); (ii) pre-curing at 75 °C; (iii) the addition of a surfactant (Triton X-100) for foaming at high-speed stirring; (iv) curing at 45 °C; (v) viscous flow sintering at 700 °C. All the final porous ceramics present a limited metal leaching and, in particular, the coarse glass fraction activated with 2.5 M NaOH solution leads to materials comparable to commercial glass foams in terms of mechanical properties.

Selective Extraction of Thorium from Rare Earth Elements Using Wrinkled Mesoporous Carbon

2018 ◽  
Vol 140 (44) ◽  
pp. 14735-14739 ◽  
Author(s):  
Zijie Wang ◽  
Alexander T. Brown ◽  
Kui Tan ◽  
Yves J. Chabal ◽  
Kenneth J. Balkus
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Mesoporous Carbon ◽  
Selective Extraction

Process investigation of the acid leaching of rare earth elements from phosphogypsum using HCl, HNO3, and H2SO4

2016 ◽  
Vol 166 ◽  
pp. 195-204 ◽  
Author(s):  
Mugdha Walawalkar ◽  
Connie K. Nichol ◽  
Gisele Azimi
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Acid Leaching

Selective Nitric Acid Leaching of Rare-Earth Elements from Calcium and Phosphate in Fluorapatite Concentrate

JOM ◽  
2019 ◽  
Vol 71 (12) ◽  
pp. 4578-4587 ◽  
Author(s):  
Seyed Ramin Banihashemi ◽  
Bijan Taheri ◽  
Seyed Mohammad Razavian ◽  
Faraz Soltani
Keyword(s):  
Rare Earth ◽  
Nitric Acid ◽  
Rare Earth Elements ◽  
Acid Leaching ◽  
Nitric Acid Leaching

scholarly journals A biosorption-based approach for selective extraction of rare earth elements from coal byproducts

2020 ◽  
Vol 241 ◽  
pp. 116726 ◽  
Author(s):  
Dan Park ◽  
Andrew Middleton ◽  
Ryan Smith ◽  
Gauthier Deblonde ◽  
Dan Laudal ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Selective Extraction

scholarly journals Environmentally friendly comprehensive hydrometallurgical method development for neodymium recovery from mixed rare earth aqueous solutions using organo-phosphorus derivatives

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Verónica Cristina Arellano Ruiz ◽  
Rambabu Kuchi ◽  
Pankaj Kumar Parhi ◽  
Jin-Young Lee ◽  
Rajesh Kumar Jyothi
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Method Development ◽  
Neodymium Oxide ◽  
Selective Extraction ◽  
Extractant Concentration ◽  
Cyanex 272 ◽  
Extraction Behavior ◽  
Technology Applications ◽  
Hydrometallurgical Method

Abstract Rare earth elements (REEs) have obtained a greatest significant in human lives owing to their important roles in various high technology applications. The present method development was deal technology important REEs such as neodymium, terbium and dysprosium, selective extraction with possible separation and recovery studies, successfully. The chloride mediated mixed aqueous solution containing 1500 mg/L each of REEs such as Nd, Tb and Dy was subjected at selective separation of Nd from other associated REEs. Three organo-phosphorous based commercial extracting agents such as Cyanex 272, PC 88A and D2EHPA, were employed for the extraction, possible separation and recovery of rare earth elements. A comparative extraction behavior of all these three extractants as function of time, pH influence, extractant concentration, temperature and diluents were systematically investigated. The extraction tendency of organo-phosphorus reagents towards the extraction of either of the REEs follows of the sequence as: D2EHPA > PC 88A > Cyanex 272. The thermodynamic behavior of either of the extractants on liquid–liquid extraction processing of REEs was investigated and thermodynamic calculations were calculated and presented. Substantial recovery of neodymium oxalate followed by its calcined product as neodymium oxide was ascertained from XRD study and SEM–EDS analysis.

scholarly journals Optimization of Acid Leaching of Rare-Earth Elements from Mongolian Apatite-Based Ore

Minerals ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 63 ◽  
Author(s):  
Rina Kim ◽  
Heechan Cho ◽  
Kenneth Han ◽  
Kihong Kim ◽  
Myoungwook Mun
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Acid Leaching

scholarly journals Acid leaching recovery and occurrence modes of rare earth elements (REEs) from natural kaolinites

2022 ◽  
Vol 175 ◽  
pp. 107278
Author(s):  
Bin Ji ◽  
Qi Li ◽  
Rick Honaker ◽  
Wencai Zhang
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Acid Leaching
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