scholarly journals Study of Ceramic Membrane from Naturally Occurring-Kaolin Clays for Microfiltration Applications

2017 ◽  
Vol 61 (3) ◽  
pp. 206 ◽  
Author(s):  
Sonia Bouzid Rekik ◽  
Jamel Bouaziz ◽  
Andre Deratani ◽  
Semia Beklouti

The focus of this work is to assess the quality of porous membranes prepared from naturally occurring kaolin clays and to evaluate the performance of tubular ceramic membranes treating integrated raw effluents from seafood industry. This material has been chosen due to its natural abundance, its non-toxicity, low cost and its valuable properties. The preparation and characterization of porous tubular ceramic membranes, using kaolin powder with and without corn starch as poreforming agent, were reported. SEM photographs indicated that the membrane surface was homogeneous. The effects of material compositions, additives and the relatively lower sintering temperature, ranging from 1100° to 1250°C, on porosity, average pore size, pore-size distribution and mechanical strength of membranes have been investigated. A correlation between microstructure and mechanical properties of membranes has been discussed. The performance of the novel ceramic membranes thus obtained was determined by evaluating both the water permeability and rejection. The obtained membrane was used to treat cuttlefish effluents generated from the conditioning seawater product industry which consumes a great amount of water. Cross-flow microfiltration was performed then, in order to reduce the turbidity and chemical oxygen demand (COD). 

Membranes ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 290
Author(s):  
Saad A. Aljlil

In this study, a method for fabricating tubular ceramic membranes via extrusion using economical and locally available bentonite–silica sand and waste palm leaves was developed as a tool for conducting the necessary task of purifying water polluted with oil and suspended solid materials produced via various industrial processes. The developed tubular ceramic membranes were found to be highly efficient at separating the pollutants from water. The properties of the fabricated membrane were evaluated via mechanical testing, pore size distribution analysis, and contact angle measurements. The water contact angle of the fabricated membrane was determined to be 55.5°, which indicates that the membrane surface is hydrophilic, and the average pore size was found to be 66 nm. The membrane was found to demonstrate excellent corrosion resistance under acidic as well as basic conditions, with weight losses of less than 1% in each case. The membrane surface was found to be negatively charged and it could strongly repulse the negatively charged fine bentonite particles and oil droplets suspended in the water, thereby enabling facile purification through backwashing. The obtained ceramic membranes with desirable hydrophilic properties can thus serve as good candidates for use in ultrafiltration processes.


Author(s):  
Renata Natsumi Haneda ◽  
Se´rgio Rodriques Fontes

This paper reports the results of the crossflow microfiltration process applied to the reduction of bacteria and retention of particles in suspension of ac¸ai (Euterpe oleracea Mart.) juice. A commercial membrane of α-alumina (Al2O3) in the form of a tube with 1.2μm of average pore size was utilized to investigate the reduction of the bacteria of ac¸ai juice without using high temperatures (pasteurization). This pore size of the ceramic structure was utilized in an attempt to reduce the polarization phenomenon and improve the permeate flux without utilizing the usual enzymatic treatment made in the microfiltration processes that utilize polymeric membrane (Cianci et al., 2005 and Ushikubo et al., 2006). An anthocyanin concentration was also observed during the microfiltration process followed by suspended particles retention as an indicator of ac¸ai juice clarifying. The Scanning Electronic Microscopy (SEM) was utilized as an essential tool to characterize the morphology of the ceramic micro porous structure and to evaluate the formation of a polarization layer on the membrane surface, while the Optical Microscopy was used to analyze the difference in the characteristics between samples of concentrate and permeate.


Author(s):  
A. I. Ivanets

The main factors affecting the physicochemical properties of microfiltration ceramic membranes based on natural quartz sand were studied. It was found that samples of large-porous ceramics with a content of 11.0 wt. % of the aluminosilicate binder and 10.0 wt. % of the burning additive are characterized by average pore size of 22±3.02 µm, water capacity of 54±5.0 m3/(h×m2×bar), and tensile strength of 9.0±0.6 bar. The optimal conditions for membrane layers coating were determined, which allowed obtaining microfiltration ceramic membranes with average pore size of 2.3±0.2 µm, water capacity of 26±1.0 m3/(h×m2×bar) and tensile strength of 6.5±0.3 bar.


Author(s):  
E. Yuliwati ◽  
H. Porawati ◽  
Elfidiah Elfidiah ◽  
A. Melani

Polyvinylidene fluoride (PVDF) composite membranes were prepared via phase inversion method by dispersing titanium dioxide (TiO2) in the dope solution. It is aimed to study the effects of TiO2 on the membrane surface properties and thus its separation performance. The PVDF membranes modified by various TiO2 contents were characterized with respect to cross-sectional structure, average pore size, effective porosity, hydrophilicity, permeability and rejection. Maximum values of membrane hydrophilicity, membrane porosity and average pore size were achieved upon addition of 1.95% TiO2. It is found that changes in the membrane surface properties are closely corresponded with the membrane fouling. The maximum flux and rejection of organic pollutants from palm oil wastewater were recorded at 82.5 L/m2 h and 98.8 %, respectively using PVDF composite membrane incorporated with 1.95% TiO2.


Membranes ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 739
Author(s):  
Mohamad Izrin Mohamad Esham ◽  
Abdul Latif Ahmad ◽  
Mohd Hafiz Dzarfan Othman

The main problem usually faced by commercial ceramic membranes in the treatment of produced water (PW) is low water flux even though ceramic membrane was well-known with their excellent mechanical, thermal, and chemical properties. In the process of minimizing the problem faced by commercial ceramic membranes, titanium dioxide (TiO2) nanocomposites, which synthesized via a sol-gel method, were deposited on the active layer of the hydrolysed bentonite membrane. This paper studied the influence of grafting time of TiO2 nanocomposite on the properties and performance of the coated bentonite membranes. Several characterizations, which are Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy-dispersive X-ray Spectroscopy (EDX), contact angle, porosity, and average pore size, were applied to both pristine and coated bentonite membranes to compare the properties of the membranes. The deposition of TiO2 nanoparticles on the surface of the coated bentonite membranes was successfully confirmed by the characterization results. The pure water flux performance showed an increment from 262.29 L h−1 m−² bar−1 (pristine bentonite membrane) to 337.05 L h−1 m−² bar−1 (Ti-Ben 30) and 438.33 L h−1 m−² bar−1 (Ti-Ben 60) as the grafting time increase but when the grafting time reached 90 min (Ti-Ben 90), the pure water flux was decreased to 214.22 L h−1 m−² bar−1 which is lower than the pristine membrane. The oil rejection performance also revealed an increase in the oil rejection performance from 95 to 99%. These findings can be a good example to further studies and exploit the advantages of modified ceramic membranes in PW treatment.


2021 ◽  
Author(s):  
Sushma Chakraborty ◽  
Ramagopal Uppaluri ◽  
Chandan Das

Abstract In this work, the influence of inorganic low-cost precursor compositions (viz. kaolin, feldspar, saw dust, sodium metasilicate and boric acid) has been investigated on the morphological characteristics (such as average pore size and porosity) of the ceramic membranes that were fabricated using dry compaction method and saw dust as the pore forming agent. In order to do so, kaolin to feldspar ratio has been varied from 0.48 – 2.05 and binder composition has been varied from 10 – 15 wt.%. For an inorganic precursor formulation of kaolin 38.77 wt.%, feldspar 23.03 wt.%, saw dust 8.19 wt.%, sodium metasilicate 15 wt.% and boric acid 15 wt.%, the sub-micron range low-cost ceramic membranes (95.8 nm average pore size and 13.95% porosity) have been achieved as a key novelty. With minor variations in the precursor composition, the microfiltration membranes could be converted to ultrafiltration membranes without undergoing any complex surface reactions or polymeric coatings. An empirical model has been as well developed to quantify the variation of dependent variables on the membrane characteristics.


2017 ◽  
Vol 54 (3) ◽  
pp. 181-201
Author(s):  
Rebecca Johnson ◽  
Mark Longman ◽  
Brian Ruskin

The Three Forks Formation, which is about 230 ft thick along the southern Nesson Anticline (McKenzie County, ND), has four “benches” with distinct petrographic and petrophysical characteristics that impact reservoir quality. These relatively clean benches are separated by slightly more illitic (higher gamma-ray) intervals that range in thickness from 10 to 20 ft. Here we compare pore sizes observed in scanning electron microscope (SEM) images of the benches to the total porosity calculated from binned precession decay times from a suite of 13 nuclear magnetic resonance (NMR) logs in the study area as well as the logarithmic mean of the relaxation decay time (T2 Log Mean) from these NMR logs. The results show that the NMR log is a valid tool for quantifying pore sizes and pore size distributions in the Three Forks Formation and that the T2 Log Mean can be correlated to a range of pore sizes within each bench of the Three Forks Formation. The first (shallowest) bench of the Three Forks is about 35 ft thick and consists of tan to green silty and shaly laminated dolomite mudstones. It has good reservoir characteristics in part because it was affected by organic acids and received the highest oil charge from the overlying lower Bakken black shale source rocks. The 13 NMR logs from the study area show that it has an average of 7.5% total porosity (compared to 8% measured core porosity), and ranges from 5% to 10%. SEM study shows that both intercrystalline pores and secondary moldic pores formed by selective partial dissolution of some grains are present. The intercrystalline pores are typically triangular and occur between euhedral dolomite rhombs that range in size from 10 to 20 microns. The dolomite crystals have distinct iron-rich (ferroan) rims. Many of the intercrystalline pores are partly filled with fibrous authigenic illite, but overall pore size typically ranges from 1 to 5 microns. As expected, the first bench has the highest oil saturations in the Three Forks Formation, averaging 50% with a range from 30% to 70%. The second bench is also about 35 ft thick and consists of silty and shaly dolomite mudstones and rip-up clast breccias with euhedral dolomite crystals that range in size from 10 to 25 microns. Its color is quite variable, ranging from green to tan to red. The reservoir quality of the second bench data set appears to change based on proximity to the Nesson anticline. In the wells off the southeast flank of the Nesson anticline, the water saturation averages 75%, ranging from 64% to 91%. On the crest of the Nesson anticline, the water saturation averages 55%, ranging from 40% to 70%. NMR porosity is consistent across the entire area of interest - averaging 7.3% and ranging from 5% to 9%. Porosity observed from samples collected on the southeast flank of the Nesson Anticline is mainly as intercrystalline pores that have been extensively filled with chlorite clay platelets. In the water saturated southeastern Nesson Anticline, this bench contains few or no secondary pores and the iron-rich rims on the dolomite crystals are less developed than those in the first bench. The chlorite platelets in the intercrystalline pores reduce average pore size to 500 to 800 nanometers. The third bench is about 55 ft thick and is the most calcareous of the Three Forks benches with 20 to 40% calcite and a proportionate reduction in dolomite content near its top. It is also quite silty and shaly with a distinct reddish color. Its dolomite crystals are 20 to 50 microns in size and partly abraded and dissolved. Ferroan dolomite rims are absent. This interval averages 7.1% porosity and ranges from 5% to 9%, but the pores average just 200 nanometers in size and occur mainly as microinterparticle pores between illite flakes in intracrystalline pores in the dolomite crystals. This interval has little or no oil saturation on the southern Nesson Anticline. Unlike other porosity tools, the NMR tool is a lithology independent measurement. The alignment of hydrogen nuclei to the applied magnetic field and the subsequent return to incoherence are described by two decay time constants, longitudinal relaxation time (T1) and transverse relaxation time (T2). T2 is essentially the rate at which hydrogen nuclei lose alignment to the external magnetic field. The logarithmic mean of T2 (T2 Log Mean) has been correlated to pore-size distribution. In this study, we show that the assumption that T2 Log Mean can be used as a proxy for pore-size distribution changes is valid in the Three Forks Formation. While the NMR total porosity from T2 remains relatively consistent in the three benches of the Three Forks, there are significant changes in the T2 Log Mean from bench to bench. There is a positive correlation between changes in T2 Log Mean and average pore size measured on SEM samples. Study of a “type” well, QEP’s Ernie 7-2-11 BHD (Sec. 11, T149N, R95W, McKenzie County), shows that the 1- to 5-micron pores in the first bench have a T2 Log Mean relaxation time of 10.2 msec, whereas the 500- to 800-nanometer pores in the chlorite-filled intercrystalline pores in the second bench have a T2 Log Mean of 4.96 msec. This compares with a T2 Log Mean of 2.86 msec in 3rd bench where pores average just 200 nanometers in size. These data suggest that the NMR log is a useful tool for quantifying average pore size in the various benches of the Three Forks Formation.


2021 ◽  
Vol 13 (14) ◽  
pp. 7593
Author(s):  
Farooq Khan Niazi ◽  
Malik Adeel Umer ◽  
Ashfaq Ahmed ◽  
Muhammad Arslan Hafeez ◽  
Zafar Khan ◽  
...  

Ultrafiltration membranes offer a progressive and efficient means to filter out various process fluids. The prime factor influencing ultrafiltration to a great extent is the porosity of the membranes employed. Regarding membrane development, alumina membranes are extensively studied due to their uniform porosity and mechanical strength. The present research work is specifically aimed towards the investigation of nanoporous alumina membranes, as a function of sintering parameters, on ultrafiltration performance. Alumina membranes are fabricated by sintering at various temperatures ranging from 1200–1300 °C for different holding times between 5–15 h. The morphological analysis, conducted using Scanning electron microscopy (SEM), revealed a homogeneous distribution of pores throughout the surface and cross-section of the membranes developed. It was observed that an increase in the sintering temperature and time resulted in a gradual decrease in the average pore size. A sample with an optimal pore size of 73.65 nm achieved after sintering at 1250 °C for 15 h, was used for the evaluation of ultrafiltration performance. However, the best mechanical strength and highest stress-bearing ability were exhibited by the sample sintered at 1300 °C for 5 h, whereas the sample sintered at 1250 °C for 5 h displayed the highest strain in terms of compression. The selected alumina membrane sample demonstrated excellent performance in the ultrafiltration of sugarcane juice, compared to the other process liquids.


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