scholarly journals Trace Elements in Almandine Garnet, Vemireddipalle Area, Krishna District, Andhra Pradesh, India

Author(s):  
Nazia Sultana

Almandine is an iron-aluminium garnet and the deep red transparent stones are often called precious garnet and are used as gemstones. The aim of the research is to study the trace element concentrations. ICP-MS is used to analyze the trace elements. The study found that Y, Zn, Sc, Cr, V, Zr and Co are present comparatively in higher concentrations.

Nutrients ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 3548
Author(s):  
Sabrina H. Bilston-John ◽  
Ardra Narayanan ◽  
Ching T. Lai ◽  
Alethea Rea ◽  
John Joseph ◽  
...  

Longitudinal variations of macro- and trace elements in human milk (HM) are not well characterised, and therefore, the recommendations for intake for Australian infants require more evidence to ensure accuracy. We aimed to investigate the longitudinal variation of HM macro- and trace-element concentrations (1–12 months) and infant intake (1–6 months) and to investigate the relationships between intake and infant growth parameters at 3 and 6 months, and determine if intake was sufficient when compared to national guidelines. HM samples were collected monthly for the first 6 months and then at 9 and 12 months postpartum from mother–infant dyads (n = 83). Test–weighing was used to determine the volume of HM consumed daily. Element concentrations (Na, Ca, K, Mg, P, I, Se, Zn, Cu, Mn, Mo, and Fe) were measured using ICP-MS, and intake was calculated using the measured concentrations and the volume of HM consumed. The average intake of HM was 776.3 ± 24.0 mL for the infants. Changes in concentration from months 1 to 12 postpartum were observed for all the measured micronutrients (all p < 0.05). The calculated intakes of all the macro- and trace elements showed that 0% to 82% of infants met the current adequate recommendations at varying periods of lactation. The calculated macro- and trace-element intakes were below the adequate intake recommendations, suggesting that they are not reflective of healthy infant requirements. These findings suggest the need for larger studies using sensitive analytical techniques and the revision of current recommendations for breastfed infants.


OENO One ◽  
2022 ◽  
Vol 56 (1) ◽  
pp. 29-40
Author(s):  
Robin Cellier ◽  
Sylvain Berail ◽  
Ekaterina Epova ◽  
Julien Barre ◽  
Fanny Claverie ◽  
...  

Thirty-nine Champagnes from six different brands originating from the AOC Champagne area were analyzed for major and trace element concentrations in the context of their production processes and in relation to their geographical origins. Inorganic analyses were performed on the must (i.e., grape juice) originating from different AOC areas and the final Champagne. The observed elemental concentrations displayed a very narrow range of variability. Typical concentrations observed in Champagne are expressed in mg/L for elements such as K, Ca, Mg, Na, B, Fe, A, and Mn. They are expressed in µg/L for trace elements such as Sr, Rb, Ba, Cu, Ni, Pb Cr and Li in decreasing order of concentrations. This overall homogeneity was observed for Sr and Rb in particular, which showed a very narrow range of concentrations (150 < Rb < 300 µg/L and 150 < Sr < 350 µg/L) in Champagne. The musts contained similar levels of concentration but showed slightly higher variability since they are directly influenced by the bedrock, which is quite homogenous in the AOC area being studied. Besides the homogeneity of the bedrock, the overall stability of the concentrations recorded in the samples can also be directly linked to the successive blending steps, both at the must level and prior to the final bottling. A detailed analysis of the main additives, sugar, yeast and bentonite, during the Champagne production process, did not show a major impact on the elemental signature of Champagne.


Author(s):  
John D. Greenough ◽  
Alejandro Velasquez ◽  
Mohamed Shaheen ◽  
Joel Gagnon ◽  
Brian J. Fryer ◽  
...  

Trace elements in native gold provide a “fingerprint” that tends to be unique to individual gold deposits. Fingerprinting can distinguish gold sources and potentially yield insights into geochemical processes operating during gold deposit formation. Native gold grains come from three historical gold ore deposits; Hollinger, McIntyre (quartz-vein ore), and Aunor near Timmins, Ontario, at the western end of the Porcupine gold camp and the south-western part of the Abitibi greenstone belt. Laser-ablation, inductively-coupled plasma mass spectrometry (LA ICP MS) trace element concentrations were determined on 20 to 25 µm wide, 300 µm long rastor trails in ~ 60 native gold grains. Analyses used Ag as an internal standard with Ag and Au determined by a scanning electron microscope with an energy dispersive spectrometer. The London Bullion Market AuRM2 reference material served as the external standard for 21 trace element analytes (Al, As, Bi, Ca, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Pd, Pt, Rh, Sb, Se, Si, Sn, Te, Ti, Zn; Se generally below detection in samples). Trace elements in native gold associate according to Goldschmidt’s classification of elements strongly suggesting that element behavior in native Au is not random. Such element behavior suggests that samples from each Timmins deposit formed under similar but slightly variable geochemical conditions. Chalcophile and siderophile elements provide the most compelling fingerprints of the three ore deposits and appear to be mostly in solid solution in Au. Lithophile elements are not very useful for distinguishing these deposits and element ABSTRACT CUT OFF BY SOFTWARE


Author(s):  
Diana Flood

Migratory fish-eating birds occupy the highest trophic positions of aquatic ecosystems and as such serve as invaluable end-point indicators of the presence and bioaccumulation of anthropogenic contaminants. The birds’ main route of contaminant exposure is through food consumption. Migration can complicate this pathway by introducing numerous feeding habitats and thus, potential sources of contamination. Birds possess a number of depuration mechanisms that permit them to reduce their contaminant burden, namely the elimination of metals and mercury (Hg) through their feathers, feces and eggs. Trace element concentrations found in the feathers reflect the contaminants circulating in the body at the time of feather growth, representing local exposure and potential mobilization from internal tissues. Molt schedules and patterns are important considerations when selecting feathers to link feeding ecology with contaminants, as migratory birds’ feathers grow on and represent different sites. Stable nitrogen (δ15N) and carbon (δ13C) and hydrogen isotopes (δD) can reveal feeding ecology and habitat use during their annual cycle. Consequently, anthropogenic and natural sources of metal accumulation can be linked to those ecological variables. This study will examine the assimilation of trace element in male Caspian Tern (Sterna caspia) and Double-crested Cormorant (Phalacrocorax auritus) breast feathers grown on wintering sites and stable isotope signatures will be used to determine origin of contaminants. The aims for this study are to determine (i) whether isotopic signatures of feathers grown on wintering sites can explain variations in feather trace element concentrations, (ii) whether isotopes can determine the source of contamination, and (iii) whether differences in trace elements between individuals are determined by location of wintering ground or species.


2021 ◽  
Author(s):  
Jesse Walters ◽  
Alicia Cruz-Uribe ◽  
Won Joon Song ◽  
Joshua Stone ◽  
Hanna Brooks ◽  
...  

&lt;p&gt;Here we present titanite U-Pb dates from two banded calc silicate gneisses (SSP18-1A and 1B) from western Maine. Mineral textures and compositions display multiple phases of metamorphism. The peak lower granulite facies assemblage is Di + Kfs + Pl + Ttn, with little to no calcite present. Late Czo + Tr replaces Di + Pl, suggesting an influx of X&lt;sub&gt;H2O&lt;/sub&gt; &gt; 0.90 fluids. Nearby metapelites show the transition from sillimanite-bearing to muscovite-bearing assemblages, indicating that fluid infiltration may be widespread. Compositional maps of clinopyroxene in SSP18-1B show fracturing and rehealing of early Fe-rich diopside with late Mg-rich diopside. Both samples exhibit overprinting of An-rich plagioclase by increasingly Ab-rich plagioclase. Titanite grains in both samples exhibit BSE textures and compositional variation consistent with multiple phases of growth and dissolution-reprecipitation reactions.&lt;/p&gt;&lt;p&gt;Titanite trace element and U-Pb data were collected by LA-ICP-MS at the University of Maine using an ESI NWR193&lt;sup&gt;UC&lt;/sup&gt; excimer laser ablation system coupled to an Agilent 8900 ICP-MS. Single spot ages range from 280 to 400 Ma with 12-20 Ma propagated 2SE. Four composition-date domains are identified in SSP18-1B: A. 400 &amp;#177; 8 Ma (dark BSE cores), B. 372 &amp;#177; 4 Ma (bright BSE cores), C. 342 &amp;#177; 6 Ma (bright BSE cores, no Eu anomaly), and D. 302 &amp;#177; 3 Ma (dark BSE rims, low LREE). Titanite Fe and Y concentrations increase with decreasing date, whereas Sr concentrations decrease. In clinopyroxene, Fe and Y decrease between high Fe-diopside and late Mg-diopside, placing the fracturing and rehealing events between 400 and 372 Ma. Strontium concentrations in titanite decrease between subsequent generations of plagioclase, diopside, and titanite, suggesting a continual fractionation of Sr from the reactive bulk composition. Low LREE in ca. 300 Ma titanite domains in both samples are consistent with the formation of texturally late allanite and clinozoisite, thus constraining the timing of the high X&lt;sub&gt;H2O&lt;/sub&gt; fluid infiltration event. Zr-in-titanite temperatures for rims in the quartz-bearing SSP18-1B give a weighted mean T of 764 &amp;#176;C at 4.5 GPa, consistent with the muscovite-absent sillimanite-bearing assemblage in garnet cores from metapelite samples. However, the 100-150 &amp;#176;C lower Grt-Bt temperatures for metapelites are not consistent with peak metamorphic phase equilibria. Our data demonstrate the utility of linking titanite textures and trace element concentrations with those of other minerals to reveal past metamorphic and deformational events. Additionally, we show that titanite may reliably preserve U and Pb isotopic ratios, trace elements, and textures over subsequent high-T metamorphic events.&lt;/p&gt;


2020 ◽  
Vol 313 ◽  
pp. 126094 ◽  
Author(s):  
Angela Giorgia Potortì ◽  
Giuseppe Daniel Bua ◽  
Vincenzo Lo Turco ◽  
Asma Ben Tekaya ◽  
Asma Beltifa ◽  
...  

2019 ◽  
Vol 42 (5) ◽  
pp. 1235-1254
Author(s):  
Jemal Ahmed

Abstract This paper reports the results of trace elements geochemistry from Tigray national state, northwestern Ethiopia. The area is part of the Arabian-Nubian Shield, where the dominant exposure is low-grade metamorphic rocks and has a long history of liver-related diseases. The increase in the number of liver-related disease patients of the area has been an environmental health issue of national concern. The aim of the study is to determine the level of trace element concentrations and distributions in water and stream sediments of the area and identify the possible sources in relation to human health. Water, stream sediment and rocks samples (20 water, 20 stream sediments, and 6 rock samples) were collected in March 2011 and analyzed for major and trace element contents using ICP-MS, ICP-OES, ion Chromatography, and XRF methods. Bromine, aluminum, fluorine, arsenic, and nitrate values exceed the WHO maximum acceptable concentration (MAC) for drinking purpose. Bromine ranges from 0.11 to 1.48 mg/l show higher values in all samples, and fluorine ranges from 0.21 to 16.49 mg/l show higher values in 20% of the samples. Other trace elements are aluminum—30%, arsenic—10%, and nitrate (NO3)—10%, and they are examples of elements which have above MAC for drinking water. Selenium deficiency may be the other problematic element in the area for which its deficiency is associated with liver damage and heart muscle disorder. The concentration of cobalt and chromium exceeded world geochemical background value in average shale at most sample stations indicated that these stations were in potential risk.


1976 ◽  
Vol 10 (2) ◽  
pp. 74-76 ◽  
Author(s):  
Richard P. Hoffmann ◽  
Daniel M. Ashby

The use of trace-elements in intravenous hyperalimentation solutions has been recommended for long-term therapy. Very little information is available concerning the presence of these nutrients as contaminants in commercially available solutions. In view of this, the concentrations of copper and zinc were measured in twenty solutions by atomic absorption. The results indicate that the amounts present may be significant in certain solutions.


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