Synthesis and Characterization of Nanocomposite of Copolymer of N-Methyl Pyrrole (NMPy) and N, N-Dimethyl Aniline (NDMA)

2019 ◽  
pp. 124-129
Author(s):  
R. Rathore ◽  
Soni Sharma
Keyword(s):  
Electrical Conductivity ◽  
Surface Morphology ◽  
Oxidative Polymerization ◽  
Polymer Nanocomposite ◽  
Xrd Analysis ◽  
Probe Method ◽  
Synthesis And Characterization ◽  
Chemical Oxidative Polymerization ◽  
Amorphous Nature

Nanocomposite of copolymer of N-Methyl pyrrole (NMPy) and N, N-Dimethyl aniline (NDMA) doped with HCl was synthesized by chemical oxidative polymerization. APS was used as oxidant. The sample was characterized by FTIR, TGA, XRD and four probe method. FTIR confirms the formation of copolymer and its structure. XRD analysis shows the amorphous nature of polymer nanocomposite. The electrical conductivity of sample was measured by using four probe method. Size and surface morphology were demonstrated by SEM.

scholarly journals Facial Synthesis and Characterization of Polypyrrole/zinc oxide (ZnO) Nanorode and Flower-like Shape Composites

2018 ◽  
Vol 34 (1) ◽  
Author(s):  
Sang Nguyen Xuan
Keyword(s):  
Zinc Oxide ◽  
Oxidative Polymerization ◽  
Polymer Nanocomposite ◽  
Synthesis And Characterization ◽  
Chemical Oxidative Polymerization ◽  
Sem Images ◽  
X Ray ◽  
Polymerization Method ◽  
Composite Samples

Polypyrrole (PPy) nanocomposites reinforced with zinc oxide (ZnO) nanorod and nano flower were fabricated by chemical oxidative polymerization method using an ammonium per-sulphate (APS, (NH4)2S2O8) as an oxidizing agent. The polymer nanocomposite were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR). The results were compared with pure as-prepared PPy. The SEM images of the nanocomposites show homogeneous dispersion characteristics and different morphologies of ZnO structures such as rod and flower-like shapes.  In the FTIR spectra, composite samples showed characteristic peaks of PPy shifted to higher positions confirmed the interfacial interactions between ZnO and PPy matrix.

The Synthesis and Characterization of SrTiO3 Film Fabricated by Micro Arcoxidation

2011 ◽  
Vol 311-313 ◽  
pp. 1262-1266 ◽  
Author(s):  
Hui Yong Guo ◽  
Wen Bo Huang ◽  
Wen Fang Li ◽  
Guo Ge Zhang ◽  
En Fu Wang
Keyword(s):  
Surface Morphology ◽  
High Dielectric Constant ◽  
Electrolyte Concentration ◽  
Pure Titanium ◽  
Xrd Analysis ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Dielectric

Pure titanium plates as anode and mixture of solutions containing 0.2M Sr(OH)2and 0.2M NaOH as electrolyte, titanium plates were microarc-oxidated for 10 minutes. X-Ray Diffraction (XRD) analysis indicated that SrTiO3film was successfully deposited. The MAO film is composed mainly of tetragonal SrTiO3phases and found to possess high dielectric constant of 371.0 at the frequency of 1 kHz. Scanning Electron Microscopy (SEM) and portable roughness tester were used to characterize the surface morphology and roughness values(Ra), The influences of electrolyte concentration, current density and frequency on the surface morphology of SrTiO3film were investigated in detail . several rules were drawn from the results. A kinetics expression was established for the growth of film thickness and agreed well with the experimental results.

scholarly journals Synthesis and characterization of poly(p-phenylenediamine): TiO2 nanocomposites and investigation of conducting properties for optoelectronic application

2020 ◽  
Vol 38 (2) ◽  
pp. 296-304
Author(s):  
S. Baruah ◽  
N. Devi ◽  
A. Puzari
Keyword(s):  
Imaging Techniques ◽  
Oxidative Polymerization ◽  
Sol Gel ◽  
Wide Band ◽  
Polymer Nanocomposite ◽  
Synthesis And Characterization ◽  
Wide Band Gap ◽  
Optoelectronic Application ◽  
Sol Gel Process

AbstractPoly(p-phenylenediamine) is a potential precursor for designing of new materials for optoelectronic application. Synthesis and characterization of poly(p-phenylenediamine) – TiO2 nanocomposites has been demonstrated. Structural change observed due to the formation of nanocomposites was correlated with concomitant change in conducting behavior of the parent polymer. Polymer nanocomposite was synthesized through an in-situ oxidative polymerization technique with simultaneous dispersion of TiO2 nanoparticles. TiO2 nanoparticles were synthesized via sol-gel process. Structural characterization was accomplished by using conventional spectroscopic and imaging techniques. I-V measurement of the nanocomposites revealed that the nearly nonconducting poly(p-phenylenediamine) after structural modification exhibits conductivity of 10−6 S/cm leading to formation of wide band gap semiconducting materials.

Synthesis and characterization of poly(2-chloroaniline) by chemical oxidative polymerization

2017 ◽  
Vol 72 (4) ◽  
pp. 1007-1020 ◽  
Author(s):  
Wanar Kongkaew ◽  
Watchara Sangwan ◽  
Walaiporn Prissanaroon-Ouajai ◽  
Anuvat Sirivat
Keyword(s):  
Oxidative Polymerization ◽  
Synthesis And Characterization ◽  
Chemical Oxidative Polymerization

Electrochemical Synthesis and Characterization of Nano Poly(o-anisidine-co-ethyl 4-aminobenzoate)

2013 ◽  
Vol 678 ◽  
pp. 239-243 ◽  
Author(s):  
Raman Sasikumar ◽  
Paramasivam Manisankar
Keyword(s):  
Electrical Conductivity ◽  
Grain Size ◽  
Cyclic Voltammetry ◽  
Surface Morphology ◽  
Sem Analysis ◽  
Synthesis And Characterization ◽  
Carbon Electrode ◽  
Ft Ir ◽  
Xrd Studies

Electroactive copolymer of o-anisidine and ethyl 4-aminobenzoate were synthesized in 1 M HClO4 using cyclic voltammetry on glassy carbon electrode. The copolymer was characterized by FT-IR spectral data. The surface morphology was studied using SEM analysis. The grain size of the copolymer was measured using XRD studies and was found to be 70 nm. The electrical conductivity of the copolymer was 3.14 ×10−3 S cm−1, as determined using a four-probe conductivity meter.

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