scholarly journals Organo-phosphorus flame retardants when applied to acrylonitrile-butadiene-styrene copolymer

2018 ◽  
Vol 1 (6) ◽  
pp. 192-196
Author(s):  
Woojung Kim ◽  
Dong Quy Hoang Thi
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Flame Retardants ◽  
Organophosphorus Compounds ◽  
Acrylonitrile Butadiene Styrene ◽  
Phosphorus Compounds ◽  
P Content ◽  
Halogen Free ◽  
Vertical Test ◽  
Butadiene Styrene

In order to find an effective halogen-free flame retardant for acrylonitrile-butadienestyrene copolymer (ABS), organo-phosphorus compounds were studied and their flame retarding performances were determined by UL 94 vertical test. It is found that the flame retardancy strongly depends on phosphorus (P) content of organophosphorus compounds. Only the mixture of ABS with 2-(6-oxido-6Hdibenz< c,e><1,2>oxaphosphorin-6-yl) methyl diethyl phosphinate (ODOPM-DE), which has the highest P content, i.e., 17.68 % gives V-0 rating for the 70/30 composition.

Surface microencapsulation modification of aluminum hypophosphite and improved flame retardancy and mechanical properties of flame-retardant acrylonitrile–butadiene–styrene composites

RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49143-49152 ◽  
Author(s):  
Ningjing Wu ◽  
Zhaoxia Xiu
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Acrylonitrile Butadiene Styrene ◽  
Aluminum Hypophosphite ◽  
Butadiene Styrene

Silicone-microencapsulated aluminum hypophosphite (SiAHP) improved effectively the flame retardancy and significantly enhanced the notched impact strength of ABS/SiAHP composites.

scholarly journals Thermoplastic polyurethane flame retardant using phosphorus/phosphorus-nitrogen compounds

2019 ◽  
Vol 2 (1) ◽  
pp. 91-95
Author(s):  
Pham Thi Thuy Linh ◽  
Hoang Thi Dong Quy
Keyword(s):  
Flame Retardant ◽  
Flame Retardants ◽  
Thermoplastic Polyurethane ◽  
Nitrogen Compounds ◽  
Fire Performance ◽  
Hydrogen Phosphate ◽  
Char Layer ◽  
Flame Retardant Properties ◽  
Halogen Free ◽  
Vertical Test

In order to improve fire performance of thermoplastic polyurethane (TPU) material, halogen-free flame retardants (triphenylphosphate- TPP and diamonium hydrogen phosphate-DAP) were studied in an attempt to obtain UL-94V ratings. The fire behaviors and thermal stability properties were evaluated using UL-94 vertical test and thermogravimetric analysis (TGA). The UL- 94V results showed that V-0 ratings were achieved at 5 wt% of DAP or 7.5 wt% loading of TPP. The incorporation of these flame retardant (FR) increases the flame retardant properties as well as the amounts of charred residues protecting the mixture from further degradation. This assertion could be accepted when observing that the char residual of TPU/DAP mixture at 500–600oC was much higher than that of neat TPU. The char layer limited the amount of fuel available and insulate the underlying composite material from the flame and, thus, make further degradation more difficult. The mechanism of flame retardants was also discussed in this study.

scholarly journals Recent Developments in the Flame-Retardant System of Epoxy Resin

Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2145 ◽  
Author(s):  
Quanyi Liu ◽  
Donghui Wang ◽  
Zekun Li ◽  
Zhifa Li ◽  
Xiaoliang Peng ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Heat Resistance ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
High Performance ◽  
Flame Retardants ◽  
Great Progress ◽  
Recent Developments ◽  
Halogen Free

With the increasing emphasis on environmental protection, the development of flame retardants for epoxy resin (EP) has tended to be non-toxic, efficient, multifunctional and systematic. Currently reported flame retardants have been capable of providing flame retardancy, heat resistance and thermal stability to EP. However, many aspects still need to be further improved. This paper reviews the development of EPs in halogen-free flame retardants, focusing on phosphorus flame retardants, carbon-based materials, silicon flame retardants, inorganic nanofillers, and metal-containing compounds. These flame retardants can be used on their own or in combination to achieve the desired results. The effects of these flame retardants on the thermal stability and flame retardancy of EPs were discussed. Despite the great progress on flame retardants for EP in recent years, further improvement of EP is needed to obtain numerous eco-friendly high-performance materials.

scholarly journals A bio-based phosphaphenanthrene-containing derivative modified epoxy thermosets with good flame retardancy, high mechanical properties and transparency

RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30943-30954
Author(s):  
Wei Peng ◽  
Yu-xuan Xu ◽  
Shi-bin Nie ◽  
Wei Yang
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Flame Retardants ◽  
The Past ◽  
Phosphorus Containing ◽  
Modified Epoxy

Phosphorus-containing flame retardants have received huge interest for improving the flame retardant behavior of epoxy resins (EP) over the past few decades.

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