scholarly journals Cadmium Compound

2020 ◽  
Author(s):  
Keyword(s):  
2011 ◽  
Vol 50 (6) ◽  
pp. 2052-2054 ◽  
Author(s):  
Dayo Oyetunde ◽  
Mohammad Afzaal ◽  
Mark A. Vincent ◽  
Ian H. Hillier ◽  
Paul O’Brien

2017 ◽  
Vol 62 (7) ◽  
pp. 1017-1021
Author(s):  
Zhong-Liang Yao ◽  
Wen-Tong Chen
Keyword(s):  

2020 ◽  
Vol 50 (11) ◽  
pp. 1130-1136
Author(s):  
Yin-Feng Wang ◽  
Xiu-Guang Yi ◽  
Xiao-Niu Fang ◽  
Jia Li ◽  
Yao Xu ◽  
...  

Wear ◽  
2005 ◽  
Vol 259 (1-6) ◽  
pp. 519-523 ◽  
Author(s):  
Hu Jianqiang ◽  
Zhu Huanqin ◽  
Wang Li ◽  
Wei Xianyong ◽  
Ji Feng ◽  
...  

1988 ◽  
Vol 41 (7) ◽  
pp. 1117 ◽  
Author(s):  
BF Abrahams ◽  
BF Hoskins ◽  
ERT Tiekink ◽  
G Winter

The crystal structures of Ni(S2COCH2CH2OCH3)2 and Cd (S2COCH2CH2OCH3)2 have been determined. Crystals Ni(S2COCH2CH2OCH3)2 are orthorhombic, Pbca , with a 7.852(1), b 7.126(2), c 24.963(4)Ǻ, Z 4. Crystals of Cd (S2COCH2CH2OCH3)2 are monoclinic, P21/c, with a 12.712(2), b 4.215(1), c 13.400(2)Ǻ, β 104.60(1)°, Z 2. In both structures the central metal atom is coordinated by the sulfur atoms in a planar arrangement, an unexpected observation for the cadmium compound.


2007 ◽  
Vol 827 (1-3) ◽  
pp. 20-24 ◽  
Author(s):  
Zilu Chen ◽  
Fupei Liang ◽  
Shengjun Zhou ◽  
Changkun Xia ◽  
Ruixiang Hu

1999 ◽  
Vol 54 (1) ◽  
pp. 117-122 ◽  
Author(s):  
Wilmar Meske ◽  
Dietrich Babel

At single crystals of the cyano complexes Cu2(NH3)8[Mo(CN)8] (a = 934.1(4), b = 1595.9(3), c = 1391.9(4) pm, β = 90.57(2)°, monoclinic space group Cc, Z = 4) and Cd2(NH3)6[Mo(CN)8]·H2O (a = 1708.7(12), b = 1307.8(4), c = 942.9(3) pm, orthorhombic space group Pna21, Z = 4) X-ray structure determinations were performed at temperatures of about 175 K. Both compounds, prepared at about 275 K in aqueous ammonia solutions and easily decomposing, exhibit distorted square antiprismatic [Mo(CN)8]4- coordination of closely resembling dimensions (mean distances Mo-C: 215.7 and 215.3 pm, resp.). The anions are bridged by ammine cations to form chains in the copper and a three-dimensional framework in the cadmium compound. Some of the cyano bridges are strongly bent (C-N-MII as small as 124° and 130°, resp.). The distorted M coordination is square pyramidal and elongated octahedral in the case of the two copper atoms (Cu-N ranging from 197 to 257 pm, three and five ligands, respectively, being NH3). In the case of cadmium both metal atoms are octahedrally coordinated, one exhibiting mer-, the other fac-arrangement of three NH3 and three NC-ligands (Cd-N ranging from 229 to 247 pm, mean 235 pm for either cadmium atom). The findings are compared with related compounds and further details are discussed.


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