Preparation and application of Fe3O4@Acetamidoxanthate as a unique nanosorbent in heavy metal removing

2021 ◽  
pp. 1-11
Author(s):  
Mohammad Moein Mohareri ◽  
Mehdi Ghaffari ◽  
Elham Sattarzadeh ◽  
Saeed Kakaei
Keyword(s):  
Heavy Metals ◽  
Chelating Agents ◽  
High Efficiency ◽  
Fourier Transforms ◽  
Metal Extraction ◽  
Removal Of Heavy Metals ◽  
Ft Ir ◽  
Temperature Time ◽  
Widespread Interest ◽  
Nano Adsorbent

Chelating agents are one of the most important substances in metal extraction, but separation is the main problem in the use of these agents as an adsorbent. After the adsorption of metals by an external magnet, magnetic NPs provide the possibility of easy collecting and isolating the adsorbent nanomaterial for many applications. Given the immense importance of magnetic NPs, there has been widespread interest in accessing the above adsorbent. In the present study, an attempt was made to synthesize acetamido xanthate which was coupled to NPs and has the potential to be used as a nano-adsorbent for the removal of heavy metals. This novel nano sorbent was characterized by scanning electron microscopy (SEM), Fourier transforms infrared (FT-IR), and Nuclear Magnetic Resonance (NMR) spectroscopy. The effect of some parameters such as temperature, time, pH, and the amount of adsorbent on the extraction reaction was investigated. The optimized condition for extraction of cerium was temperature of 30°C, pH = 8, reaction time of 45 minutes using 7.5 mg of the prepared nanosorbent, that in such condition the yield of reaction achieved up to 97%. The prepared adsorbent showed high efficiency in the adsorption of heavy metals specifically.

Application of Immobilized Fungi Phanerochaete chrysosporium in Removal of Heavy-Metals from Wastewater

2013 ◽  
Vol 779-780 ◽  
pp. 1674-1677 ◽  
Author(s):  
Dan Lian Huang ◽  
Guang Ming Zeng ◽  
Piao Xu ◽  
Cui Lai ◽  
Mei Hua Zhao ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Iron Oxide ◽  
Magnetic Nanoparticles ◽  
Phanerochaete Chrysosporium ◽  
High Efficiency ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Removal Of Heavy Metals ◽  
Iron Oxide Magnetic Nanoparticles ◽  
Ca Alginate

Immobilized microbe technologies are expected to be effectively used in wastewater treatment. Removal of heavy-metals from wastewater by immobilized Phanerochaete chrysosporium (Pc) with Ca-alginate and iron oxide magnetic nanoparticles (MNPs) was studied. The results showed that a biosorbent as Pc immobilized by Ca-alginate and iron oxide magnetic nanoparticles was successfully developed. And the iron oxide magnetic nanoparticles played an important role in the increase of biosorption capacity of Pc. Energy dispersive spectrometer (EDS) analysis confirmed that metal ions adsorbed to the surface of the biosorbents were partly transmitted to the interior of biosorbents, mainly embedded with iron oxide nanoparticles and Ca-alginate. Moreover, it was found that MNPs-Ca-alginate immobilized Pc showed a good affinity to various heavy metals, such as Pb(II), Zn(II), Cd(II) or Mg(II) and so on. The results proved the high efficiency of the biosorbents for heavy-metal removal and its potential application in the treatment of metal-containing wastewater.

scholarly journals Effect of Soil Washing Solutions on Simultaneous Removal of Heavy Metals and Arsenic from Contaminated Soil

2020 ◽  
Vol 17 (9) ◽  
pp. 3133 ◽  
Author(s):  
Kanghee Cho ◽  
Eunji Myung ◽  
Hyunsoo Kim ◽  
Cheonyoung Park ◽  
Nagchoul Choi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sulfuric Acid ◽  
Phosphoric Acid ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Soil Washing ◽  
Metal Extraction ◽  
Simultaneous Removal ◽  
Removal Of Heavy Metals ◽  
Removal Efficiencies

In this study, we investigated the feasibility of using a solution of sulfuric acid and phosphoric acid as an extraction method for soil-washing to remove Cu, Pb, Zn, and As from contaminated soil. We treated various soil particles, including seven fraction sizes, using sulfuric acid. In addition, to improve Cu, Pb, Zn, and As removal efficiencies, washing agents were compared through batch experiments. The results showed that each agent behaved differently when reacting with heavy metals (Cu, Pb, and Zn) and As. Sulfuric acid was more effective in extracting heavy metals than in extracting As. However, phosphoric acid was not effective in extracting heavy metals. Compared with each inorganic acid, As removal from soil by washing agents increased in the order of sulfuric acid (35.81%) < phosphoric acid (62.96%). Therefore, an enhanced mixture solution using sulfuric acid and phosphoric acid to simultaneously remove heavy metals and As from contaminated soils was investigated. Sulfuric acid at 0.6 M was adopted to combine with 0.6 M phosphoric acid to obtain the mixture solution (1:1) that was used to determine the effect for the simultaneous removal of both heavy metals and As from the contaminated soil. The removal efficiencies of As, Cu, Pb, and Zn were 70.5%, 79.6%, 80.1%, and 71.2%, respectively. The combination of sulfuric acid with phosphoric acid increased the overall As and heavy metal extraction efficiencies from the contaminated soil samples. With the combined effect of dissolving oxides and ion exchange under combined washings, the removal efficiencies of heavy metals and As were higher than those of single washings.

Use of citric acid for heavy metals extraction from contaminated sewage sludge for land application

2006 ◽  
Vol 54 (9) ◽  
pp. 129-135 ◽  
Author(s):  
D. del Mundo Dacera ◽  
S. Babel
Keyword(s):  
Heavy Metals ◽  
Citric Acid ◽  
Land Application ◽  
Metal Extraction ◽  
Lead Removal ◽  
Inorganic Matter ◽  
Highly Effective ◽  
Removal Of Heavy Metals ◽  
Anaerobically Digested Sludge ◽  
Extracting Agents

Recent studies revealed that organic acids such as citric and oxalic acids seemed to be more promising as chemical extracting agents for removal of heavy metals from contaminated sludge, since they are biodegradable and can attain a higher metal extraction efficiency at mildly acidic pH compared to other extracting agents. Results of a lab-scale study on the efficiency of citric acid in the extraction of chromium (Cr), copper (Cu), lead (Pb), nickel (Ni) and zinc (Zn) from anaerobically digested sludge, revealed that citric acid seemed to be highly effective in extracting Cr (at 100%), Cu (at 88%), Ni (at 98%) and Zn (at 100%) at pH 2.33, mostly at 5 days leaching time except for Cu and Zn, which are at 1 day and 2 h contact times respectively. Lead removal at the same pH was also high at 95% but at a longer leaching time of 11 days. At pH 3, citric acid seemed to be highly effective in extracting Pb (at 100%) at 1 day leaching time, although higher removals were also attained for Ni (70%) and Zn (80%) at only 2 h leaching time. Chemical speciation studies showed that Cr, Cu and Ni in the sludge sample seem to predominate in residual fractions, while Pb and Zn were found mostly bound to organic and inorganic matter forms, hence the potential of the sludge for land application.

scholarly journals Chemical and Biological Leaching Methods to Remove Heavy Metals from Sewage Sludge: A Review

2008 ◽  
Vol 4 (3) ◽  
pp. 509-517
Author(s):  
Lugard N. Ukiwe ◽  
Allinor J.I ◽  
Ejele A.E ◽  
Anyadiegwu C.I.C ◽  
Ibeneme S.I
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Thiobacillus Ferrooxidans ◽  
Extraction Procedure ◽  
Metal Extraction ◽  
High Yield ◽  
Chemical Leaching ◽  
Solids Concentration ◽  
Acid Consumption ◽  
Removal Of Heavy Metals

The removal of heavy metals (HMs) in sewage sludge (SS) is important since sludge is often disposed or applied on farmland to enhance soil fertility. The present study reviewed two conceptual approaches (chemical and biological leaching) of removing HMs present in SS. In the chemical leaching method, traditional acid treatment together with novel methods such as aeration, complexation and sequential extraction procedure have been reviewed extensively. Certain factors influence the removal of HMs in SS. These factors include; pH, leaching agent, redox potential, and contact time. Nitric acid (HNO3), hydrochloric acid (HCl), sulphuric acid (H2SO4), phosphoric acid (H3PO4), ethylenediamine tetraacetic acid (EDTA), as well as Thiobacillus thiooxidans and Thiobacillus ferrooxidans are the most widely studied leaching agents and substrates involved in the chemical and bioleaching processes. However, the bioleaching process has been proposed as a safe, efficient, economical, environmental friendly method to remove HMs in SS due to its simplicity, high yield of metal extraction, low acid consumption, and low sludge solids concentration. Nevertheless, the present review has noted that most researchers are of the opinion that more studies are needed in the bioleaching method in order to enhance its commercial attraction.  

scholarly journals Acid Treatment Halloysite Nanoclay: Eco-Friendly Heterogeneous Catalyst for the Synthesis of Pyrrole Derivatives

Proceedings ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 17
Author(s):  
Ali Maleki ◽  
Zoleikha Hajizadeh
Keyword(s):  
Infrared Spectroscopy ◽  
Acid Treatment ◽  
High Efficiency ◽  
Fourier Transforms ◽  
Halloysite Nanotubes ◽  
Hydroxyl Groups ◽  
Simple Method ◽  
Pyrrole Derivatives ◽  
Ft Ir ◽  
Fourier Transforms Infrared Spectroscopy

In this study, halloysite nanotubes (HNTs) as a green and available nano-mineral were used. The hydroxyl groups of HNTs were increased by acid treatment. So, the efficiency of HNTs was improved. The catalyst application of acid treatment HNTs was investigated in the synthesis of pyrrole as an important heterocycle compound. The catalyst was characterized by Fourier transforms infrared spectroscopy (FT-IR). Easy and simple method, high efficiency and eco-friendly are the advantages of this report.

Removal of Heavy Metals by Using Chitosan/ Poly (Acryl Amide-Acrylic Acid) Hydrogels: Characterization and Kinetic Study

2021 ◽  
Vol 19 (2) ◽  
pp. 31-37
Author(s):  
Layth S. Jasim ◽  
Aseel M. Aljeboree
Keyword(s):  
Heavy Metals ◽  
Aqueous Solution ◽  
Reaction Order ◽  
Time Intervals ◽  
Freundlich Isotherms ◽  
Removal Of Heavy Metals ◽  
Ft Ir ◽  
Structural Surface ◽  
Kinetics Of ◽  
Kinetics Of Sorption

In this Study, hydrogel P(CH/AA-co-AM) was prepared, identification and utilized as an efficient absorbent to eliminate Cr (III) and Cd (II) ions from the aqueous solution. The adsorption of these ions follows Freundlich isotherms. Due to greater activity surface of the hydrogel in adsorption of the contaminants, they can be utilized for elimination of the mentioned ions from water. Therefore, we characterized structural, surface and thermal properties of the prepared materials with technique: TGA, FE-SEM and FT-IR. Moreover, we implemented the kinetics of sorption with regard to the amounts of the metal sorbet at distinct time intervals and thus examined the modeling of the isotherm and kinetic curves. Finally, we computed the reaction order as well as rate constant.

Enhanced Electrokinetic Removal of Heavy Metals in MSWI Fly Ash Assisted by Cation Exchange Membranes

2011 ◽  
Vol 84-85 ◽  
pp. 626-630 ◽  
Author(s):  
Xi Peng ◽  
Bin Quan Jiao ◽  
Lin Yu ◽  
Dong Wei Li ◽  
Ke Yang
Keyword(s):  
Heavy Metals ◽  
Fly Ash ◽  
Cation Exchange ◽  
Electroosmotic Flow ◽  
Metal Extraction ◽  
Mswi Fly Ash ◽  
Assisted Extraction ◽  
Removal Of Heavy Metals ◽  
Trial Test ◽  
Exchange Membrane

Since MSWI fly ash enriches heavy metals and many toxic components and these components would potentially leach when the ashes are land filled, it is regulated as hazardous waste in many countries. Electrokinetic removal, an electrochemically assisted extraction method, has recently been adopted as a new method for removal of heavy metals from MSWI fly ashes. But the generation of metal hydroxide precipitation near the cathode decreased conductivity of electrokinetic removal system and limited metal extraction from the sample area. In this study, cation exchange membrane was used in electrokinetic removal experiment to improve this method. After 192 hours of electrokinetic removal, about 15%Cd,20%Pb, 30% Zn, and 10% As was removed from 2.850kg MSWI fly ash. It showed positive effect compared to the trial test. But there still exists some problems, such as low removal efficiency. Further work should be done to solve it.Moreover, the high conductivity in fly ash limits the current , which in turn causes low electroosmotic flow. While electroosmotic flow is the main factor leting the heavy meatals release from fly ash, it would become the focus in further experiment to look for ways increasing the electroosmotic flow in sample cell.

scholarly journals Use of Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans in the Recovery of Heavy Metals from Landfill Leachates

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3336
Author(s):  
Tomasz Kamizela ◽  
Anna Grobelak ◽  
Malgorzata Worwag
Keyword(s):  
Heavy Metals ◽  
Mixed Culture ◽  
Reverse Osmosis ◽  
Landfill Leachate ◽  
Acidithiobacillus Ferrooxidans ◽  
High Efficiency ◽  
Metal Removal ◽  
Acidithiobacillus Thiooxidans ◽  
Landfill Leachates ◽  
Removal Of Heavy Metals

Among the methods used to remove metals and their compounds from landfill leachates with low application costs and high efficiency are bioleaching and biosorption. The most effective bacteria used in the metal removal process are Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans. The aim of the study was to determine the usefulness of the A. ferrooxidans and A. thiooxidans population in removing heavy metals from landfill leachate. In addition, development opportunities for bacterial population using landfill leachate as growth medium were identified. The substrate for the research was the raw leachate before the reverse osmosis process. In order to increase the efficiency of trace elements removal and recovery from leachate, variable combinations have been used which differ by the addition of sulfuric acid, A. ferrooxidans culture, A. thiooxidans culture, mixed culture containing populations of both bacteria, and elemental sulfur. Based on the research, it was found that the removal of heavy metals from leachate was a selective process. High bioleaching efficiency, from 80% to 90%, was obtained for all metals for which the sample acidification or sulfur addition was used. The simultaneous combination of both these additives turned out to be the most advantageous. The A. thiooxidans culture was the most effective in bioleaching reverse osmosis effluents. For the A. ferrooxidans culture used, much lower efficiencies were obtained, while by contrast, the use of mixed culture of two bacterium species had no significant effect.

Sign in / Sign up

Export Citation Format

Share Document