Geochemical, Topographical, and Meteorological Controls on Groundwater Arsenic Contamination in Sharda River Basin of Uttar Pradesh, India

2020 ◽  
Vol 6 (2) ◽  
pp. 71-87
Author(s):  
Sonal Bindal ◽  
Anand Kumar ◽  
Javed Mallick ◽  
Satyanarayan Shashtri ◽  
Pankaj Kumar ◽  
...  

Groundwater arsenic (As) contamination is a health threat for millions of people in the Gangetic plains of India. It is, therefore, critical to understand the mechanism of As enrichment to reduce the As exposure. Geochemical analysis of 30 groundwater samples collected across the banks of River Sharda was performed for the identification of major geochemical processes controlling groundwater geochemistry. Shallow wells (3-10 m) are found to be contaminated with As and is confined to newer alluvium of Holocene age. The average temporal decline of the groundwater level was observed across 10 monitoring stations is 0.067 m/yr. Decreasing rainfall, lesser recharge and huge groundwater extraction for irrigation might have impacted the groundwater to flow faster, while the increase in temperature and weathering regime favoured arsenic mobilisation. The long-term trends of rainfall show a decline of 1.97 mm/yr and the temperature increase is observed to be 0.0049°C/yr. These changes in rainfall and temperature also might have impacted the As mobilisation in groundwater. NO3- was found to be low in samples with low As concentrations, indicating the prevalence of reducing conditions. Whereas high concentrations of Fe were observed for high As samples, indicating their common source of origin. Also, the alkaline nature of aquifer and high concentrations of HCO3- might have contributed to As enrichment. Results from scatter plots and correlation matrix also support this sequential reduction leading to the reductive dissolution of iron oxyhydroxides and thus enriching the concentration of As in the groundwater.

2004 ◽  
Vol 36 (4) ◽  
pp. 2002
Author(s):  
N. Λαμπράκης ◽  
Soren Jessen ◽  
Γ. Παναγόπουλος ◽  
E. Πυτικάκης

The lower Pinios basin at the eastern coast of the Peloponnesus, hosts a system of alternative aquifers in the Pleistocene sediments of "Kalatha" formation. The elaboration of chemical analyses of the principal and trace elements of groundwater samples shown that a Redox environments and the presence of deep thermal water affect the groundwater quality. The aquifers sectors with reducing conditions are characterized by high concentrations of alkalinity, ammonia, total iron and total manganese groundwater. In the aquifers sectors with oxidizing conditions the values of the above parameters are low and the dominance of the chemical elements oxidizing forms are obvious.


1996 ◽  
Vol 31 (3) ◽  
pp. 485-504 ◽  
Author(s):  
Patricia Chow-Fraser ◽  
Barb Crosbie ◽  
Douglas Bryant ◽  
Brian McCarry

Abstract During the summer of 1994, we compared the physical and nutrient characteristics of the three main tributaries of Cootes Paradise: Spencer, Chedoke and Borer’s creeks. On all sampling occasions, concentrations of CHL α and nutrients were always lowest in Borer’s Creek and highest in Chedoke Creek. There were generally 10-fold higher CHL α concentrations and 2 to 10 times higher levels of nitrogen and phosphorus in Chedoke Creek compared with Spencer Creek. Despite this, the light environment did not differ significantly between Spencer and Chedoke creeks because the low algal biomass in Spencer Creek was balanced by a relatively high loading of inorganic sediments from the watershed. Laboratory experiments indicated that sediments from Chedoke Creek released up to 10 µg/g of soluble phosphorus per gram (dry weight) of sediment, compared with only 2 µg/g from Spencer Creek. By contrast, sediment samples from Spencer Creek contained levels of polycyclic aromatic hydrocarbon that were as high as or higher than those from Chedoke Creek, and much higher than those found in Borer’s Creek. The distribution of normalized PAH concentrations suggests a common source of PAHs in all three tributaries, most likely automobile exhaust, since there were high concentrations of fluoranthene and pyrene, both of which are derivatives of engine combustion.


1998 ◽  
Vol 37 (6-7) ◽  
pp. 87-93 ◽  
Author(s):  
M. Kussmaul ◽  
A. Groengroeft ◽  
H. Koethe

In the year 1993 a confined and unused harbour basin was used to store 290,000 m3 of fine-grained dredged material from Hamburg harbour. About 70% of the deposit surface was water covered. The edge areas were above the water table and covered with reed. Emissions of dissolved compounds into the groundwater, as well as surface gas emissions were measured from 1994 to 1996. As indicators for water fluxes from the deposit we used NH4+ and HCO3− because of their high concentrations in mud porewater in comparison to groundwater. The average concentrations of NH4+ and HCO3− in the porewater increased during 2 years from 85 to 250 mg NH4+ 1−1 and from 2.0 to 3.1 g HCO3− 1−1, while the groundwater samples showed constant values of 8 mg NH4+ 1−1 and 0.7 g HCO3− 1−1. Furthermore, the average gas emissions over the water surface were 3.2 g CH4 m−2 d−1 and 0.8 g CO2 m−2 d−1. In contrast, no methane and 3.0 g CO2 m−2 d−1 were emitted from land areas. The results indicated, that there were no significant emissions of mud porewater compounds into the groundwater but high CH4-emissions over the water covered surface of the mud deposit.


Author(s):  
Neha Thakur ◽  
Nahid Zia Khan ◽  
Narendra Rai

Background: Barabanki one of the most populous districts of Uttar Pradesh with population growth rate being much higher than the national population growth rate. The objective of this study was to gain the knowledge about awareness and contraceptive practices in married women residing in Barabanki. To identify socio-demographic factors associated with unmet needs for contraceptionand also to ascertain the participation of husband in family planning.Methods: A cross sectional study was conducted in outpatient department of Obstetrics Gynecology and Department of Pediatrics in Medical college hospital in Barabanki. 144 females were enrolled in the study during the study period of one year. They were interviewed on the basis of a pre-structured proforma. Data obtained was then analyzed.Results: A total 144 women in the age group 18-45 years participated in the study of which 53% had knowledge of contraception. More than two thirds were not using any form of contraception. The most common method of contraception was barrier method followed by Depot medroxy progesterone acetate. Copper T was least used mode of contraception. The most common source of knowledge regarding contraception was from electronic media followed by friends and family. The most common reason behind the absence of contraception was lack of knowledge of contraception and husband disapproval.Conclusions: Poor knowledge of contraception led to decreased usage of contraceptive measures. Husband participation is virtually absent in family planning leading to high fertility. In order to make our family planning programs successful we must incorporate media for wider coverage to increase awareness and husbands for better implementation.


2015 ◽  
Vol 17 (1) ◽  
pp. 162-174 ◽  

<div> <p>This paper presents an assessment of the impact of uncontrolled and unscientific disposal of MSW on ground water in Dhanbad city, India. In this study, ground water quality around municipal solid waste disposal sites was investigated. Ground water quality analysis was carried out on samples collected at various distances from two disposal sites. The study has revealed that the ground water quality near dumping sites does not conform to the drinking water quality standards as per IS:10500. The impacts of indiscriminate dumping activity on ground water appeared most clearly as high concentrations of total dissolved solids, electrical conductivity, chlorides, chemical oxygen demand, and sulphates. High amount of metals like Na, K, Ca, Mg, Cd, Cu, Ni, Fe, Zn and Mn has also been detected in the groundwater samples near dumping area. Leachate characterization study also reveals high potential for groundwater contamination. Presence of feacal coliform contamination in groundwater samples indicates potential health risk for individuals exposed to this water.&nbsp;</p> </div> <p>&nbsp;</p>


2021 ◽  
Author(s):  
juyeon Lee ◽  
minjune Yang

&lt;p&gt;This study conducted a rhizofiltration experiment for uranium-removal with the edible plants (&lt;em&gt;Lactuca sativa, Brassica campestris &lt;/em&gt;L., &lt;em&gt;Raphanus sativus &lt;/em&gt;L., and &lt;em&gt;Oenanthe javanica&lt;/em&gt;) which generally consumed in South Korea. Various batch experiments were performed with different initial uranium concentrations, pH conditions, and genuine groundwater. The results showed the uranium accumulation and bioconcentration factor (BCF) of plant roots increase with an increase in initial uranium concentrations in the solution. Of the four plants, the amount of uranium accumulated in &lt;em&gt;Raphanus sativus &lt;/em&gt;L. roots was 1215.8 &amp;#956;g/g DW with the maximum BCF value of 2692.7. The BCF value based on various pH conditions (pHs 3, 5, 7 and 9) of artificial solutions was highest at pH 3 for all four plants, and the BCF value of &lt;em&gt;Brassica campestris &lt;/em&gt;L. was the maximum of 11580.3 at pH 3. As a result of rhizofiltration experiments with genuine groundwater contaminated with uranium, the BCF values of &lt;em&gt;Raphanus sativus &lt;/em&gt;L. were 1684.7 and 1700.1, the highest among the four species, in Oesam-dong and Bugokdong groundwater samples with uranium concentration of 83 and 173 &amp;#956;g/L. From SEM/EDS analysis, it was confirmed that uranium in contaminated groundwater was adsorbed as a solid phase on the root surface. These results demonstrate that &lt;em&gt;Raphanus sativus &lt;/em&gt;L. not only has a high tolerance to high concentrations of uranium and low pH conditions but also has a remarkable potential for uranium accumulation capacity.&lt;/p&gt;


2013 ◽  
Vol 6 (3) ◽  
pp. 213-222 ◽  
Author(s):  
G. Schatzmayr ◽  
E. Streit

Mycotoxins are ubiquitously present in agricultural commodities, such as cereals and oil seeds. If ingested in sufficiently high concentrations, they exert severe toxic effects in humans and animals. In 2004, a survey programme was launched to assess the extent of mycotoxin contamination in feed and feed raw materials. Since then, over 19,000 samples have been analysed and more than 70,000 individual analyses have been conducted. While it is difficult to infer any long-term trends on a global level, the data confirm that high mycotoxin contamination is often linked to unusual weather. Overall, 72% of the samples contained detectable amounts of aflatoxins, fumonisins, deoxynivalenol, zearalenone or ochratoxin A. Co-contamination with two or more mycotoxins was detected in 38% of the samples. In most cases the concentrations were low enough to ensure compliance with EU guidance values or maximum levels. However, co-contaminated samples with concentrations below guidance and maximum values might still exert adverse effects due to synergistic interactions of the mycotoxins. Emerging mycotoxins and masked mycotoxins may also contribute to the overall toxicity of the feed and their presence is frequently detected with multi-mycotoxin LC-MS/MS. Since by-product feeds, such as distillers dried grain with solubles, often concentrate the mycotoxins of the original substrate, they contribute excessively to the overall contamination of feed rations and therefore need special attention. Regarding food the situation is quite similar: low level contamination is frequently observed in official controls but maximum levels are rarely exceeded in developed countries. As it is very difficult to remove mycotoxins from contaminated commodities, preventing them from accumulation in agricultural commodities is the most effective strategy to combat the problem. Preventive measures range from crop rotation and resistance breeding to inoculation with microbial antagonists. Nevertheless, excessive mycotoxin levels may occur despite all preventive measures. Therefore, continuous monitoring is essential and efficient detoxification strategies are needed to deal with such outbreaks.


1988 ◽  
Vol 117 (4) ◽  
pp. 428-434 ◽  
Author(s):  
Karin E. Bornfeldt ◽  
Hans J. Arnqvist ◽  
Hans H. Dahlkvist ◽  
Anna Skottner ◽  
Jarl E. S. Wikberg

Abstract. Binding of IGF-I to plasma membranes from bovine mesenteric arteries was studied. The maximal specific binding of IGF-I was found to be 7.4 ± 1.7% of total 125I-IGF-I added to the incubation medium. Unlabelled IGF-I displaced 125I-IGF-I with an IC50 value of 0.5 nmol/l and a maximal displacement of 64.2 ± 2.8% of total binding. The potency of insulin to displace 125I-IGF-I was 100–1000-fold lower. Crosslinking of 125I-IGF-I to the receptor with disuccinimidyl suberate, followed by SDS-polyacrylamide gel electrophoresis under reducing conditions showed an IGF-I binding protein with a molecular weight of 146000 Dalton. In summary, we have shown the presence of receptors for IGF-I in plasma membranes isolated from macrovessels. The binding characteristics and the size of the binding unit were found to be similar to those of the IGF-1 receptor found in cultured vascular smooth muscle cells. Furthermore, insulin at high concentrations was found to interact with the IGF-I receptor.


Geologos ◽  
2016 ◽  
Vol 22 (2) ◽  
pp. 137-147
Author(s):  
Tomasz Kotowski ◽  
Stefan Satora

AbstractWe present the results of isotope measurements (δ18O, δ D, δ13CDICand14C) and chemical analyses (TDS, TOC, HCO3-, SO42-, Cl-, NO3-, NH4+, Ca2+, Mg2+Na+and K+) conducted on groundwater samples collected from deep Cenozoic aquifers. These aquifers are the basic source of drinking water at numerous localities within the study area in northern Poland. Most of the δ18O determinations are characterised by low variability (i.e., > 70 per cent of δ18O are between -9.5‰ and -9.2‰). In most cases tritium activity was not detected or its content slightly exceeded the uncertainty of measurement (from ±0.3 T.U. to ± 0.5 T.U.). On average, 14C activity is twice higher than that under similar conditions and in hydrogeological systems. The δ13CDICvalues fall within the -13.6‰ to -12.8‰ range. A slight variability is observed when considering all isotope and chemical data within the study area and under these hydrogeological conditions. In general, the results of isotope and chemical analyses seem to be homogeneous, indicating the presence of closely similar groundwaters in the system, irrespective of geological formation. It is likely that there is a significant hydraulic connection between shallow and deep aquifers in the Gwda catchment, which indicates the potential for seepage of pollutants from shallow Pleistocene to deep Miocene aquifers. This can endanger the latter by e.g., high concentrations of NO3-, SO42-and Cl-ions from shallow aquifers within the Gwda catchment.


2009 ◽  
Vol 59 (5) ◽  
pp. 1043-1051 ◽  
Author(s):  
X. W. Wang ◽  
N. N. Zhong ◽  
D. M. Hu ◽  
Z. Z. Liu ◽  
Z. H. Zhang

The concentrations of polycyclic aromatic hydrocarbons (PAHs) in the leachate from the gangue and 20 groundwater samples, which were collected from the 12th Coal Mine around gangue piles in Henan Province, China, were determined by SPE-GC-MS. The characteristics of PAHs pollutants in groundwater were investigated, and compared with the concentrations of PAHs in the leachate from different weathered gangues to discuss the pollution effects of PAHs from coal gangue on groundwater. The results showed that total concentrations of the 16 EPA preferentially controlled PAHs ranged from 146.9 ng/L to 1220.6 ng/L.The components of PAHs such as chrysene, benzo[a]anthracene, benzo[b + k]fluoranthene, indeno[1,2,3-c,d]–pyrene, and dibenz[a,h]anthracene were fairly high. The 2–4 rings PAHs such as naphthalene, phenanthrene, fluorene and chrysene were dominant in groundwater, which was similar to those of the leachate from the different weathered gangues. Therefore, it should be paid much more attention on the transport of lower ring numbered PAHs leached by rains from the coal mines after landfilling and dumping. Based on the spatial distribution of PAHs and the high concentrations of PAHs with 2–4 rings in groundwater and leaching samples, there might be other pollution sources of PAHs except for penetration from coal gangue into groundwater in the Pingdingshan coal mine area.


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