scholarly journals Solution viscosity – molar mass relationships for poly(butylene succinate) and discussion on molar mass analysis

2015 ◽  
Vol 9 (5) ◽  
pp. 424-434 ◽  
Author(s):  
Q. Charlier ◽  
E. Girard ◽  
F. Freyermouth ◽  
M. Vandesteene ◽  
N. Jacquel ◽  
...  
2014 ◽  
Vol 131 (16) ◽  
pp. n/a-n/a ◽  
Author(s):  
Matthieu Garin ◽  
Lan Tighzert ◽  
Isabelle Vroman ◽  
Sinisa Marinkovic ◽  
Boris Estrine

2004 ◽  
Vol 69 (12) ◽  
pp. 1013-1028 ◽  
Author(s):  
Danijela Jovanovic ◽  
Marija Nikolic ◽  
Jasna Djonlagic

segmented poly(ester-ether)s based on poly(butylene succinate) and two different types of polyethers were investigated. The poly(ester-ether)s were synthesized by transesterification reaction of dimethyl succinate 1,4-butanediol and poly(ethylene oxide) (PEO, Mn = 1000 g/mol) in the first series, and poly(tetramethylene oxide) (PTMO,Mn = 1000 g/mol) in the second. The mass fraction of soft segments was varied between 10 and 50 mass. %. The effect of the introduction of two different polyether soft segments on the structure, thermal and rheological properties were investigated. The composition of the poly(ester-ether)s, determined from their 1H-NMR spectra showed that incorporation of soft polyether segments was successfully performed by the transesterification reaction in bulk. The molecular weight was estimated from solution viscosity measurements and complex dynamic viscosities. The thermal properties investigated by DSC indicated that the presence of soft segments lowers the melting and crystallization temperature of the hard phase, as well as the degree of crystallinity. Dynamical mechanical analysis was used to investigate the influence of composition on the rheological behavior of the segmented poly(ester-ether)s. The results obtained from an enzymatic degradation test performed on some of the synthesized polymers showed that the biodegradability is enhanced with increasing hydrophilicity.


2018 ◽  
Vol 9 (9) ◽  
pp. 1116-1131 ◽  
Author(s):  
P. S. Eselem Bungu ◽  
H. Pasch

The multiple preparative fractionation concept provides sample libraries with different degrees of branching and different molar masses that are analyzed regarding the LDPE microstructure.


2012 ◽  
Vol 48 (12) ◽  
pp. 1965-1975 ◽  
Author(s):  
Nikoleta Stoyanova ◽  
Rosica Mincheva ◽  
Dilyana Paneva ◽  
Nevena Manolova ◽  
Philippe Dubois ◽  
...  

2014 ◽  
Vol 216 (1) ◽  
pp. 95-105 ◽  
Author(s):  
Barbara Maret ◽  
Agnès Crépet ◽  
Clément Faye ◽  
Laurent Garrelly ◽  
Catherine Ladavière

Polymer ◽  
2008 ◽  
Vol 49 (21) ◽  
pp. 4502-4509 ◽  
Author(s):  
Sandra Laun ◽  
Harald Pasch ◽  
Nicolas Longiéras ◽  
Christophe Degoulet

2003 ◽  
Vol 52 (9) ◽  
pp. 1519-1526 ◽  
Author(s):  
Renjith Devasia ◽  
CP Reghunadhan Nair ◽  
KN Ninan

2014 ◽  
Vol 131 (20) ◽  
pp. n/a-n/a ◽  
Author(s):  
Matthieu Garin ◽  
Lan Tighzert ◽  
Isabelle Vroman ◽  
Sinisa Marinkovic ◽  
Boris Estrine

2017 ◽  
Vol 178 ◽  
pp. 302-310 ◽  
Author(s):  
Stephan Silbermann ◽  
Christian Weilach ◽  
Gerhard Kliba ◽  
Karin Fackler ◽  
Antje Potthast

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