scholarly journals Influence of carbon nanotube clustering on the electrical conductivity of polymer composite films

2010 ◽  
Vol 4 (5) ◽  
pp. 292-299 ◽  
Author(s):  
J. O. Aguilar ◽  
J. R. Bautista-Quijano ◽  
F. Aviles
Keyword(s):  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Polymer Composite ◽  
Composite Films

The Effect of Nanotube Loading and Dispersion on the Three-Dimensional Nanostructure of Carbon Nanotube-Conducting Polymer Composite Films

2002 ◽  
Vol 739 ◽  
Author(s):  
Mark Hughes ◽  
George Z. Chen ◽  
Milo S. P. Shaffer ◽  
Derek J. Fray ◽  
Alan H. Windle
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Conducting Polymer ◽  
Polymer Composite ◽  
Electrochemical Polymerization ◽  
Composite Films ◽  
Three Dimensional ◽  
Ionic Diffusion ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

ABSTRACTNanoporous composite films of multi-walled carbon nanotubes (MWNTs) and either polypyrrole (PPy) or poly(3-methylthiophene) (P3MeT) were grown using an electrochemical polymerization technique in which the nanotubes and conducting polymer were deposited simultaneously. The concentration and dispersion of MWNTs in the polymerization electrolyte was found to have a significant effect on the thickness of polymer coated on each MWNT and hence the loading of MWNTs in the films produced. It has been shown that for an increasing concentration of MWNTs in the polymerization electrolyte, the thickness of polymer coated on each MWNT decreases. This relationship made it possible to minimize ionic diffusion distances within the nanoporous MWNT-PPy films produced, reducing their electrical and ionic resistance and increasing their capacitance relative to similarly prepared pure PPy films.

scholarly journals Polymer-Single Wall Carbon Nanotube Composites for Potential Spacecraft Applications

2001 ◽  
Vol 706 ◽  
Author(s):  
Cheol Park ◽  
Zoubeida Ounaies ◽  
Kent A. Watson ◽  
Kristin Pawlowski ◽  
Sharon E. Lowther ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Composite Films ◽  
Polymeric Materials ◽  
Polymer Nanocomposite ◽  
Weight Percent ◽  
Nanocomposite Films ◽  
Mechanical And Thermal Properties ◽  
Single Wall Carbon Nanotube ◽  
Single Wall Carbon

AbstractPolymer-single wall carbon nanotube (SWNT) composite films were prepared and characterized as part of an effort to develop polymeric materials with improved combinations of properties for potential use on future spacecraft. Next generation spacecraft will require ultra-lightweight materials that possess specific and unique combinations of properties such as radiation and atomic oxygen resistance, low solar absorptivity, high thermal emissitivity, electrical conductivity, tear resistance, ability to be folded and seamed, and good mechanical properties. The objective of this work is to incorporate sufficient electrical conductivity into space durable polyimides to mitigate static charge build-up. The challenge is to obtain this level of conductivity (10-8 S/cm) without degrading other properties of importance, particularly optical transparency. Several different approaches were attempted to fully disperse the SWNTs into the polymer matrix. These included high shear mixing, sonication, and synthesizing the polymers in the presence of pre-dispersed SWNTs. Acceptable levels of conductivity were obtained at loading levels less than one tenth weight percent SWNT without significantly sacrificing optical properties. Characterization of the nanocomposite films and the effect of SWNT concentration and dispersion on the conductivity, solar absorptivity, thermal emissivity, mechanical and thermal properties were discussed. Fibers and non-woven porous mats of SWNT reinforced polymer nanocomposite were produced using electrospinning.

scholarly journals Ultrafast laser orthogonal alignment and patterning of carbon nanotube-polymer composite films

2012 ◽  
Vol 101 (20) ◽  
pp. 203301 ◽  
Author(s):  
Ryan D. Murphy ◽  
Michael J. Abere ◽  
Huanan Zhang ◽  
Haiping Sun ◽  
Ben Torralva ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Polymer Composite ◽  
Composite Films ◽  
Ultrafast Laser

The Effect of Aggregation on the Electrical Conductivity of Spin-Coated Polymer/Carbon Nanotube Composite Films

Langmuir ◽  
2007 ◽  
Vol 23 (10) ◽  
pp. 5707-5712 ◽  
Author(s):  
Ronald H. Schmidt ◽  
Ian A. Kinloch ◽  
Andrew N. Burgess ◽  
Alan H. Windle
Keyword(s):  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Composite Films ◽  
Carbon Nanotube Composite

Physical Properties of Thin PVDF/MWNT (Multi-Walled Carbon Nanotube) Composite Films by Melt Blending

2008 ◽  
Vol 8 (9) ◽  
pp. 4860-4863 ◽  
Author(s):  
Soon Man Hong ◽  
Seung Sang Hwang
Keyword(s):  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Physical Properties ◽  
Vinylidene Fluoride ◽  
Composite Films ◽  
Nucleating Agent ◽  
Multi Walled Carbon Nanotube ◽  
Poly Vinylidene Fluoride ◽  
Carbon Nanotube Composite ◽  
Internal Mixer

Poly(vinylidene fluoride)(PVDF)/Multi-walled carbon nanotube (MWNT) composites were melt blended using internal mixer. The relationships between structures and physical properties of thin PVDF/MWNT composite films were studied. With increasing the content of MWNT, the size of spherulites in PVDF decreased. MWNT was used as a nucleating agent. The incorporation of MWNT produced a polar β-form crystal structure of PVDF. The permittivities of thin PVDF/MWNT composite films were increased with increasing the MWNT content. The percolation level in electrical conductivity occurred between 2 and 2.5 wt%. The critical conductivity saturation point for the electrical conductivity in PVDF was confirmed. Similar tendency was also observed in thermal conductivity.

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