scholarly journals Automated determination of the stable carbon isotopic composition (δ13C) of total dissolved inorganic carbon (DIC) and total nonpurgeable dissolved organic carbon (DOC) in aqueous samples: RSIL lab codes 1851 and 1852

2014 ◽  
Author(s):  
Kinga M. Révész ◽  
Daniel H. Doctor
Keyword(s):  
Organic Carbon ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Carbon Isotopic Composition ◽  
Stable Carbon ◽  
Aqueous Samples ◽  
Carbon Isotopic ◽  
Total Dissolved Inorganic Carbon ◽  
Automated Determination

scholarly journals Stable Carbon Isotopes of Phytoplankton as a Tool to Monitor Anthropogenic CO2 Submarine Leakages

Water ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3573
Author(s):  
Federica Relitti ◽  
Nives Ogrinc ◽  
Michele Giani ◽  
Federica Cerino ◽  
Mirta Smodlaka Smodlaka Tankovic ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Stable Carbon Isotopes ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Carbon Isotopic Composition ◽  
Stable Carbon ◽  
Carbonate System ◽  
Δ13c Values ◽  
Carbon Isotopic ◽  
Anthropogenic Co2

This study aims to validate the stable carbon isotopic composition (δ13C) of phytoplankton as a tool for detecting submarine leakages of anthropogenic CO2(g), since it is characterised by δ13C values significantly lower than the natural CO2 dissolved in oceans. Three culture experiments were carried out to investigate the changes in δ13C of the diatom Thalassiosira rotula during growth in an artificially modified medium (ASW). Three different dissolved inorganic carbon (DIC) concentrations were tested to verify if carbon availability affects phytoplankton δ13C. Simultaneously, at each experiment, T. rotula was cultured under natural DIC isotopic composition (δ13CDIC) and carbonate system conditions. The available DIC pool for diatoms grown in ASW was characterised by δ13CDIC values (−44.2 ± 0.9‰) significantly lower than the typical marine range. Through photosynthetic DIC uptake, microalgae δ13C rapidly changed, reaching significantly low values (until −43.4‰). Moreover, the different DIC concentrations did not affect the diatom δ13C, exhibiting the same trend in δ13C values in the three ASW experiments. The experiments prove that phytoplankton isotopic composition quickly responds to changes in the δ13C of the medium, making this approach a promising and low-impact tool for detecting CO2(g) submarine leakages from CO2(g) deposits.

A Syringe Gas-Stripping Procedure for Gas-Chromatographic Determination of Dissolved Inorganic and Organic Carbon in Fresh Water and Carbonates in Sediments

1973 ◽  
Vol 30 (10) ◽  
pp. 1441-1445 ◽  
Author(s):  
Michael P. Stainton
Keyword(s):  
Organic Carbon ◽  
Gas Phase ◽  
Atmospheric Pressure ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Chromatographic Determination ◽  
Canadian Shield ◽  
Gas Stripping ◽  
Inorganic And Organic

A simple, rapid method for determining dissolved inorganic carbon in water is described. A 20-cm3 sample of water is drawn into a 50-cm3 polypropylene syringe and acidified by injection of 1 cm3 of dilute sulphuric acid. Twenty-nine cubic centimeters of helium at atmospheric pressure is injected into the syringe followed by 10 sec of manual agitation to partition CO2 between gas and liquid phase. The gas phase containing 60% of CO2 from the sample is then analyzed by gas chromatography. This method has been used to determine dissolved inorganic and organic carbon in Canadian Shield waters and to determine total carbonates in sediments.

scholarly journals Evaluating Dissolved Inorganic Carbon Cycling in a Forested Lake Watershed Using Carbon Isotopes

Radiocarbon ◽  
1992 ◽  
Vol 34 (3) ◽  
pp. 636-645 ◽  
Author(s):  
Ramon Aravena ◽  
S. L. Schiff ◽  
S. E. Trumbore ◽  
P. J. Dillon ◽  
Richard Elgood
Keyword(s):  
Isotopic Composition ◽  
Carbon Isotopes ◽  
Inorganic Carbon ◽  
Dissolved Inorganic Carbon ◽  
Carbon Isotopic Composition ◽  
Isotopic Fractionation ◽  
Early Spring ◽  
Late Winter ◽  
Isotope Pattern ◽  
Carbon Isotopic

Dissolved inorganic carbon (DIC) is the main acid buffer in forested lake watersheds in Canada. We used carbon isotopes (13C, 14C) to evaluate the production and cycling of DIC in an acid-sensitive lake watershed of the Precambrian Shield. Soil CO2, groundwater and stream DIC were characterized chemically and isotopically. Soil CO2 concentration profiles reflect both changes in production and in losses due to diffusion. δ13C soil CO2 profiles (δ13C values of −23‰ in summer, slightly enriched during the fall and −25%‰ during the winter) are a reflection of the isotopic composition of the sources and changes in isotopic fractionation due to diffusion. Carbon isotopic composition (13C, 14C) of the groundwater and stream DIC clearly indicate that weathering of silicates by soil CO2 is the main source of DIC in these watersheds. 14C data show that, in addition to recent groundwater, an older groundwater component with depleted 14C activity is also present in the bedrock. The carbon isotope pattern in the groundwater also implies that, besides the main springtime recharge events, contributions to the groundwater may also occur during late winter/early spring.

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