The experimental researches results of adaptation of complex hydrogen and thermo-baro-chemical bottome-hole zone treatment to the conditions of coal bed are shown. Hydrogen production is realized by hydrolysis of hydro reactive substances on an aluminum basis in this technology. The methods of controlled hydrogen production depending on temperature in reaction zone are proposed. Research results proved the application of complex hydrogen and thermobaro- chemical bottome-hole zone treatment in the wells with horizontal borehole.