Organic metamorphism in the California petroleum basins; Chapter A, Rock-Eval and vitrinite reflectance

1999 ◽  
Author(s):  
Zahra Sadeghtabaghi ◽  
Mohsen Talebkeikhah ◽  
Ahmad Reza Rabbani

AbstractVitrinite reflectance (VR) is considered the most used maturity indicator of source rocks. Although vitrinite reflectance is an acceptable parameter for maturity and is widely used, it is sometimes difficult to measure. Furthermore, Rock-Eval pyrolysis is a current technique for geochemical investigations and evaluating source rock by their quality and quantity of organic matter, which provide low cost, quick, and valid information. Predicting vitrinite reflectance by using a quick and straightforward method like Rock-Eval pyrolysis results in determining accurate and reliable values of VR with consuming low cost and time. Previous studies used empirical equations for vitrinite reflectance prediction by the Tmax data, which was accompanied by poor results. Therefore, finding a way for precise vitrinite reflectance prediction by Rock-Eval data seems useful. For this aim, vitrinite reflectance values are predicted by 15 distinct machine learning models of the decision tree, random forest, support vector machine, group method of data handling, radial basis function, multilayer perceptron, adaptive neuro-fuzzy inference system, and multilayer perceptron and adaptive neuro-fuzzy inference system, which are coupled with evolutionary optimization methods such as grasshopper optimization algorithm, bat algorithm, particle swarm optimization, and genetic algorithm, with four inputs of Rock-Eval pyrolysis parameters of Tmax, S1/TOC, HI, and depth for the first time. Statistical evaluations indicate that the decision tree is the most precise model for VR prediction, which can estimate vitrinite reflectance precisely. The comparison between the decision tree and previous proposed empirical equations indicates that the machine learning method performs much more accurately.


2020 ◽  
Vol 10 (8) ◽  
pp. 3207-3225
Author(s):  
Mohamed Ragab Shalaby ◽  
Muhammad Izzat Izzuddin bin Haji Irwan ◽  
Liyana Nadiah Osli ◽  
Md Aminul Islam

Abstract This research aims to conduct source rock characterization on the Narimba Formation in the Bass Basin, Australia, which is made of mostly sandstone, shale and coal. The geochemical characteristics and depositional environments have been investigated through a variety of data such as rock–eval pyrolysis, TOC, organic petrography and biomarkers. Total organic carbon (TOC) values indicated good to excellent organic richness with values ranging from 1.1 to 79.2%. Kerogen typing of the examined samples from the Narimba Formation indicates that the formation contains organic matter capable of generating kerogen Type-III, Type-II-III and Type-II which is gas prone, oil–gas prone and oil prone, respectively. Pyrolysis maturity parameters (Tmax, PI), in combination with vitrinite reflectance and some biomarkers, all confirm that all samples are at early mature to mature and are in the oil and wet gas windows. The biomarkers data (the isoprenoids (Pr/Ph), CPI, isoprenoids/n-alkanes distribution (Pr/nC17 and Ph/nC18), in addition to the regular sterane biomarkers (C27, C28 and C29) are mainly used to evaluate the paleodepositional environment, maturity and biodegradation. It has been interpreted that the Narimba Formation was found to be deposited in non-marine (oxygen-rich) depositional environment with a dominance of terrestrial plant sources. All the analyzed samples show clear indication to be considered at the early mature to mature oil window with some indication of biodegradation.


1982 ◽  
Vol 22 (1) ◽  
pp. 5
Author(s):  
A. R. Martin ◽  
J. D. Saxby

The geology and exploration history of the Triassic-Cretaceous Clarence-Moreton Basin are reviewed. Consideration of new geochemical data ('Rock-Eval', vitrinite reflectance, gas chromatography of extracts, organic carbon and elemental analysis of coals and kerogens) gives further insights into the hydrocarbon potential of the basin. Although organic-rich rocks are relatively abundant, most source rocks that have achieved the levels of maturation necessary for hydrocarbon generation are gas-prone. The exinite-rich oil-prone Walloon Coal Measures are in most parts relatively immature. Some restraints on migration pathways are evident and igneous and tectonic events may have disturbed potentially well-sealed traps. Further exploration is warranted, even though the basin appears gas-prone and the overall prospects for hydrocarbons are only fair. The most promising areas seem to be west of Toowoomba for oil and the Clarence Syncline for gas.


Geology ◽  
2020 ◽  
Vol 48 (9) ◽  
pp. 851-856 ◽  
Author(s):  
Benjamin Brigaud ◽  
Magali Bonifacie ◽  
Maurice Pagel ◽  
Thomas Blaise ◽  
Damien Calmels ◽  
...  

Abstract Geothermometers are commonly used to reconstruct the diagenetic and thermal history of rocks. However, characterizing the timing, origin, and temperature of paleofluid flow remains challenging because it must be assessed indirectly through the analysis of microscopic cements that precipitate and fill intergranular spaces during fluid circulation. Here, we measure both the clumped isotope (Δ47) temperature and in situ U-Pb age of individual diagenetic calcite cements within a sedimentary section of the Paris Basin (France), whose thermal history has been previously inferred to be <60 °C. We show that cementation occurred during two stages associated with major events at the western European lithospheric scale: (1) the Bay of Biscay rifting (Late Jurassic–Early Cretaceous), and (2) north-south Pyrenean compression (Eocene) followed by east-west extension during the European Cenozoic rift system event (Oligocene). Related to both events, we report unexpectedly hot fluids, up to 110 °C, contrasting with the lower temperatures inferred from other geothermometers (e.g., fluid inclusions, clay minerals, apatite fission tracks, maturity of organic matter by Rock-Eval pyrolysis, or vitrinite reflectance). These high temperatures (>70 °C) have been measured for calcite cements containing single-phase aqueous fluid inclusions, challenging the commonly accepted assertion that the absence of nucleation of a vapor phase indicates crystallization at low temperature (∼<70 °C). We suggest that the kinetics of mineralization events prevented the recording of short-lived hot fluid flows by other geothermometers.


2017 ◽  
Vol 180 ◽  
pp. 29-45 ◽  
Author(s):  
Stephen Cheshire ◽  
Paul R. Craddock ◽  
Guangping Xu ◽  
Bastian Sauerer ◽  
Andrew E. Pomerantz ◽  
...  

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