scholarly journals Adsorption-desorption Kinetics of Hydrogen Molecules on Granulated Alumina Using Resonance-enhanced Multiphoton Ionization Method.

Shinku ◽  
1999 ◽  
Vol 42 (3) ◽  
pp. 286-289 ◽  
Author(s):  
Tamotsu MAGOME ◽  
Katsuyuki FUKUTANI ◽  
Tatsuo OKANO
Soil Science ◽  
1988 ◽  
Vol 146 (4) ◽  
pp. 221-231 ◽  
Author(s):  
J. J. T. I. BOESTEN ◽  
L. J. T. VAN DER PAS

2019 ◽  
Vol 17 (2) ◽  
pp. 371-380 ◽  
Author(s):  
Mohamed El messoudi ◽  
Aicha Boukhriss ◽  
Omar Cherkaoui ◽  
M’hammed El kouali ◽  
Said Gmouh

1993 ◽  
Vol 99 (9) ◽  
pp. 7190-7197 ◽  
Author(s):  
C. R. Carlson ◽  
W. F. Buechter ◽  
F. Che‐Ibrahim ◽  
E. G. Seebauer

Molecules ◽  
2020 ◽  
Vol 25 (16) ◽  
pp. 3662
Author(s):  
Victor N. Bondarev ◽  
Volodymyr V. Kutarov ◽  
Eva Schieferstein ◽  
Vladimir V. Zavalniuk

The experiments on the kinetics of molecular desorption from structurally disordered adsorbents clearly demonstrate its non-Debye behavior at “long” times. In due time, when analyzing the desorption of hydrogen molecules from crystalline adsorbents, attempts were made to associate this behavior with the manifestation of second-order effects, when the rate of desorption is limited by the rate of surface diffusion of hydrogen atoms with their subsequent association into molecules. However, the estimates made in the present work show that the dominance of second-order effects should be expected in the region of times significantly exceeding those where the kinetics of H2 desorption have long acquired a non-Debye character. To explain the observed regularities, an approach has been developed according to which frozen fluctuations in the activation energy of desorption play a crucial role in the non-Debye kinetics of the process. The obtained closed expression for the desorption rate has a transparent physical meaning and allows us to give a quantitative interpretation of a number of experiments on the desorption kinetics of molecules not only from crystalline (containing frozen defects) but also from amorphous adsorbents. The ways of further development of the proposed theory and its experimental verification are outlined.


Energies ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 4013 ◽  
Author(s):  
Norbert Skoczylas ◽  
Anna Pajdak ◽  
Mariusz Młynarczuk

The paper presents the results of studies on sorption and CO2 desorptions from coals from two Polish mines that differed in petrographic and structural properties. The tests were carried out on spherical and plane sheet samples. On the basis of the sorption tests, the effective diffusion coefficient was calculated on the plane sheet samples based on a proper model. Similar tests were performed on the spherical samples. Mathematical model results for plane sheet samples were compared with the most frequently chosen model for spherical samples. The kinetics of CO2 desorption from plane sheet samples were compared with the kinetics of sample shrinkage. In both samples, the shrinkage was about 0.35%. The size change kinetics and CO2 desorption kinetics significantly differed between the samples. In both samples, the determined shrinkage kinetics was clearly faster than CO2 kinetics.


Soil Science ◽  
2011 ◽  
Vol 176 (11) ◽  
pp. 582-588 ◽  
Author(s):  
Chang Yoon Jeong ◽  
H. Magdi Selim

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