scholarly journals QUANTITATIVE STUDY ON THE EFFECT OF HIGH-TEMPERATURE CURING AT AN EARLY AGE ON STRENGTH DEVELOPMENT OF CONCRETE : Experiment with mortar using moderate-heat portland cement

Author(s):  
Hisashi SUGIYAMA ◽  
Shigeo CHINO
2019 ◽  
Vol 11 (6) ◽  
pp. 168781401985194 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Ruijie Xia ◽  
Huanhuan Hou ◽  
Haibin Yin ◽  
...  

Nanomaterial, as a new emerging material in the field of civil engineering, has been widely utilized to enhance the mechanical properties of cementitious material. Nano-SnO2 has presented high hardness characteristics, but there is little study of the application of nano-SnO2 in the cementitious materials. This study mainly investigated the hydration characteristics and strength development of Portland cement paste incorporating nano-SnO2 powders with 0%, 0.08%, and 0.20% dosage. It was found that the early-age compressive strength of cement paste could be greatly improved when nano-SnO2 was incorporated with 0.08% dosage. The hydration process and microstructure were then measured by hydraulic test machine, calorimeter, nanoindentation, X-ray diffraction, scanning electron microscope, and mercury intrusion porosimetry. It was found that the cement hydration process was promoted by the addition of nano-SnO2, and the total amount of heat released from cement hydration is also increased. In addition, the addition of nano-SnO2 can promote the generations of high density C-S-H and reduce the generations of low density C-S-H indicating the nucleation effect of nano-SnO2 in the crystal growth process. The porosity and probable pore diameter of cement paste with 0.08% nano-SnO2 were decreased, and the scanning electron microscopic results also show that the cement paste with 0.08% nano-SnO2 promotes the densification of cement microstructure, which are consistent with the strength performance.


Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4999
Author(s):  
Lanh Si Ho ◽  
Kenichiro Nakarai ◽  
Kenta Eguchi ◽  
Yuko Ogawa

To improve the strength of cement-treated sand effectively, the use of various cement types was investigated at different curing temperatures and compared with the results obtained from similar mortars at higher cement contents. The compressive strengths of cement-treated sand specimens that contained high early-strength Portland cement (HPC) cured at elevated and normal temperatures were found to be higher than those of specimens that contained ordinary Portland cement (OPC) and moderate heat Portland cement at both early and later ages. At 3 days, the compressive strength of the HPC-treated sand specimen, normalized with respect to that of the OPC under normal conditions, is nearly twice the corresponding value for the HPC mortar specimens with water-to-cement ratio of 50%. At 28 days, the normalized value for HPC-treated sand is approximately 1.5 times higher than that of mortar, with a value of 50%. This indicates that the use of HPC contributed more to the strength development of the cement-treated sand than to that of the mortar, and the effects of HPC at an early age were higher than those at a later age. These trends were explained by the larger quantity of chemically bound water observed in the specimens that contained HPC, as a result of their greater alite contents and porosities, in cement-treated sand. The findings of this study can be used to ensure the desired strength development of cement-treated soils by considering both the curing temperature and cement type. Furthermore, they suggested a novel method for producing a high internal temperature for promoting the strength development of cement-treated soils.


Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 816
Author(s):  
Yuli Wang ◽  
Huijuan Lu ◽  
Junjie Wang ◽  
Hang He

In order to improve the early age strength of ordinary Portland cement-based materials, many early strength agents were applied in different conditions. Different from previous research, the nano calcium silicate hydrate (C-S-H) particles used in this study were synthesized through the chemical reaction of CaO, SiO2, and H2O under 120 °C using the hydrothermal method, and the prepared nano C-S-H particles were highly crystalized. The influences of different amounts of nano C-S-H particles (0%, 0.5%, 1%, 2% and 3% by weight of cement) on the setting time, compressive strength, and hydration heat of cement paste were studied. The hydration products and microstructure of the cement paste with different additions of nano C-S-H particles were investigated through thermogravimetry-differential thermal analysis (TG-DTA), X-ray powder diffraction (XRD), and scanning electron microscope (SEM) tests. The results show that the nano C-S-H particles could be used as an early strength agent, and the early strength of cement paste can be increased by up to 43% through accelerating the hydration of tricalcium silicate (C3S). However, the addition of more than 2% nano C-S-H particles was unfavorable to the later strength development due to more space being left during the initial accelerated hydration process. It is suggested that the suitable content of the nano C-S-H particles is 0.5%−1% by weight of cement.


2019 ◽  
Vol 889 ◽  
pp. 294-303
Author(s):  
Quoc Si Bach

The compressive strength development always go along with the microstructure development in concrete through the process of cement hydration. In the hydrated products of cement, calcium silicate hydrate (C-S-H) forms a network of nanoparticles so C-S-H gel is the main compound giving compressive strength of concrete. As we know that C-S-H gel produced by the reactions with water of two main minerals in cement such as Tricalcium Silicate () and Dicalcium Silicate (). In addition, the increase of C-S-H content in concrete due to the pozzolanic reaction of the pozzolan with calcium hydroxide (CH). With the aim of this research is quantitative study of hydration of and in the Reactive Powder Concrete (RPC) together with its compressive strength development, three concrete formulas were estimated in this study which made from three different types of cement ownership different mineral compositions content were tested on compressive strength and on heat flux emitted from hydration process by isothermal calorimetry. The purpose of measuring heat flux emitted from chemical reaction process in concrete is to verify the hydration kinetic model for portland cement containing the silica fume. Basing on this simulation program, the amount of C-S-H gel in concrete is calculated. The research results showed that the the C-S-H content formed in binder paste of RPC is proportional to compressive strength development. The (Ordinary Portland Cement) OPC with higher content have compressive strength development earlier.


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